Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
explosive properties of explosives
Type of information:
experimental study
Adequacy of study:
key study
Study period:
18 Feb - 6 Apr 2020
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2020
Report date:
2020

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
UN Manual of Tests and Criteria: Part I: Classification procedures, test methods and criteria relating to explosives of Class 1
Version / remarks:
UN Manual of Tests and Criteria, rev. 7 (2019), Appendix 6
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: OECD 113 Screening test for thermal stability and stability in air
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Remarks:
Hess. Ministerium für Umwelt, Klimaschutz, Landwirtschaft und Verbraucherschutz, Wiesbaden, Germany

Test material

Constituent 1
Chemical structure
Reference substance name:
1,1,3-trimethyl-2,3-dihydro-1H-inden-4-amine
EC Number:
838-724-1
Cas Number:
94568-76-0
Molecular formula:
C12H17N
IUPAC Name:
1,1,3-trimethyl-2,3-dihydro-1H-inden-4-amine

Results and discussion

Small-scale preliminary tests
Parameter:
other: decomposition energy from DSC measurement
Remarks on result:
not required
Remarks:
If the decomposition energy is below 500 J/g further tests for explosive properties are unnecessary.

Any other information on results incl. tables

Thermal stability
One DSC measurement in closed glass crucibles showed no endothermal or exothermal effects up to 450 °C. At approximately 450 °C the course of the baseline became ambiguous (possibly caused by a rise in pressure). This measurement already indicated the absence of significant exothermal effects. However, due to the disturbance of the baseline the measurement was repeated in closed high pressure crucibles to ensure that no significant exothermal effects were missed.
One DSC measurement in closed high pressure crucibles showed two exothermal effects in the temperature ranges of 225 - 330 °C and 420 - 490 °C with an overall energy release of 156 J/g.
The results are summarized in the Table below:





























Ident-No.Weight / mgFinal temperature / °CTemperature range / °CType of effectEnergy / J/g
3904110.36500-  
3905617.57500

225-330


420-490



Exothermal


Exothermal



96


60


Applicant's summary and conclusion