Benzamide, N-[1-cyano-2-[5-cyano-2-(trifluoromethyl)phenoxy]-1-methylethyl]-4-[(trifluoromethyl)thio]-

Guidance on Safe Use

First-aid measures

Inhalation: Move exposed person to fresh air. Keep person warm and at rest.

If not breathing, if breathing is irregular or if respiratory arrest

occurs, provide artificial respiration or oxygen by trained personnel.

Get medical attention if adverse health effects

persist or are severe. If unconscious, place in recovery position and

get medical attention immediately. Maintain an open airway.

Loosen tight clothing such as a collar, tie, belt or waistband.

Ingestion: Wash out mouth with water. Move exposed person to fresh air.

Keep person warm and at rest. If material has been swallowed and

the exposed person is conscious, give small quantities of water to

drink. Stop if the exposed person feels sick as vomiting may be

dangerous. Do not induce vomiting unless directed to do so by

medical personnel. If vomiting occurs, the head should be kept low

so that vomit does not enter the lungs. Get medical attention if

adverse health effects persist or are severe. Never give anything by

mouth to an unconscious person. If unconscious, place in recovery

position and get medical attention immediately. Maintain an open

airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Skin contact: Flush contaminated skin with plenty of water. Remove

contaminated clothing and shoes. Continue to rinse for at least 10

minutes. Get medical attention. In the event of any complaints or

symptoms, avoid further exposure. Wash clothing before reuse.

Clean shoes thoroughly before reuse.

Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the

upper and lower eyelids. Check for and remove any contact lenses.

Continue to rinse for at least 10 minutes. Get medical attention.

Fire-fighting measures

Suitable extinguishing media: Use dry chemical, CO2, water spray (fog) or foam.

Not suitable extinguishing media: None known

Hazards arising from the substance: No specific fire- or explosion hazard

Hazardous combustion products: No specific data

Special precautions for fire-fighters: Promptly isolate the scene by removing all persons from the vicinity

of the incident if there is a fire. No action shall be taken involving

any personal risk or without suitable training.

Special protective equipment for fire-fighters:Fire-fighters should wear appropriate protective equipment and selfcontained breathing apparatus (SCBA) with a full face-piece operating in positive pressure mode.

Accidental release measures

Personal precautions: No action shall be taken involving any personal risk or without

suitable training. Keep unnecessary and unprotected personnel from entering. Do not touch or walk

through spilled material. Provide adequate ventilation. Put on appropriate personal protective

equipment

Environmental precautions: Avoid dispersal of spilled material and runoff and contact with soil,

waterways, drains and sewers. Inform the relevant authorities if the

product has caused environmental pollution (sewers, waterways, soil

or air).

Large spill: Move containers from spill area. Prevent

entry into sewers, water courses, basements or confined areas.

Contain and collect spillage and place in container for disposal according to local regulations.

Small spill: Move containers from spill area. Prevent

entry into sewers, water courses, basements or confined areas.

Contain and collect spillage and place in container for disposal according to local regulations.

Handling and storage

Manufacture and use of this chemical intermediate takes place under strictly controlled conditions, as described in Art. 17/18 REACH. The substance is rigorously contained during manufacturing and use and appropriate risk management measures including PPE (i.g. during charging or sampling) are applied.Occupational exposure is reduced to a minimum and well controlled by measurements. A management system covering all general aspects of a chemical production is in place, especially cleaning and maintenance of plants and equipment. An authorisation scheme based on instructions covering the whole process ensures that only trained and authorised staff handles the substance.

Handling: Put on appropriate personal protective equipment.

Eating, drinking and smoking should be prohibited in areas where

this material is handled, stored and processed. Workers should

wash hands and face before eating, drinking and smoking.  Do not get in eyes or

on skin or clothing.  Do not ingest.  Keep in the original container

or an approved alternative made from a compatible material, kept

tightly closed when not in use.  Do not reuse empty containers. Empty containers contain residues which may be dangerous.

Storage: Store in accordance with local regulations.  Store in original container protected from direct

sunlight in a dry, cool and well-ventilated area, away from

incompatible materials and food and drink.

Keep container tightly closed and sealed until ready for use.

Containers that have been opened must be carefully resealed and

kept upright to prevent leakage. Do not store in unlabeled

containers. Use appropriate containment to avoid environmental

contamination.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

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Shipping

Labels:

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Special provisions / remarks

Remarks:

No dangerous cargo
Keep away from cargo suspectible to odour; keep away from foodstuffs, acids, and alkalis.
Keep dry
Heat sensitive from 25 °C

Inland waterway transport (UN RTDG/ADN(R))

UN number:

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Shipping

Labels:

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Special provisions / remarks

Remarks:

No dangerous cargo
Keep away from cargo suspectible to odour; keep away from foodstuffs, acids, and alkalis.
Keep dry
Heat sensitive from 25 °C

Marine transport (UN RTDG/IMDG)

UN number:

--

Shipping information

Proper shipping name and description:

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Chemical name:

--

Labels:

--

Special provisions / remarks

Remarks:

No dangerous cargo
Keep away from cargo suspectible to odour; keep away from foodstuffs, acids, and alkalis.
Keep dry
Heat sensitive from 25 °C

Air transport (UN RTDG/ICAO/IATA)

UN number:

--

Shipping information

Proper shipping name and description:

--

Chemical name:

--

Labels:

--

Special provisions / remarks

Remarks:

No dangerous cargo
Keep away from cargo suspectible to odour; keep away from foodstuffs, acids, and alkalis.
Keep dry
Heat sensitive from 25 °C

Additional transport information

Additional information

Special provisions / remarks / other:

The producer uses packaging for the product, which meets the requirements for products with a hazard potential as far as
tightness and stability are concerned. Consequently transport is possible without increased danger as long as attention is paid to the usual
measures such as stack height, protection against falling and correct labelling. In case of partially fractured containers, these must be kept closed carefully on any transport, in order to prevent spillage.

Exposure controls / personal protection

Exposure limit values: Not available

Recommended monitoring procedures:

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to

determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective

equipment. Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to

chemical agents and national guidance documents for methods for the determination of hazardous substances.

Risk management measures/Occupational exposure controls

Technical measures: If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls tp keep worker exposure below any recommended or statutory limits.

Personal protection measures:

Respiratory protection: Use a properly fitted, air-purifying or air-fed respirator complying with

an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or

anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Recommended: Full mask with type ABEK filter.

Hand protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical

products if a risk assessment indicates this is necessary. After contamination with product change the gloves immediately and

dispose of them according to relevant national and local regulations. <1 hour breakthrough time : Polyvinyl chloride - PVC or Rubber gloves.

Eye protection: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid

exposure to liquid splashes, mists, gases or dusts. Recommended: safety glasses with side-shields.

Skin protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and

should be approved by a specialist before handling this product.

Hygiene measures: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory

and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated

clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Environmental exposure controls: Emissions from ventilation or work process equipment should be checked to ensure they comply with the

requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process

equipment will be necessary to reduce emissions to acceptable levels.

Stability and reactivity

Stability and reactivity: The product is stable

Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid: In the case of dusty organic products the possibility of a dust explosion should always be considered. No dangerous reaction when usedand handled as directed.

Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Disposal considerations

Methods of disposal: Examine possibilities for re-utilisation. Product residues and uncleaned empty containers should be packaged, sealed,

labelled, and disposed of or recycled according to relevant national and local regulations. Where large quantities are concerned, consult the

supplier. When uncleaned empty containers are passed on, the recipient must be warned of any possible hazard that may be caused by residues.

For disposal within the EC, the appropriate code according to the European Waste List (EWL) should be used.

It is among the tasks of the polluter to assign the waste to waste codes specific to industrial sectors and processes according to the European

Waste List (EWL).

Hazardous waste: The classification of the product does not meet the criteria for a hazardous waste according to EC directive 91/689/EC.