workplace-signs

Workplace Signs - minimum requirements & signs on containers and pipes

EU. Workplace Signage: Annexes I and III, Directive 92/58/EEC, last amended by Directive 2014/27/EU, 5 March 2014

This list contains hazardous substances based on Table 3 of Annex VI to the CLP Regulation 1272/2008/EC. According to the annexes to Directive 92/58/EEC, storage areas and containers containing chemical substances or mixtures that are classified as hazardous according to the CLP Regulation must be duly marked and/or labeled. Directive 92/58/EEC requires employers to ensure proper signage is posted in areas where hazards cannot be avoided or reduced.

RELEVANT LEGISLATION
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Index
080-004-00-7
Danger Symbols
Skull and crossbones

Health hazard


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Group members
This group of substance has the following member substances:
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Name EC / List no. CAS no. Association
Mersalyl 207-748-9 492-18-2 Expert judgement
Chloro[p-[(2-hydroxy-1-naphthyl)azo]phenyl]mercury 221-358-6 3076-91-3 Expert judgement
Methyl(pentachlorophenolato)mercury 227-596-7 5902-76-1 Expert judgement
Mercurate(1-), (4-carboxylatophenyl)hydroxy-, hydrogen (1:1) - 1126-48-3 Expert judgement
Di(acetato-O)anilinemercury 264-306-8 63549-47-3 Expert judgement
Diisopropylmercury - 1071-39-2 Expert judgement
2-hydroxy-5-(1,1,3,3-tetramethylbutyl)phenylmercury acetate 209-534-0 584-18-9 Expert judgement
[2,5-dichloro-3,6-dihydroxy-2,5-cyclohexadiene-1,4-dionato(2-)-O1,O6]mercury 251-672-9 33770-60-4 Expert judgement
Dipotassium tetracyanomercurate 209-735-3 591-89-9 Expert judgement
Iodomethylmercury 205-600-8 143-36-2 Expert judgement
(2',7'-dibromo-3',6'-dihydroxy-3-oxospiro[isobenzofuran-1(3H),9'-[9H]xanthen]-4'-yl)hydroxymercury 259-779-2 55728-51-3 Expert judgement
Bromomethylmercury 208-057-5 506-83-2 Expert judgement
Mersalyl acid 207-637-5 486-67-9 Expert judgement
Diphenylmercury 209-606-1 587-85-9 Expert judgement
Mercury, phenyl((2-phenyldiazenecarbothioic acid-kappaS) 2-phenylhydrazidato-kappaN2)- - 12406-51-8 Expert judgement
4-hydroxymercuric?phenyl sulfonic acid, sodium salt - 73548-15-9 Expert judgement
(2-carboxyphenyl)hydroxymercury 237-918-8 14066-61-6 Expert judgement
Hydrogen [3-[(α-carboxylato-o-anisoyl)amino]-2-hydroxypropyl]hydroxymercurate(1-) 247-796-8 26552-50-1 Expert judgement
(neodecanoato-O)phenylmercury 247-783-7 26545-49-3 Expert judgement
Di-p-tolylmercury 208-672-9 537-64-4 Expert judgement
Ethylhydroxymercury - 107-28-8 Expert judgement
2-methoxyethylmercury acetate 205-790-2 151-38-2 Expert judgement
Sodium [3-[[(3-carboxylatopropionamido)carbonyl]amino]-2-methoxypropyl]hydroxymercurate(1-) 231-532-3 7620-30-6 Expert judgement
Hydrogen μ-hydroxy[μ-[orthoborato(3-)-O:O']]diphenyldimercurate(1-) 304-637-8 94277-53-9 Expert judgement
BMC 663-974-1 543-63-5 Expert judgement
Mercury(1+) trifluoroacetate 220-875-4 2923-15-1 Expert judgement
2-ethoxyethylmercury chloride 204-670-7 124-01-6 Expert judgement
Mercaptomerin sodium 244-298-2 21259-76-7 Expert judgement
Mercury bis(4-chlorobenzoate) 239-548-2 15516-76-4 Expert judgement
Mercury, (acetato-O)(methylphenyl)- - 1300-78-3 Expert judgement
Phenylmercury propionate 203-094-3 103-27-5 Expert judgement
3-(Acetoxymercuri)pyridine - 102-99-8 Expert judgement
(2-ethylhexanoato)phenylmercury 236-326-7 13302-00-6 Expert judgement
Butanoic acid, 4-((((2-methoxypropyl)amino)carbonyl)amino)-4-oxo-, mercury complex - 72-58-2 Expert judgement
Amylmercury chloride - 544-15-0 Expert judgement
Chloropropylmercury - 2440-40-6 Expert judgement
(4-((4-(Dimethylamino)phenyl)azo)phenyl)mercuric acetate 631-561-5 19447-62-2 Expert judgement
Thiomersal 200-210-4 54-64-8 Expert judgement
Mercury, hydroxy(hydroxynitrophenyl)-, monosodium salt - 1300-34-1 Expert judgement
Hydrogen triiodomercurate(1-), compound with 3-methyl-3H-benzothiazol-2-imine (1:1) 276-613-4 72379-35-2 Expert judgement
Mercury, [N-(2-methylphenyl)benzenesulfonamidato-N]phenyl- - 2440-34-8 Expert judgement
Sodium timerfonate 227-741-4 5964-24-9 Expert judgement
Mercury difulminate 211-057-8 628-86-4 Expert judgement
Mercury, iodophenyl- 664-429-0 823-04-1 Expert judgement
Naphthenic acids, mercury salts 215-651-8 1336-96-5 Expert judgement
[μ-[(oxydiethylene but-2-enedioato)(2-)]]diphenyldimercury 301-791-8 94070-92-5 Expert judgement
Chloro-o-tolylmercury 220-469-7 2777-37-9 Expert judgement
Phenylmercury dimethyldithiocarbamate 251-026-6 32407-99-1 Expert judgement
Phenyl(quinolin-8-olato-N1,O8)mercury 238-316-8 14354-56-4 Expert judgement
Bromo(2-hydroxypropyl)mercury 242-613-8 18832-83-2 Expert judgement
Ethanethiolmercury chloride - 1785-43-9 Expert judgement
Ethyliodomercury 219-471-0 2440-42-8 Expert judgement
2-ethoxyethylmercury acetate 204-678-0 124-08-3 Expert judgement
Tris(ethylmercury) phosphate 218-790-2 2235-25-8 Expert judgement
2-Chloromercuri-4-nitrophenol - 24579-90-6 Expert judgement
Otimerate sodium 240-572-0 16509-11-8 Expert judgement
Phenylmercury acetate 200-532-5 62-38-4 Expert judgement
Mercury(2+) (9Z,12Z)-octadeca-9,12-dienoate 231-814-6 7756-49-2 Expert judgement
Mercury dibenzoate 209-499-1 583-15-3 Expert judgement
Sodium 4-chloromercuriobenzoate 221-700-4 3198-04-7 Expert judgement
Chlormerodrin 200-530-4 62-37-3 Expert judgement
(maleoyldioxy)bis[phenylmercury] 220-286-2 2701-61-3 Expert judgement
Mercury acetate 209-766-2 592-63-2 Expert judgement
Dihydrogen [orthoborato(3-)-O]phenylmercurate(2-) 203-068-1 102-98-7 Expert judgement
Phenylmercury stearate 203-217-0 104-59-6 Expert judgement
Tetrakis(acetato-O)[μ4-(3',6'-dihydroxy-3-oxospiro[isobenzofuran-1(3H),9'-[9H]xanthene]-2',4',5',7'-tetrayl)]tetramercury 259-075-5 54295-90-8 Expert judgement
Diphenyl[μ-[(tetrapropenyl)succinato(2-)-O:O']]dimercury 248-355-2 27236-65-3 Expert judgement
Diiodo(5-iodopyridin-2-amine-N1)mercury 298-602-3 93820-20-3 Expert judgement
[2-ethylhexyl hydrogen maleato-O']phenylmercury 248-559-1 27605-30-7 Expert judgement
[salicylato(2-)-O1,O2]mercury 227-760-8 5970-32-1 Expert judgement
[2,2',2''-nitrilotri(ethanol)-N,O,O',O'']phenylmercury lactate 245-581-3 23319-66-6 Expert judgement
Bis(trichloromethyl)mercury 229-867-5 6795-81-9 Expert judgement
1-cyano-3-(methylmercurio)guanidine 207-935-5 502-39-6 Expert judgement
(acetato-O)[3-(chloromethoxy)propyl-C,O]mercury 227-719-4 5954-14-3 Expert judgement
Mercury, diheptyl- - 51622-02-7 Expert judgement
Disuccinimidomercury 209-537-7 584-43-0 Expert judgement
Benzenesulfonic acid, 4-hydroxy-3,5-diiodo-, mercury(2+) salt (1:1) - 515-43-5 Expert judgement
Mercury, (3-(2,5-dioxo-1-pyrrolidinyl)-2-methoxypropyl)hydroxy-, compd. with 3,7-dihydro-1,3-dimethyl-1H-purine-2,6-dione (1:1) - 747-23-9 Expert judgement
Bis(5-oxo-DL-prolinato-N1,O2)mercury 304-523-8 94276-38-7 Expert judgement
Mercury(1+) ethyl sulphate 275-904-3 71720-55-3 Expert judgement
Mercury distearate 211-458-8 645-99-8 Expert judgement
Hydrargaphen 238-107-1 14235-86-0 Expert judgement
Phenylmercury hydroxide 202-866-7 100-57-2 Expert judgement
Phenylmercury chloride 202-865-1 100-56-1 Expert judgement
[N-(2-methylphenyl) benzenesulfone amidate-N] phenyl mercury - 54129-03-2 Expert judgement
Diethylmercury 211-000-7 627-44-1 Expert judgement
[μ-[(oxydiethylene phthalato)(2-)]]diphenylmercury 301-792-3 94070-93-6 Expert judgement
Bis(ethylmercuri)phosphate - 2440-45-1 Expert judgement
(dihydroxyphenyl)phenylmercury 248-426-8 27360-58-3 Expert judgement
Mercury, (acetato-kappaO)(3-(chloromethoxy-kappaO)propyl-kappaC)- - 1319-86-4 Expert judgement
Di(phenylmercury) dodecylsuccinate - 24806-32-4 Expert judgement
Benzenesulfonic acid, p-hydroxy-, mercury deriv., disodium salt - 535-55-7 Expert judgement
Methylmercury benzoate 222-834-6 3626-13-9 Expert judgement
Di-sec-butylmercury - 691-88-3 Expert judgement
Dimercury di(acetate) 211-161-3 631-60-7 Expert judgement
(Trifluoromethyl)mercuric bromide - 421-09-0 Expert judgement
Ethylmercury chloride 203-478-0 107-27-7 Expert judgement
(3-chloro-4-hydroxyphenyl)mercury;hydrate - 538-04-5 Expert judgement
Mercurous gluconate - 63937-14-4 Expert judgement
(oleato)phenylmercury 203-218-6 104-60-9 Expert judgement
Chloro(trans-2-methoxycyclooctyl)mercury - 5185-84-2 Expert judgement
2-(ethylmercuriothio)benzoic acid 205-719-5 148-61-8 Expert judgement
Octadecanoic acid, mercury(1+) salt - 86320-46-9 Expert judgement
(acetato-O)methylmercury 203-547-5 108-07-6 Expert judgement
Sodium 4-hydroxymercuriobenzoate 205-340-5 138-85-2 Expert judgement
Mercury hydrogen cyclohexanebutyrate 263-665-8 62638-02-2 Expert judgement
[(2-hydroxyethyl)amino]phenylmercury acetate 263-211-9 61792-06-1 Expert judgement
Mercury bis(trifluoroacetate) 236-250-4 13257-51-7 Expert judgement
Bis(5-oxo-L-prolinato-N1,O2)mercury 305-388-8 94481-62-6 Expert judgement
Bis(lactato-O1,O2)mercury 242-667-2 18917-83-4 Expert judgement
Mercury bis(2-ethylhexanoate) 236-113-9 13170-76-8 Expert judgement
Cyclopentanecarboxylic acid, 3-(((3-mercapto-2-methoxypropyl)amino)carbonyl)-2,2,3-trimethyl-, mercury complex - 76-31-3 Expert judgement
Phenylmercury salicylate 248-828-3 28086-13-7 Expert judgement
N-(ethylmercurio)toluene-4-sulphonanilide 208-231-0 517-16-8 Expert judgement
[naphthoato(1-)-O]phenylmercury 250-736-3 31632-68-5 Expert judgement
Phenylmercury benzoate 202-331-8 94-43-9 Expert judgement
Dibutylrtut - 629-35-6 Expert judgement
(metaborato-O)phenylmercury 250-518-8 31224-71-2 Expert judgement
Mercury, bis(3-fluorophenyl)- - 1961-02-0 Expert judgement
[μ-[orthoborato(2-)-O:O']]diphenyldimercury 228-465-7 6273-99-0 Expert judgement
methylmercury nitrile - 2597-97-9 Expert judgement
Di-o-tolylmercury 210-499-9 616-99-9 Expert judgement
1H-Tetrazole, 5-nitro-, mercury(2+) salt - 60345-95-1 Expert judgement
methylmercury salts 694-823-8 22967-92-6 Expert judgement
[benzoato(2-)-C2,O1]mercury 227-228-5 5722-59-8 Expert judgement
Hydrogen [metasilicato(2-)-O](2-methoxyethyl)mercurate(1-) 264-920-6 64491-92-5 Expert judgement
Lactatophenylmercury 204-560-9 122-64-5 Expert judgement
Chloro-2-thienylmercury 227-481-1 5857-39-6 Expert judgement
Chloro-m-tolylmercury 227-722-0 5955-19-1 Expert judgement
Mercurobutol 207-869-7 498-73-7 Expert judgement
Chloromercuriferrocene 631-381-7 1273-75-2 Expert judgement
Bis(ethylthio)mercury - 811-50-7 Expert judgement
2-methoxyethylmercury chloride 204-659-7 123-88-6 Expert judgement
2-Acetoxymercurio-4-nitrophenol - 63468-53-1 Expert judgement
(bromodichloromethyl)phenylmercury 221-961-4 3294-58-4 Expert judgement
4-aminophenylmercury acetate 228-497-1 6283-24-5 Expert judgement
Bromoethylmercury 203-477-5 107-26-6 Expert judgement
Mercury dioleate 214-741-4 1191-80-6 Expert judgement
(2,3,4,5,6-pentachlorophenoxy)-phenylmercury - 1142-64-9 Expert judgement
mercury, chloro(3-hydroxyphenyl)- - 70538-27-1 Expert judgement
Iodo(iodomethyl)mercury 205-485-4 141-51-5 Expert judgement
Merbromin 204-933-6 129-16-8 Expert judgement
Meralein sodium 224-498-6 4386-35-0 Expert judgement
Phenylmercury nitrate 200-242-9 55-68-5 Expert judgement
Bis(acetato-O)[μ-(3',6'-dihydroxy-3-oxospiro[isobenzofuran-1(3H),9'-[9H]xanthene]-2',7'-diyl)]dimercury 222-673-1 3570-80-7 Expert judgement
Mercury di(acetate) 216-491-1 1600-27-7 Expert judgement
Mercury, iodo(trifluoromethyl)- - 421-11-4 Expert judgement
(2-carboxy-m-tolyl)hydroxymercury, monosodium salt 258-195-5 52795-88-7 Expert judgement
Phenyl(trichloromethyl)mercury 221-960-9 3294-57-3 Expert judgement
Mercury dithizonate 621-496-0 14783-59-6 Expert judgement
Mercury succinate 209-656-4 589-65-1 Expert judgement
Chloro(hydroxyphenyl)mercury 215-308-2 1320-80-5 Expert judgement
Mercury, (3-((((3-carboxy-1-oxopropyl)amino)carbonyl)amino)-2-methoxypropyl)hydroxy- - 140-20-5 Expert judgement
(Pentafluorophenyl)mercury - 973-17-1 Expert judgement
Mercury, chloro(4-((2,4-dinitrophenyl)amino)phenyl)- - 15785-93-0 Expert judgement
Dipropyl mercury - 628-85-3 Expert judgement
Mercury, (acetato)pyridyl- (8CI) - 1334-77-6 Expert judgement
6-methyl-3-nitrobenzoxamercurete 205-112-5 133-58-4 Expert judgement
Mercurate(1-), [dodecenylbutanedioato(2-)-O']phenyl-, hydrogen 304-575-1 94276-88-7 Expert judgement
Bromophenylmercury 214-760-8 1192-89-8 Expert judgement
Hydroxymercury nitrile - 31065-88-0 Expert judgement
basic phenylmercury nitrate 620-403-0 8003-05-2 Expert judgement
p-tolylmercury chloride 208-716-7 539-43-5 Expert judgement
Mercury, (nitrate-O)(trifluoromethyl)- - 461-40-5 Expert judgement
Methylmercury hydroxide 214-667-2 1184-57-2 Expert judgement
[μ-[[4,4'-(oxydiethylene) bis(dodecenylsuccinato)](2-)]]diphenyldimercury 299-418-6 93882-20-3 Expert judgement
Dimethyl[μ-[sulphato(2-)-O:O']]dimercury 223-288-1 3810-81-9 Expert judgement
Mercury, bis(phenylmethyl)- 677-698-4 780-24-5 Expert judgement
Phenylmercuric phthalate 664-337-0 84-70-8 Expert judgement
Mercury(2+) tetrakis(thiocyanato-N)cobaltate(2-) 248-602-4 27685-51-4 Expert judgement
Chloromethylmercury 204-064-2 115-09-3 Expert judgement
2-chloromercuriophenol 201-962-6 90-03-9 Expert judgement
[μ-[metasilicato(2-)-O:O]]bis(2-methoxyethyl)dimercury 242-997-7 19367-79-4 Expert judgement
Mercuderamide 208-371-2 525-30-4 Expert judgement
Lactic acid, mercury(2+) salt (2:1) (8CI) - 814-82-4 Expert judgement
Diiodobis(5-iodopyridin-2-amine)mercury dihydroiodide 264-100-8 63325-16-6 Expert judgement
(acetato-O)diamminephenylmercury 269-247-1 68201-97-8 Expert judgement
Bis[(trimethylsilyl)methyl]mercury 236-315-7 13294-23-0 Expert judgement
Mercury(2+) chloroacetate 247-925-8 26719-07-3 Expert judgement
Bis(acetato-O)[μ-[1,3-dioxane-2,5-diylbis(methylene)-C:C',O,O']]dimercury 281-717-8 84029-43-6 Expert judgement
Mercurate(2-), tetraiodo-, copper(2+) (1:1), (T-4)- - 27228-67-7 Expert judgement
4-chloromercuriobenzoic acid 200-442-6 59-85-8 Expert judgement
Turpentine, Venice, sulfurized, reaction products with hydrogen tetrachloroaurate(-1), sulfurized turpentine oil and mercurous nitrate, mixed with mercurous oxide 293-784-0 91082-69-8 Expert judgement
(phenylmercurio)urea 218-909-8 2279-64-3 Expert judgement
Amminephenylmercury(1+) acetate 245-006-6 22450-90-4 Expert judgement
Phenyl(tribromomethyl)mercury 221-963-5 3294-60-8 Expert judgement
4-Chloromercuribenzenesulfonate - 554-77-8 Expert judgement
Mercury, chloropyridinyl- - 1334-75-4 Expert judgement
Disodium tetra(cyano-C)mercurate(2-) 239-766-8 15682-88-9 Expert judgement
4-(Chloromercuri)benzenesulfonic acid monosodium salt 683-356-5 14110-97-5 Expert judgement
Bis[(+)-lactato]mercury 251-657-7 33724-17-3 Expert judgement
(lactato-O1,O2)mercury 242-673-5 18918-06-4 Expert judgement
Trimercury biscitrate 242-096-9 18211-85-3 Expert judgement
(acetato-O)ethylmercury 203-688-2 109-62-6 Expert judgement
4-Chloromercuriphenol - 623-07-4 Expert judgement