Registration Dossier
Registration Dossier
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EC number: 223-660-3 | CAS number: 4006-73-9
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
General information: Remove from exposure. Remove contaminated clothing and shoes.
Consult a doctor if irritation develop or persist.
After inhalation: Remove to fresh air and monitor breathing. If breathing becoming difficult,
give oxygen and consult a physician. If breathing stops, give artificial
respiration and consult a physician.
After skin contact: Take off contaminated clothing immediately, wash the skin with plenty of
water and soap.
After eye contact: Flush with plenty of water for at least 15 minutes.
Assure adequate flushing by separating the eyelids with fingers.
Consult a specialist for medical surveillance.
After swallowing: Wash out the mouth with clear water if the patient is conscious.
Consult with a physician.
Do not induce vomiting.
Most important symptoms and effects, both acute and delayed: I
NHALATION: low concentrations with slight nasal and throat effect.
Headache, dizziness,
confusion, coordination disorder, stubbornness, inefficiency, nausea and
vomiting
cause. At higher exposures, bronchitis, pneumonia, hepatic impairment, loss
of consciousness
and death can occur.
EYE: The vapor is slightly irritating. Fluid causes pain and transient irritation.
SKIN: slightly irritating. The skin is slightly absorbed through the skin.
INGESTION: nausea, vomiting, diarrhea and loss of consciousness occur.
Indication of any immediate medical attention and special treatment needed:
In case of sickness, symptoms or allergic reactions call immediate medical
attention.
General information: Remove from exposure. Remove contaminated clothing and shoes.
Consult a doctor if irritation develop or persist.
After inhalation: Remove to fresh air and monitor breathing. If breathing becoming difficult,
give oxygen and consult a physician. If breathing stops, give artificial
respiration and consult a physician.
After skin contact: Take off contaminated clothing immediately, wash the skin with plenty of
water and soap.
After eye contact: Flush with plenty of water for at least 15 minutes.
Assure adequate flushing by separating the eyelids with fingers.
Consult a specialist for medical surveillance.
After swallowing: Wash out the mouth with clear water if the patient is conscious.
Consult with a physician.
Do not induce vomiting.
Most important symptoms and effects, both acute and delayed: I
NHALATION: low concentrations with slight nasal and throat effect.
Headache, dizziness,
confusion, coordination disorder, stubbornness, inefficiency, nausea and
vomiting
cause. At higher exposures, bronchitis, pneumonia, hepatic impairment, loss
of consciousness
and death can occur.
EYE: The vapor is slightly irritating. Fluid causes pain and transient irritation.
SKIN: slightly irritating. The skin is slightly absorbed through the skin.
INGESTION: nausea, vomiting, diarrhea and loss of consciousness occur.
Indication of any immediate medical attention and special treatment needed:
In case of sickness, symptoms or allergic reactions call immediate medical
attention.
Fire-fighting measures
Extinguishing media: Water spray, carbon dioxide, extinguishing powder, foam.
Unsuitable extinguishing media: Unknown.
Special hazards arising from the substance or mixture:
Carbondioxide and carbonmonoxide.
Advice for firefighters: Wear selfcontained breathing apparatus and protective clothing for firefighting.
Fire hazard class Danger of explosion
Fire and explosion hazard Extremely flammable liquid. Vapours may form explosive mixtures with air.Take precautionary measures against static electricity.
Unsuitable extinguishing media: Unknown.
Special hazards arising from the substance or mixture:
Carbondioxide and carbonmonoxide.
Advice for firefighters: Wear selfcontained breathing apparatus and protective clothing for firefighting.
Fire hazard class Danger of explosion
Fire and explosion hazard Extremely flammable liquid. Vapours may form explosive mixtures with air.Take precautionary measures against static electricity.
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Wear protective clothing. Respiratory, eye and skin protection needed.
Remove ignition sources.
Environmental precautions: Hinder substance from entering soil, sewers or living water.
Methods and material for containment and cleaning up:
Collect the product carefully and place material into suitable, labelled
container for disposal. Ventilate the effected area and wash spill site after
material pickup is complete. Don’t evacuate in the waste water system.
Wear protective equipment.
Wear protective clothing. Respiratory, eye and skin protection needed.
Remove ignition sources.
Environmental precautions: Hinder substance from entering soil, sewers or living water.
Methods and material for containment and cleaning up:
Collect the product carefully and place material into suitable, labelled
container for disposal. Ventilate the effected area and wash spill site after
material pickup is complete. Don’t evacuate in the waste water system.
Wear protective equipment.
Handling and storage
Precautions for safe handling:
Handling: Do not breathe vapour, mist associated with material.
Provide for fresh air ventilation.
Safety measures: Suitable general and local exhaust ventillation is needed.
Fire and explosion protection
measures:
Take measures against electrostatic discharges.
Conditions for safe storage, including
any incompatibilities:
Keep in wellclosed storage containers, in a cool and wellventilated
place.
Handling: Do not breathe vapour, mist associated with material.
Provide for fresh air ventilation.
Safety measures: Suitable general and local exhaust ventillation is needed.
Fire and explosion protection
measures:
Take measures against electrostatic discharges.
Conditions for safe storage, including
any incompatibilities:
Keep in wellclosed storage containers, in a cool and wellventilated
place.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 1294 TOLUENE
Shipping information
- Proper shipping name and description:
- TOLUENE (Toluene solution)
- Language:
- English
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
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SpecialProvisionsopen allclose all
Exposure controls / personal protection
Control parameters:
National ( HUngarian) occupational exposure limit values:
AK: 190 mg/m3 ; CK: 380 mg/m3 ; MK: None
Other occupational exposure limit
values:
No data.
Relevant regulations and recommended monitoring procedures: 91/322/EEC; 98/24/EC directives and its modifications (2000/39/EC, 2006/15/EC)
Appropriate engineering controls: Suitable general and local exhaust ventilation.
Closed system.
Personal protection equipment
Eye/face protection: Safety googles, face shield.
Hand protection: Protective gloves against solvents.
Respiratory protection Full face gasmask with A2 brown filter cartridge.
Personal protection, general hygienic
measures:
Wear protective clothes to avoid skin contact.
Remove contaminated clothing. Wash before reuse.
Wash hands with soap and water thoroughly after handling.
Environmental exposure controlls: Do not let into drains.
Material and contaminated packaging should handle as hazardous wastes.
National ( HUngarian) occupational exposure limit values:
AK: 190 mg/m3 ; CK: 380 mg/m3 ; MK: None
Other occupational exposure limit
values:
No data.
Relevant regulations and recommended monitoring procedures: 91/322/EEC; 98/24/EC directives and its modifications (2000/39/EC, 2006/15/EC)
Appropriate engineering controls: Suitable general and local exhaust ventilation.
Closed system.
Personal protection equipment
Eye/face protection: Safety googles, face shield.
Hand protection: Protective gloves against solvents.
Respiratory protection Full face gasmask with A2 brown filter cartridge.
Personal protection, general hygienic
measures:
Wear protective clothes to avoid skin contact.
Remove contaminated clothing. Wash before reuse.
Wash hands with soap and water thoroughly after handling.
Environmental exposure controlls: Do not let into drains.
Material and contaminated packaging should handle as hazardous wastes.
Stability and reactivity
Reactivity: Possibility to hazardous reactivity is not expected.
Stability: Stable at normal temperature and pressure.
Possibility of hazardous reactions: The substance has no hazardous reactivity. Organic substance, hazardous
reaction is possible with strong oxidizers, acids, bases.
Conditions to avoid (heat, pressure,
light, shock):
Avoid ignition sources.
Incompatible materials: Strong oxidising agents.
Hazardous decomposition products Not known.
Stability: Stable at normal temperature and pressure.
Possibility of hazardous reactions: The substance has no hazardous reactivity. Organic substance, hazardous
reaction is possible with strong oxidizers, acids, bases.
Conditions to avoid (heat, pressure,
light, shock):
Avoid ignition sources.
Incompatible materials: Strong oxidising agents.
Hazardous decomposition products Not known.
Disposal considerations
Disposal of the product related waste:
Dispose the solid waste or incinerate in accordance of all state and local
regulations. Burn the material in a chemical incinerator equipped with an afterburner and scrubber.
Disposal of contaminated packaging:
Dispose according to the state and local regulations.
Relevant community, national and regional provisions:
Directive 2008/98/EC of the European Parliament and of the Council of 19 November 2008 on waste Directive 91/689/EEC of hazardous wastes.
Dispose the solid waste or incinerate in accordance of all state and local
regulations. Burn the material in a chemical incinerator equipped with an afterburner and scrubber.
Disposal of contaminated packaging:
Dispose according to the state and local regulations.
Relevant community, national and regional provisions:
Directive 2008/98/EC of the European Parliament and of the Council of 19 November 2008 on waste Directive 91/689/EEC of hazardous wastes.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
