Registration Dossier
Registration Dossier
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EC number: 615-064-0 | CAS number: 700874-87-9
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
In case of inhalation
- If breathed in, move person into fresh air.
- Oxygen or artificial respiration if needed.
- Consult a physician.
In case of skin contact
- Wash off with soap and water.
In case of eye contact
- Flush eyes with running water for several minutes, while keeping the eyelids wide open.
- Consult a physician.
In case of ingestion
- negligible
Most important symptoms and effects, both acute and delayed
In case of inhalation
Effects
- No hazards to be specially mentioned.
In case of skin contact
Symptoms
- No skin irritation
In case of eye contact
Symptoms
- May cause
- Redness
In case of ingestion
- negligible
Fire-fighting measures
-Extinguishing media
Suitable extinguishing media
- Water
- powder
- Foam
- Dry chemical
- Carbon dioxide (CO2)
Unsuitable extinguishing media
- None
5.2 Special hazards arising from the substance or mixture
Specific hazards during firefighting
- Extremely flammable gas.
- Extremely flammable liquid and vapour.
- Flash back possible over considerable distance.
- Explosion risk in case of fire.
- Vapours are heavier than air and may spread along floors.
- Risk of ignition.
- Thermal decomposition can lead to release of toxic and corrosive gases.
Hazardous combustion products:
- Gaseous hydrogen fluoride (HF).
- Fluorophosgene
5.3 Advice for firefighters
Special protective equipment for firefighters
- Wear self-contained breathing apparatus and protective suit.
- When intervention in close proximity wear acid resistant over suit.
Further information
- Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
- Evacuate personnel to safe areas.
- Approach from upwind.
- Protect intervention team with a water spray as they approach the fire.
- Keep containers and surroundings cool with water spray.
- Keep product and empty container away from heat and sources of ignition.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel
- Prevent further leakage or spillage if safe to do so.
Advice for emergency responders
- Ventilate the area.
- Suppress (knock down) gases/vapours/mists with a water spray jet.
- Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing.
- Cover the spreading liquid with foam in order to slow down the evaporation.
- Keep away from open flames, hot surfaces and sources of ignition.
- Refer to protective measures listed in sections 7 and 8.
Environmental precautions
- Should not be released into the environment.
- Do not flush into surface water or sanitary sewer system.
Methods and materials for containment and cleaning up
- Suppress (knock down) gases/vapours/mists with a water spray jet.
- Soak up with inert absorbent material.
- Suitable material for picking up.
- Earth
- Dry sand
- Shovel into suitable container for disposal.
Reference to other sections
- Refer to protective measures listed in sections 7 and 8 of SDS
Handling and storage
Precautions for safe handling
- Ensure adequate ventilation.
- Wear protective gloves/ protective clothing/ eye protection/ face protection.
- Keep away from heat/sparks/open flames/hot surfaces. No smoking.
- Keep away from heat and sources of ignition.
- Use explosion-proof electrical/ ventilating/ lighting equipment.
- Ground/bond container and receiving equipment.
- Use only non-sparking tools.
- Take precautionary measures against static discharge.
- Purge piping circuits and equipment with nitrogen.
- To avoid thermal decomposition, do not overheat.
Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities
Technical measures/Storage conditions
- Keep away from heat and sources of ignition.
- Store in a well-ventilated place. Keep cool.
- To maintain product quality, do not store in heat or direct sunlight.
- Vapours are heavier than air and may spread along floors.
- Keep away from combustible material.
- Keep away from incompatible products
- Provide electrical equipment safe for hazardous locations.
- Ensure all equipment is electrically grounded before beginning transfer operations.
- Refer to protective measures listed in sections 7 and 8 of SDS
Packaging material
Suitable material
- Stainless steel
- Carbon steel
- Contents under pressure.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 1993
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID, N.O.S. (Perfluoro-3,5-Dioxa-1-Hexene)
- Labels:
- 3
Special provisions / remarks
- Special provisions:
- Special precautions for user
Hazard Identification Number: 33
Tunnel restriction code (D/E)
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 1993
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID, N.O.S. (Perfluoro-3,5-Dioxa-1-Hexene)3
- Labels:
- 3
Special provisions / remarks
- Remarks:
- Special precautions for user
Hazard Identification Number: 33
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 1993
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID, N.O.S. (Perfluoro-3,5-Dioxa-1-Hexene)
- Labels:
- 3
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 1993
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID, N.O.S. (Perfluoro-3,5-Dioxa-1-Hexene)
- Labels:
- 3
Special provisions / remarks
- Remarks:
- Special precautions for user
Packing instruction (cargo aircraft) 361
Max net qty/pkg 30.00 L
Packing instruction (passenger aircraft) 351
Max net qty/pkg 1.00 L
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Exposure controls
Control measures
Engineering measures
- Ensure adequate ventilation.
- Refer to protective measures listed in sections 7 and 8.
- Apply technical measures to comply with the occupational exposure limits.
Individual protection measures
Respiratory protection
- In case of insufficient ventilation, wear suitable respiratory equipment.
- In case of vapour or mist, face mask with combined ABEK-P2 cartridge.
- In case of decomposition (see section 10), use an air breathing apparatus with face mask.
- Use only respiratory protection that conforms to international/ national standards.
Hand protection
- Wear protective gloves.
Suitable material
- Nitrile rubber
- Neoprene gloves
- Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).
Eye protection
- Tightly fitting safety goggles
Skin and body protection
- Wear work overall and safety shoes.
Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.
Stability and reactivity
Reactivity
- No dangerous reaction known under conditions of normal use.
- Stable under recommended storage conditions.
- In case of heating:
- polymerisation
Possibility of hazardous reactions
- No dangerous reaction known under conditions of normal use.
Conditions to avoid
- To avoid thermal decomposition, do not overheat.
- Keep away from flames and sparks.
Incompatible materials
- Combustible material
- Flammable materials
- Strong oxidizing agents
- Peroxides
- Bases
Hazardous decomposition products
- Fluorofosgene
- Gaseous hydrogen fluoride (HF)
Disposal considerations
Disposal considerations
Waste treatment methods
Product Disposal
- Can be incinerated, when in compliance with local regulations.
- The incinerator must be equipped with a system for the neutralisation or recovery of HF.
- Dispose of in accordance with local regulations.
Advice on cleaning and disposal of packaging
- Purge the container with nitrogen and direct the gas to a treatment plant.
- Empty containers can be landfilled, when in accordance with the local regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
