Registration Dossier
Registration Dossier
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EC number: 608-319-2 | CAS number: 29126-51-0
Guidance on Safe Use
Guidance on Safe Use
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Administrative data
First-aid measures
DESCRIPTION OF FIRST AID MEASURES
INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.
SKIN CONTACT
Wash contact areas with soap and water.
EYE CONTACT
Flush thoroughly with water for at least 15 minutes. Get medical assistance.
INGESTION
Seek immediate medical attention.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
Headache, dizziness, drowsiness, nausea and other CNS effects. Eye pain, redness, tearing, swelling of eyelids, itching.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED
The need to have special means for providing specific and immediate medical treatment available in the workplace is not expected.
INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.
SKIN CONTACT
Wash contact areas with soap and water.
EYE CONTACT
Flush thoroughly with water for at least 15 minutes. Get medical assistance.
INGESTION
Seek immediate medical attention.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
Headache, dizziness, drowsiness, nausea and other CNS effects. Eye pain, redness, tearing, swelling of eyelids, itching.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED
The need to have special means for providing specific and immediate medical treatment available in the workplace is not expected.
Fire-fighting measures
EXTINGUISHING MEDIA
Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.
Unsuitable Extinguishing Media: Straight streams of water
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE
Hazardous Combustion Products: Incomplete combustion products, Oxides of carbon, Smoke, Fume
ADVICE FOR FIRE FIGHTERS
Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel.
Unusual Fire Hazards: Explosion: Avoid generating dust; fine dust dispersed in air in sufficient concentration and in the presence of an ignition source is a potential dust explosion hazard. Hazardous material.
Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.
Unsuitable Extinguishing Media: Straight streams of water
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE
Hazardous Combustion Products: Incomplete combustion products, Oxides of carbon, Smoke, Fume
ADVICE FOR FIRE FIGHTERS
Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel.
Unusual Fire Hazards: Explosion: Avoid generating dust; fine dust dispersed in air in sufficient concentration and in the presence of an ignition source is a potential dust explosion hazard. Hazardous material.
Accidental release measures
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
PROTECTIVE MEASURES
Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required, due to toxicity or flammability of the material. Dust Deposits should not be allowed to accumulate on surfaces, as these may form an explosive mixture if they are released into the atmosphere in sufficient concentration. Avoid dispersal of dust in the air (for example, clearing dust surfaces with compressed air). Prevent dust exposure to ignition sources. For example, use non-sparking tools and prohibit smoking, flares, sparks or flames in immediate area.
ENVIRONMENTAL PRECAUTIONS
Prevent entry into waterways, sewers, basements or confined areas.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP
Land Spill: Stop leak if you can do so without risk. Ventilate the area. Prevent dust cloud. Vacuum material into a recovery container.
Water Spill: Stop leak if you can do so without risk. Warn other shipping. Material will sink. Consult an expert. No immediate action required.
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.
NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
PROTECTIVE MEASURES
Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required, due to toxicity or flammability of the material. Dust Deposits should not be allowed to accumulate on surfaces, as these may form an explosive mixture if they are released into the atmosphere in sufficient concentration. Avoid dispersal of dust in the air (for example, clearing dust surfaces with compressed air). Prevent dust exposure to ignition sources. For example, use non-sparking tools and prohibit smoking, flares, sparks or flames in immediate area.
ENVIRONMENTAL PRECAUTIONS
Prevent entry into waterways, sewers, basements or confined areas.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP
Land Spill: Stop leak if you can do so without risk. Ventilate the area. Prevent dust cloud. Vacuum material into a recovery container.
Water Spill: Stop leak if you can do so without risk. Warn other shipping. Material will sink. Consult an expert. No immediate action required.
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.
Handling and storage
PRECAUTIONS FOR SAFE HANDLING
Minimize dust generation and accumulation. Routine housekeeping should be instituted to ensure that dusts do not accumulate on surfaces. Dust from material can accumulate electrostatic charges due to friction from transfer and mixing operations and cause an electrical spark (ignition source). Provide adequate precautions to ignition sources, such as electrical grounding and bonding, inert atmosphere or non-sparking tools. However, bonding and grounds may not eliminate the hazard for static accumulation. Consult local applicable standards for guidance. Refer to NFPA 654, Standard for the Prevention of Fire and Dust Explosions from the Manufacturing, Processing, and Handling of Combustible Particulate Solids and EN 61241, Electrical Apparatus for Use in the Presence of Combustible Dust for safe handling. Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Avoid contact with eyes. Product may generate heat if it comes in contact with water or water vapour. Prevent small spills and leakage to avoid slip hazard.
Static Accumulator: This material is a static accumulator.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
The type of container used to store the material may affect static accumulation and dissipation. Do not store in open or unlabelled containers. Keep container tightly closed and dry.
Minimize dust generation and accumulation. Routine housekeeping should be instituted to ensure that dusts do not accumulate on surfaces. Dust from material can accumulate electrostatic charges due to friction from transfer and mixing operations and cause an electrical spark (ignition source). Provide adequate precautions to ignition sources, such as electrical grounding and bonding, inert atmosphere or non-sparking tools. However, bonding and grounds may not eliminate the hazard for static accumulation. Consult local applicable standards for guidance. Refer to NFPA 654, Standard for the Prevention of Fire and Dust Explosions from the Manufacturing, Processing, and Handling of Combustible Particulate Solids and EN 61241, Electrical Apparatus for Use in the Presence of Combustible Dust for safe handling. Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Avoid contact with eyes. Product may generate heat if it comes in contact with water or water vapour. Prevent small spills and leakage to avoid slip hazard.
Static Accumulator: This material is a static accumulator.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
The type of container used to store the material may affect static accumulation and dissipation. Do not store in open or unlabelled containers. Keep container tightly closed and dry.
Transport information
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Marine transport (UN RTDG/IMDG)
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Additional transport information
Additional information
- Special provisions / remarks / other:
- LAND (ADR/RID): Not Regulated for Land Transport
INLAND WATERWAYS (ADNR/ADN): Not Regulated for Inland Waterways Transport
SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code
SEA (MARPOL 73/78 Convention - Annex II): Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not classified according to Annex II
AIR (IATA): Not Regulated for Air Transport
Exposure controls / personal protection
EXPOSURE CONTROLS
ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:
Adequate ventilation should be provided so that exposure limits are not exceeded. It is recommended that all dust control equipment such as local exhaust ventilation and material transport systems involved in handling of this product are designed and maintained to minimize dust generation and accumulation. Ensure that dust-handling systems (such as exhaust ducts, dusts collectors, vessels, and processing equipment) are designed to minimize the potential for dust ignition and prevent explosion propagation. For example, use explosion relief vents, an explosion suppression system or inert equipment internals. Additional examples of proper equipment include using only appropriately classified electrical equipment and powered industrial trucks.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
Particulate air-purifying respirator approved for dust or oil mist is recommended. European Committee for Standardization (CEN) standards EN 136, 140 and 405 provide respirator masks and EN 149 and 143 provide filter recommendations.
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:
No protection is ordinarily required under normal conditions of use.
Eye Protection: Chemical goggles are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:
No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping.
ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions.
ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:
Adequate ventilation should be provided so that exposure limits are not exceeded. It is recommended that all dust control equipment such as local exhaust ventilation and material transport systems involved in handling of this product are designed and maintained to minimize dust generation and accumulation. Ensure that dust-handling systems (such as exhaust ducts, dusts collectors, vessels, and processing equipment) are designed to minimize the potential for dust ignition and prevent explosion propagation. For example, use explosion relief vents, an explosion suppression system or inert equipment internals. Additional examples of proper equipment include using only appropriately classified electrical equipment and powered industrial trucks.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
Particulate air-purifying respirator approved for dust or oil mist is recommended. European Committee for Standardization (CEN) standards EN 136, 140 and 405 provide respirator masks and EN 149 and 143 provide filter recommendations.
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:
No protection is ordinarily required under normal conditions of use.
Eye Protection: Chemical goggles are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:
No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping.
ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions.
Stability and reactivity
REACTIVITY: See sub-sections below.
CHEMICAL STABILITY: Material is stable under normal conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur.
CONDITIONS TO AVOID: Excessive heat. High dust concentrations. High energy sources of ignition.
INCOMPATIBLE MATERIALS: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.
CHEMICAL STABILITY: Material is stable under normal conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur.
CONDITIONS TO AVOID: Excessive heat. High dust concentrations. High energy sources of ignition.
INCOMPATIBLE MATERIALS: Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.
Disposal considerations
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal.
WASTE TREATMENT METHODS
Recycle empty drums at an appropriate facility in accordance with current applicable laws and regulations, and product characteristics at time of disposal. Ensure drums are tightly sealed. Unused material should be returned for material reclaiming.
REGULATORY DISPOSAL INFORMATION
European Waste Code: 07 XX XX
NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s).
Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
WASTE TREATMENT METHODS
Recycle empty drums at an appropriate facility in accordance with current applicable laws and regulations, and product characteristics at time of disposal. Ensure drums are tightly sealed. Unused material should be returned for material reclaiming.
REGULATORY DISPOSAL INFORMATION
European Waste Code: 07 XX XX
NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s).
Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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