Registration Dossier
Registration Dossier
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EC number: 304-038-1 | CAS number: 94233-08-6
Guidance on Safe Use
Guidance on Safe Use
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Administrative data
First-aid measures
EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem persists, seek medical advice.
SKIN: Remove contaminated clothing. Wash immediately with plenty of water. If irritation persists, get medical advice/attention. Wash contaminated clothing before using it again.
INHALATION: Remove to open air. In the event of breathing difficulties, get medical advice/attention immediately.
INGESTION: Get medical advice/attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious person, unless authorised by a doctor.
SKIN: Remove contaminated clothing. Wash immediately with plenty of water. If irritation persists, get medical advice/attention. Wash contaminated clothing before using it again.
INHALATION: Remove to open air. In the event of breathing difficulties, get medical advice/attention immediately.
INGESTION: Get medical advice/attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious person, unless authorised by a doctor.
Fire-fighting measures
Extinguishing media
SUITABLE EXTINGUISHING EQUIPMENT
The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray.
UNSUITABLE EXTINGUISHING EQUIPMENT
None in particular.
Special hazards arising from the substance or mixture
HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
Do not breathe combustion products.
Advice for firefighters
GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water used for extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).
SUITABLE EXTINGUISHING EQUIPMENT
The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray.
UNSUITABLE EXTINGUISHING EQUIPMENT
None in particular.
Special hazards arising from the substance or mixture
HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
Do not breathe combustion products.
Advice for firefighters
GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water used for extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).
Accidental release measures
Personal precautions, protective equipment and emergency procedures
If there are no contraindications, spray powder with water to prevent the formation of dust. Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency procedures.
Environmental precautions
The product must not penetrate into the sewer system or come into contact with surface water or ground water.
Methods and material for containment and cleaning up
Collect the leaked product and place it in containers for recovery or disposal. If the product is flammable, use explosion-proof equipment. If there are no contraindications, use jets of water to eliminate product residues. Make sure the leakage site is well aired. Evaluate the compatibility of the container to be used.
If there are no contraindications, spray powder with water to prevent the formation of dust. Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency procedures.
Environmental precautions
The product must not penetrate into the sewer system or come into contact with surface water or ground water.
Methods and material for containment and cleaning up
Collect the leaked product and place it in containers for recovery or disposal. If the product is flammable, use explosion-proof equipment. If there are no contraindications, use jets of water to eliminate product residues. Make sure the leakage site is well aired. Evaluate the compatibility of the container to be used.
Handling and storage
Precautions for safe handling
Avoid leakage of the product into the environment. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in which people eat.
Conditions for safe storage, including any incompatibilities
Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away from any incompatible materials.
Avoid leakage of the product into the environment. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in which people eat.
Conditions for safe storage, including any incompatibilities
Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away from any incompatible materials.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Exposure controls
As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well aired through effective local aspiration. When choosing personal protective equipment, ask your chemical substance supplier for advice. Personal protective equipment must be CE marked, showing that it complies with applicable standards. Provide an emergency shower with face and eye wash station.
HAND PROTECTION
In the case of prolonged contact with the product, protect the hands with penetration-resistant work gloves (see standard EN 374). Work glove material must be chosen according to the use process and the products that may form. Latex gloves may cause sensitivity reactions.
SKIN PROTECTION
Wear category II professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body with soap and water after removing protective clothing.
EYE PROTECTION
Wear airtight protective goggles (see standard EN 166). In the presence of risks of exposure to splashes or squirts during work, adequate mouth, nose and eye protection should be used to prevent accidental absorption.
RESPIRATORY PROTECTION
If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, wear a type FFP1 or higher class face mask if otherwise required by the risk assessment (see standard EN 149). Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the threshold values considered. The protection provided by masks is in any case limited. If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529.
ENVIRONMENTAL EXPOSURE CONTROLS
The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure compliance with environmental standards.
As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well aired through effective local aspiration. When choosing personal protective equipment, ask your chemical substance supplier for advice. Personal protective equipment must be CE marked, showing that it complies with applicable standards. Provide an emergency shower with face and eye wash station.
HAND PROTECTION
In the case of prolonged contact with the product, protect the hands with penetration-resistant work gloves (see standard EN 374). Work glove material must be chosen according to the use process and the products that may form. Latex gloves may cause sensitivity reactions.
SKIN PROTECTION
Wear category II professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body with soap and water after removing protective clothing.
EYE PROTECTION
Wear airtight protective goggles (see standard EN 166). In the presence of risks of exposure to splashes or squirts during work, adequate mouth, nose and eye protection should be used to prevent accidental absorption.
RESPIRATORY PROTECTION
If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, wear a type FFP1 or higher class face mask if otherwise required by the risk assessment (see standard EN 149). Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the threshold values considered. The protection provided by masks is in any case limited. If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529.
ENVIRONMENTAL EXPOSURE CONTROLS
The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure compliance with environmental standards.
Stability and reactivity
Reactivity
There are no particular risks of reaction with other substances in normal conditions of use. If heated or brought into contact with hot bodies the product might release ammonia.
Chemical stability
The product is stable in normal conditions of use and storage.
Possibility of hazardous reactions
No hazardous reactions are foreseeable in normal conditions of use and storage.
Conditions to avoid
Alteration of the pH value might cause the product to precipitate.
Incompatible materials
Do not add alkaline substances (i.e. sodium hydroxide), the product might release ammonia. Avoid contact with aluminium and copper.
Hazardous decomposition products
In the event of thermal decomposition or fire, vapours potentially dangerous to health may be released.
There are no particular risks of reaction with other substances in normal conditions of use. If heated or brought into contact with hot bodies the product might release ammonia.
Chemical stability
The product is stable in normal conditions of use and storage.
Possibility of hazardous reactions
No hazardous reactions are foreseeable in normal conditions of use and storage.
Conditions to avoid
Alteration of the pH value might cause the product to precipitate.
Incompatible materials
Do not add alkaline substances (i.e. sodium hydroxide), the product might release ammonia. Avoid contact with aluminium and copper.
Hazardous decomposition products
In the event of thermal decomposition or fire, vapours potentially dangerous to health may be released.
Disposal considerations
Waste treatment methods
Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product should be evaluated according to applicable regulations. Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.
Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product should be evaluated according to applicable regulations. Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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