Registration Dossier
Registration Dossier
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EC number: 266-803-5 | CAS number: 67634-00-8
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
· 4.1 Description of first aid measures
· General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact:
Check for and remove any contact lenses.
Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
DO NOT DELAY!
Wash mouth out with water
Do not induce vomiting; call for medical help immediately.
If vomiting occurs spontaneously, keep head below hips to prevent aspiration.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Information for doctor: Treat symptomatically and supportively.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
· General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact:
Check for and remove any contact lenses.
Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
DO NOT DELAY!
Wash mouth out with water
Do not induce vomiting; call for medical help immediately.
If vomiting occurs spontaneously, keep head below hips to prevent aspiration.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Information for doctor: Treat symptomatically and supportively.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
Fire-fighting measures
Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· 5.2 Special hazards arising from the substance or mixture Combustible
· 5.3 Advice for firefighters
· Protective equipment:
Do not inhale explosion gases or combustion gases.
Wear self-contained respiratory protective device.
Wear fully protective suit.
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· 5.2 Special hazards arising from the substance or mixture Combustible
· 5.3 Advice for firefighters
· Protective equipment:
Do not inhale explosion gases or combustion gases.
Wear self-contained respiratory protective device.
Wear fully protective suit.
Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation
Keep ignition sources away - no smoking.
Wear protective equipment. Keep unprotected persons away.
· 6.2 Environmental precautions:
Do not allow to penetrate the ground/soil.
Do not allow product to reach sewage system or any water course in the undiluted form.
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Send for recovery or disposal in suitable receptacles.
Ensure adequate ventilation
Keep ignition sources away - no smoking.
Wear protective equipment. Keep unprotected persons away.
· 6.2 Environmental precautions:
Do not allow to penetrate the ground/soil.
Do not allow product to reach sewage system or any water course in the undiluted form.
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Send for recovery or disposal in suitable receptacles.
Handling and storage
7.1 Precautions for safe handling
Avoid direct contact (skin/eye contact, ingestion and/or inhalation of fume/mist/dust) with the product in the
undiluted form.
Ensure good ventilation/exhaustion at the workplace.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
No special measures required.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Prevent any seepage into the ground.
· Information about storage in one common storage facility: Store away from oxidising agents.
· Further information about storage conditions:
Protect from heat and direct sunlight.
Store in cool, dry conditions in well sealed receptacles.
Avoid direct contact (skin/eye contact, ingestion and/or inhalation of fume/mist/dust) with the product in the
undiluted form.
Ensure good ventilation/exhaustion at the workplace.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
No special measures required.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Prevent any seepage into the ground.
· Information about storage in one common storage facility: Store away from oxidising agents.
· Further information about storage conditions:
Protect from heat and direct sunlight.
Store in cool, dry conditions in well sealed receptacles.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- none
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Exposure controls / personal protection
8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace: Not required.
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
Select PPE appropriate for the operations taking place taking into account the product properties.
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Respiratory protection:
Not necessary if room is well-ventilated.
Use suitable respiratory protective device in case of insufficient ventilation.
· Protection of hands:Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection: Goggles recommended during refilling
· Body protection:
Impervious protective clothing
Body protection must be chosen depending on activity, possible exposure and product properties.
· Ingredients with limit values that require monitoring at the workplace: Not required.
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
Select PPE appropriate for the operations taking place taking into account the product properties.
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Respiratory protection:
Not necessary if room is well-ventilated.
Use suitable respiratory protective device in case of insufficient ventilation.
· Protection of hands:Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection: Goggles recommended during refilling
· Body protection:
Impervious protective clothing
Body protection must be chosen depending on activity, possible exposure and product properties.
Stability and reactivity
10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: Strong oxidising agents.
· 10.6 Hazardous decomposition products: Carbon monoxide and carbon dioxide
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: Strong oxidising agents.
· 10.6 Hazardous decomposition products: Carbon monoxide and carbon dioxide
Disposal considerations
Waste treatment methods
· Recommendation
Recommended Hierarchy of Controls:
- Minimise waste;
- Reuse if not contaminated;
- Recycle, if possible; or
- Safe disposal (if all else fails).
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Contact waste processors for recycling information.
Used, degraded or contaminated product may be classified as hazardous waste. Anyone classifying hazardous
waste and determining its fate must be qualified in accordance with state and international legislation.
· European waste catalogue
Waste key numbers in accordance with the European Waste Catalogue (EWC) are origin-referred defined.
Since this product is used in several industries, no waste key can be provided by the supplier. The waste key
number should be determined in arrangement with your waste disposal partner or the responsible authority.
Uncleaned packaging:
· Recommendation:
Disposal must be made according to official regulations.
Container remains hazardous when empty. Continue to observe all precuations.
Containers, even those that are “empty,” may contain residues that can develop flammable and/or hazardous
vapours upon heating. Do not cut, drill, grind, weld, or perform similar operations on or near empty
containers.
· Recommendation
Recommended Hierarchy of Controls:
- Minimise waste;
- Reuse if not contaminated;
- Recycle, if possible; or
- Safe disposal (if all else fails).
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Contact waste processors for recycling information.
Used, degraded or contaminated product may be classified as hazardous waste. Anyone classifying hazardous
waste and determining its fate must be qualified in accordance with state and international legislation.
· European waste catalogue
Waste key numbers in accordance with the European Waste Catalogue (EWC) are origin-referred defined.
Since this product is used in several industries, no waste key can be provided by the supplier. The waste key
number should be determined in arrangement with your waste disposal partner or the responsible authority.
Uncleaned packaging:
· Recommendation:
Disposal must be made according to official regulations.
Container remains hazardous when empty. Continue to observe all precuations.
Containers, even those that are “empty,” may contain residues that can develop flammable and/or hazardous
vapours upon heating. Do not cut, drill, grind, weld, or perform similar operations on or near empty
containers.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
