Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Oxidising properties

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Administrative data

Endpoint:
oxidising liquids
Type of information:
other: expert statement
Adequacy of study:
supporting study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Study performed according to standard guidelines with acceptable restrictions.

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2012
Report date:
2012

Materials and methods

Test material

Constituent 1
Chemical structure
Reference substance name:
Phosphinic acid
EC Number:
228-601-5
EC Name:
Phosphinic acid
Cas Number:
6303-21-5
Molecular formula:
H3O2P
IUPAC Name:
phosphinic acid

Results and discussion

Test results (Oxidising liquids)
Remarks on result:
other: not oxidising

Applicant's summary and conclusion

Interpretation of results:
GHS criteria not met
Conclusions:
Phosphinic acid is well known to be a strong reducing agent. Moreover its classification according to regulation on transport of dangerous goods is yet established (Class 8, UN N°3264: corrosive liquid, acidic, inorganic) and confirms that phosphinic acid 60% is unable to show an exothermic reaction with a fuel.
Executive summary:

Expert statement (as cited in the report):

As stated Annex VII, point 7.13 of the REACH regulation No 1907/2006 “This test need not to be performed when examination of the structural formula establishes that the substance is incapable of reacting exothermically with a combustible material.”

According to the chemical structure and the fact that it is in solution in water as well as the strong reduction potential of the solid test substance it is possible to exclude beyond reasonable doubt that this substance has oxidising properties.

The test substance is classified in the class 8 N° UN 3264 (corrosive liquid, acidic, inorganic) according to UN regulation on transport of dangerous goods confirming the conclusion based on the chemical structure regarding the absence of oxidising properties.