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Physical & Chemical properties

Flash point

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Administrative data

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Reference
Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2016-11-04
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Version / remarks:
2008
Deviations:
no
Qualifier:
according to guideline
Guideline:
ISO 13736 (Petroleum products and other liquids - Determination of flash point - Abel closed cup method)
Version / remarks:
2013
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: Recommendations on the TRANSPORT OF DANGEROUS GOODS: Manual of Tests and Criteria: Class 3, Flammable Liquids
Version / remarks:
6th edition, 2015
Deviations:
no
GLP compliance:
no
Type of method:
closed cup
Flash point apparatus:
Abel apparatus
Key result
Flash point:
17 °C
Atm. press.:
1 013 hPa
Remarks on result:
other: average corrected and rounded down to the nearest multiple of 0.5 °C

Preliminary test:

In the preliminary test the lowest temperature where an ignition was observed was 16.0 °C.

Main test:

amount of test item / g

temperature / °C

ignition (+/-)

air pressure/ hPa

flash point (corr.)/ °C

66.44

17.0

+

1004.9

17.20

66.51

17.0

+

1003.8

17.23

In the main test the lowest temperature where an ignition was observed was 17.0 °C. The mean measured flash point is corrected to the ambient pressure to be 17.22 °C. The resulting average corrected flash point rounded down to the nearest multiple of 0.5 °C is 17.0 °C.

Interpretation of results:
Category 2 (highly flammable liquids) based on GHS criteria
Conclusions:
The test item has a flash point of 17.0 °C (average corrected and rounded down to the nearest multiple of 0.5 °C).
Executive summary:

In the current study the flash point of the test item was determined according to Regulation EC No. 440/2008 Method A.9. Flash Point, DIN EN ISO 13736 (2013).

The flash point of the test item was determined to be 17.0°C (average corrected and rounded down to the nearest multiple of 0.5°C).

Description of key information

For this endpoint one experimental study is available. The flash point was determined according to EC method A.9, in closed cup using a Abel apparatus. The flash point was found to be 17.0°C.

Key value for chemical safety assessment

Flash point at 101 325 Pa:
17 °C

Additional information

According to the results of the test on the flash point, the test item is classified as following:

UN Transport Regulation: As the test item has a boiling range of 108 - 111 °C (see Study No. CSL-16-2233.01), (> 35 °C) and a measured flash point of 17.0 °C (<23 °C), it has to be classified in class 3 as flammable liquid of Packaging Group II.

GHS (CLP Regulation EC 1272/2008 Annex 1: 2.6): As the test item has a measured flash point of 17.0 °C (< 23 °C), it has to be classified as highly flammable liquid of category 2 and has to be marked with the warning "H225: highly flammable liquid and vapour".