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Diss Factsheets

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
explosive properties of explosives
Type of information:
experimental study
Adequacy of study:
key study
Study period:
From June 15, 1999 to June 16, 1999
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.14 (Explosive properties)
Deviations:
no
GLP compliance:
yes
Parameter:
other: DSC
Remarks on result:
not thermal sensitive if heated under defined confinement
Remarks:
The heat of decomposition was below 500 J/g. Therefore, the main test on explosion properties was not performed.

The measurement in a closed glass pan did not show any endothermic effect prior an exothermal effect in the range of 140 -205°C, with energy of 42 J/g. At 215°C, an exothermal decomposition was observed in the range 215-320°C, with decomposition energy of 265 J/g. Measured decomposition energy was below 500 J/g, so the main test of explosive properties was deemed unnecessary.

Interpretation of results:
GHS criteria not met
Conclusions:
Under the study conditions, the test substance was found to be non-explosive.
Executive summary:

A study was conducted to determine the explosiveness of the test substance according to the EU Method A.14, in compliance with GLP.

A preliminary screening study for explosive properties was carried out with the purified test substance by differential scanning calorimetry (DSC) in closed glass pan. The heat of decomposition was below 500 J/g. Therefore, the main test on explosion properties was not performed.

Under the study conditions, the test substance was found to be non-explosive.

Description of key information

The test substance is non-explosive (Smeykal, 1999).

Key value for chemical safety assessment

Explosiveness:
non explosive

Additional information

Justification for classification or non-classification