Registration Dossier
Registration Dossier
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EC number: 225-007-8 | CAS number: 4605-14-5
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
Immediately remove contaminated clothing. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). If not breathing, give artificial respiration. First aid personnel should pay attention to their own safety.
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further symptoms are possible
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.
Immediately remove contaminated clothing. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). If not breathing, give artificial respiration. First aid personnel should pay attention to their own safety.
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further symptoms are possible
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media:
dry powder, foam
Unsuitable extinguishing media for safety reasons:
water jet
Special hazards arising from the substance or mixture
nitrogen oxides, carbon oxides, amine derivatives
The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated.
Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Suitable extinguishing media:
dry powder, foam
Unsuitable extinguishing media for safety reasons:
water jet
Special hazards arising from the substance or mixture
nitrogen oxides, carbon oxides, amine derivatives
The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated.
Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Avoid inhalation. Avoid contact with the skin, eyes and clothing.
Environmental precautions
Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up
For small amounts: Pick up with suitable absorbent material.
For large amounts: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr).
Dispose of absorbed material in accordance with regulations. Do not discharge into drains/surface waters/groundwater. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations.
Avoid inhalation. Avoid contact with the skin, eyes and clothing.
Environmental precautions
Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up
For small amounts: Pick up with suitable absorbent material.
For large amounts: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr).
Dispose of absorbed material in accordance with regulations. Do not discharge into drains/surface waters/groundwater. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations.
Handling and storage
Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Handle in accordance with good industrial hygiene and safety practice. Remove contaminated clothing and protective equipment before entering eating areas. Hands and/or face should be washed before breaks and at the end of the shift. When using do not eat, drink or smoke.
Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Containers should be stored tightly sealed in a dry place.
Storage stability:
Storage temperature: < 30 °C
Storage duration: 24 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.
Ensure thorough ventilation of stores and work areas. Handle in accordance with good industrial hygiene and safety practice. Remove contaminated clothing and protective equipment before entering eating areas. Hands and/or face should be washed before breaks and at the end of the shift. When using do not eat, drink or smoke.
Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Containers should be stored tightly sealed in a dry place.
Storage stability:
Storage temperature: < 30 °C
Storage duration: 24 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Control parameters
Components with occupational exposure limits
No occupational exposure limits known.
Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.
Body protection:
chemical protection overall (f.e. according to EN 13982) if dust is formed.
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with the skin, eyes and clothing. Avoid inhalation. When using, do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Store work clothing separately.
Components with occupational exposure limits
No occupational exposure limits known.
Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.
Body protection:
chemical protection overall (f.e. according to EN 13982) if dust is formed.
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with the skin, eyes and clothing. Avoid inhalation. When using, do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Store work clothing separately.
Stability and reactivity
Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals:
Corrosive effects to metal are not anticipated. In the presence of water or moisture metal corrosion cannot be excluded.
Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.
Chemical stability
The product is chemically stable.
Possibility of hazardous reactions
Evolution of heat under influence of acids.
Conditions to avoid
Research and developmental product, therefore not yet tested or assessed.
Incompatible materials
Substances to avoid:
oxidizing agents, acids
Hazardous decomposition products
Thermal decomposition products:
carbon oxides, nitrous gases
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals:
Corrosive effects to metal are not anticipated. In the presence of water or moisture metal corrosion cannot be excluded.
Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.
Chemical stability
The product is chemically stable.
Possibility of hazardous reactions
Evolution of heat under influence of acids.
Conditions to avoid
Research and developmental product, therefore not yet tested or assessed.
Incompatible materials
Substances to avoid:
oxidizing agents, acids
Hazardous decomposition products
Thermal decomposition products:
carbon oxides, nitrous gases
Disposal considerations
Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging:
The packaging must not be re-used.
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging:
The packaging must not be re-used.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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