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Physical & Chemical properties

Vapour pressure

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
02 May 2018 to 25 May 2018
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Version / remarks:
Not reported
Deviations:
no
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Version / remarks:
Not reported
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
effusion method: isothermal thermogravimetry
Test no.:
#2
Temp.:
25 °C
Vapour pressure:
0 Pa
Test no.:
#3
Temp.:
25 °C
Vapour pressure:
0 Pa
Temp.:
25 °C
Vapour pressure:
0 Pa
Remarks on result:
other: Mean vapour pressure

For run 1, there was initial high weight losses at lower temperatures. This was indicative of degassing of the sample. Only the data from runs 2 and 3 have therefore been used for calculations.

Table 1: A summary of the run 2 and 3 results

 Parameter  Run 2  Run 3
 Correlation (R2)  0.9941  0.9965
 Slope  -4134  -4490
 Intercept  10.19  10.90
 log10PT at 25 °C  -3.7  -4.2
 PT (Pa) at 25 °C  0.00021  0.000069

Table 2: Vapour Pressure Measurements (Run 2)

 Temperature (°C)  Evaporation rate, VT (g/minute) log10VT   log10PT
 118.63  0.0000002613  -4.098  -0.3745
 123.61  0.0000003556  -3.964  -0.2313
 128.59  0.0000004873  -3.827  -0.0849
 133.58  0.0000006356  -3.712  0.0386
 138.56  0.0000007712  -3.628  0.1285

Table 3: Vapour Pressure Measurements (Run 3)

 Temperature (°C)  Evaporation rate, VT(g/minute) log10VT   log10PT
 123.64  0.0000002342  -4.145  -0.4253
 128.61  0.0000003325  -3.993  -0.2625
 133.58  0.0000004368  -3.874  -0.1357
 138.55  0.0000005693  -3.759  -0.01259
Conclusions:
The vapour pressure of the test item was determined to be 1 x 10-4 Pa at 25 °C.
Executive summary:

The vapour pressure of the test item was determined in a study following OECD 104 and EC Method A.4 guidelines, using the effusion method. The vapour pressure of the test item was determined to be 1 x 10-4 Pa at 25 °C.

 

The study is a GLP compliant, guideline experimental study and is fully acceptable for assessment of this endpoint.

Description of key information

The vapour pressure of the test item was determined to be 1 x 10-4 Pa at 25 °C.

Key value for chemical safety assessment

Vapour pressure:
0 Pa
at the temperature of:
25 °C

Additional information

The vapour pressure of the test item was determined in a study following OECD 104 and EC Method A.4 guidelines, using the effusion method.

 

The study is a GLP compliant, guideline experimental study and is fully acceptable for assessment of this endpoint.