pregnant-women-protection

Protection of Pregnant and Breastfeeding Workers Directive, Annex I+II

EU. Chemical Agents: Annexes I & II, Directive 92/85/EEC on Pregnant Workers, 28 November 1992 (updated by table 3 of Annex VI to CLP, 5 October 2018)

This list contains a non-exhaustive inventory of substances to which pregnant workers and workers who have recently given birth or are breastfeeding may not be exposed. Employers are obligated to prevent the exposure of these workers to any agents that may have adverse health effects on either mother or child. The inventory originates from Table 3 of Annex VI to the CLP.

RELEVANT LEGISLATION
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salts of benzidine

EC / List no: - CAS no: -
CLP (1272/2008) CMRs
Carc. 1A
ECCAR Directive 2004/37/EC
yes

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Group members
This group of substance has the following member substances:
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Name EC / List no. CAS no. Association
Disodium 5-[[4'-[[2,4-diamino-5-[(4-sulphophenyl)azo]phenyl]azo][1,1'-biphenyl]-4-yl]azo]salicylate 223-294-4 3811-71-0 Expert judgement
benzidine, bis(3,5-dinitrobenzoate) - 92415-52-6 Expert judgement
(1,1'-Biphenyl)-4,4'-diamine, dihydrofluoride - 41766-73-8 Expert judgement
Disodium 7-hydroxy-8-[[4'-[[4-[[(p-tolyl)sulphonyl]oxy]phenyl]azo][1,1'-biphenyl]-4-yl]azo]naphthalene-1,3-disulphonate 222-655-3 3567-65-5 Expert judgement
Benzidine, hydrochloride - 14414-68-7 Expert judgement
Salts of benzidine - - Expert judgement (ECHA)
Dipotassium O,O'-(4,4'-diaminobiphenyl-3,3'-ylene)diglycollate 277-771-7 74220-10-3 Expert judgement
benzidine, mono(2-hydroxy-3,5-dinitrobenzoate) - 78577-03-4 Expert judgement
Disodium 5-[[4'-[[2,6-diamino-3-methyl-5-[(4-sulphonatophenyl)azo]phenyl]azo][1,1'-biphenyl]-4-yl]azo]-3-methylsalicylate 228-829-5 6360-54-9 Expert judgement
Hexasodium 5,5'-[(3,7-disulphonato-1,5-naphthylene)bis[azo(6-hydroxy-3,1-phenylene)azo[6(or 7)-sulphonato-4,1-naphthylene]azo[1,1'-biphenyl]-4,4'-diylazo]]bis(salicylate) 232-397-3 8014-91-3 Expert judgement
Disodium 4,4'-diaminobiphenyl-2,2'-disulfonate - 27336-24-9 Expert judgement
Disodium 5-[[4'-[(7-amino-1-hydroxy-3-sulphonato-2-naphthyl)azo][1,1'-biphenyl]-4-yl]azo]salicylate 219-391-6 2429-82-5 Expert judgement
Tetrasodium 5-[[4'-[[2,6-diamino-3-[[8-hydroxy-3,6-disulphonato-7-[(4-sulphonato-1-naphthyl)azo]-2-naphthyl]azo]-5-tolyl]azo][1,1'-biphenyl]-4-yl]azo]salicylate 219-390-0 2429-81-4 Expert judgement
2,[?]-Naphthalenedisulfonic acid, 4-[[][[]4-[[](4-amino-1-naphthalenyl)azo]-1-naphthalenyl]azo]-, disodium salt 616-837-5 8004-59-9 Expert judgement
(1,1'-Biphenyl)-4,4'-diamine, dihydriodide - 75534-79-1 Expert judgement
3,3'-dimethoxybenzidine 204-355-4 119-90-4 Expert judgement
Disodium 5-[[4'-[[4,5-dihydro-3-methyl-5-oxo-1-(4-sulphonatophenyl)-1H-pyrazol-4-yl]azo][1,1'-biphenyl]-4-yl]azo]salicylate 236-106-0 13164-93-7 Expert judgement
(1,1'-Biphenyl)-4,4'-diamine, monoacetate - 52754-64-0 Expert judgement
Trisodium 5-[[4'-[[8-amino-1-hydroxy-7-[(p-nitrophenyl)azo]-3,6-disulphonato-2-naphthyl]azo]-4-biphenyl]azo]salicylate 226-545-6 5422-17-3 Expert judgement
1,1'-Biphenyl-4,4'-diamine, monoperchlorate - 29806-76-6 Expert judgement
Disodium 4-amino-5-hydroxy-3-[[4'-[(4-hydroxyphenyl)azo][1,1'-biphenyl]-4-yl]azo]-6-(phenylazo)naphthalene-2,7-disulphonate 222-835-1 3626-28-6 Expert judgement
Disodium 5-[[4'-[(1-amino-4-sulphonato-2-naphthyl)azo][1,1'-biphenyl]-4-yl]azo]salicylate 219-387-4 2429-79-0 Expert judgement
3,3'-dichlorobenzidine 202-109-0 91-94-1 Expert judgement
[1,1'-Biphenyl]-4,4'-diamine, perchlorate - 38668-12-1 Expert judgement
benzidine, mono(3,5-dinitrobenzoate) - 78577-08-9 Expert judgement
Disodium 5-[[4'-[(2-amino-8-hydroxy-6-sulphonato-1-naphthyl)azo][1,1'-biphenyl]-4-yl]azo]salicylate 219-393-7 2429-84-7 Expert judgement
Disodium 4-amino-3-[[4'-[(2,4-diamino-5-methylphenyl)azo][1,1'-biphenyl]-4-yl]azo]-5-hydroxy-6-(phenylazo)naphthalene-2,7-disulphonate 219-392-1 2429-83-6 Expert judgement
Tetrasodium 3,3'-[(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[5-amino-4-hydroxynaphthalene-2,7-disulphonate] 200-786-7 72-57-1 Expert judgement
Disodium 4-amino-5-hydroxy-6-[[4'-[(4-hydroxyphenyl)azo][1,1'-biphenyl]-4-yl]azo]-3-[(4-nitrophenyl)azo]naphthalene-2,7-disulphonate 224-376-2 4335-09-5 Expert judgement
Disodium 4-amino-3-[[4'-[(2,4-diaminophenyl)azo][1,1'-biphenyl]-4-yl]azo]-5-hydroxy-6-(phenylazo)naphthalene-2,7-disulphonate 217-710-3 1937-37-7 Expert judgement
3,3'-dichlorobenzidine dihydrochloride 210-323-0 612-83-9 Expert judgement
4,4'-bi-o-toluidine 204-358-0 119-93-7 Expert judgement
Benzidine dihydrochloride 208-519-6 531-85-1 Expert judgement
Disodium 3,3'-[[1,1'-biphenyl]-4,4'-diylbis(azo)]bis(4-aminonaphthalene-1-sulphonate) 209-358-4 573-58-0 Expert judgement
[[1,1'-biphenyl]-4,4'-diyl]diammonium sulphate 208-520-1 531-86-2 Expert judgement
(1,1'-Biphenyl)-ar,ar',4,4'-tetramine - 66836-18-8 Expert judgement
Benzidine 202-199-1 92-87-5 Expert judgement (ECHA)
[2,2'-dichloro[1,1'-biphenyl]-4,4'-diyl]diammonium sulphate 274-338-4 70146-07-5 Expert judgement
benzidine, bis(2-hydroxy-3,5-dinitrobenzoate) - 92415-34-4 Expert judgement
4,4'-bi-o-toluidine dihydrochloride 210-322-5 612-82-8 Expert judgement
benzidine, phosphate (1:1) - 66907-22-0 Expert judgement
1,3,6-Naphthalenetrisulfonic acid, 8-hydroxy-7-((4'-((2-hydroxy-1-naphthalenyl)azo)-(1,1'-biph 613-540-2 6426-67-1 Expert judgement
Tetrasodium 3,3'-[[1,1'-biphenyl]-4,4'-diylbis(azo)]bis[5-amino-4-hydroxynaphthalene-2,7-disulphonate] 220-012-1 2602-46-2 Expert judgement
Disodium [5-[[4'-[[2,6-dihydroxy-3-[(2-hydroxy-5-sulphophenyl)azo]phenyl]azo][1,1'-biphenyl]-4-yl]azo]salicylato(4-)]cuprate(2-) 240-221-1 16071-86-6 Expert judgement
Benzidine acetate 252-984-8 36341-27-2 Expert judgement
(1,1'-Biphenyl)-4,4'-diamine, monohydrochloride - 75752-15-7 Expert judgement
Disodium 5-[[4'-[[2,4-dihydroxy-3-[(4-sulphonatophenyl)azo]phenyl]azo][1,1'-biphenyl]-4-yl]azo]salicylate 220-768-2 2893-80-3 Expert judgement
Nickel(2+), ((1,1'-biphenyl)-4,4'-diamine-N)- - 67632-50-2 Expert judgement
Benzidine diperchlorate - 41195-21-5 Expert judgement
Disodium 8-[[4'-[(4-ethoxyphenyl)azo][1,1'-biphenyl]-4-yl]azo]-7-hydroxynaphthalene-1,3-disulphonate 222-560-7 3530-19-6 Expert judgement
Disodium 5-[[4'-[[1-hydroxy-7-(phenylamino)-3-sulphonato-2-naphthyl]azo][1,1'-biphenyl]-4-yl]azo]salicylate 222-450-9 3476-90-2 Expert judgement
Benzidine sulphate 244-236-4 21136-70-9 Expert judgement