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Diss Factsheets

Physical & Chemical properties

Boiling point

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Administrative data

Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2012
Reliability:
2 (reliable with restrictions)

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2011
Report date:
2012

Materials and methods

Test guideline
Qualifier:
equivalent or similar to guideline
Guideline:
EU Method A.2 (Boiling Temperature)
Principles of method if other than guideline:
Approximately 100g of sample was placed in an open beaker, and heated on a hotplate. The temperature was monitored using a thermometer
GLP compliance:
not specified
Type of method:
distillation method

Test material

Constituent 1
Chemical structure
Reference substance name:
2-ethylhexyl diphenyl phosphite
EC Number:
239-716-5
EC Name:
2-ethylhexyl diphenyl phosphite
Cas Number:
15647-08-2
Molecular formula:
C20H27O3P
IUPAC Name:
phosphorous acid, 2-ethylhexyl diphenyl ester
Details on test material:
2-ethylhexyl diphenyl phosphite (Lankromark LE98) Batch 016991

Results and discussion

Boiling point
Boiling pt.:
> 224 °C
Decomposition:
yes
Remarks on result:
other: Hydrolysis and decomposition are expected to occur prior to boiling. An exact decomposition temperature could not be determined.

Any other information on results incl. tables

On heating the sample in an open beaker, a small amount of condensation was seen above the sample at 120ºC, and vapours were visible at 149ºC, although the sample did not show any signs of boiling. The test was terminated at 224ºC due to the limitations of the equipment used. No signs of boiling were noted.

Applicant's summary and conclusion

Conclusions:
2-Ethylhexyl diphenyl phosphite is known to hydrolyse readily on contact with moisture. The signs of boiling seen in the open beaker apparatus can therefore be attributed to 2-ethylhexanol which is liberated by the hydrolysis of the phosphite. It can therefore be concluded that 2-ethylhexyl diphenyl phosphite decomposes or hydrolyses before the boiling point is reached.