Bis(2-ethylhexyl) phosphonate

Guidance on Safe Use

First-aid measures

Description of first aid measures

Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Skin contact: Wash contaminated skin with soap and water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Ingestion: Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Most important symptoms and effects, both acute and delayed

Potential acute health effects

Eye contact: Causes serious eye irritation.

Inhalation: No known significant effects or critical hazards.

Skin contact: Causes skin irritation.

Ingestion: No known significant effects or critical hazards

Over-exposure signs/symptoms

Eye contact: Adverse symptoms may include pain or irritation, watering, redness.

Inhalation: No specific data.

Skin contact: Adverse symptoms may include irritation, redness.

Ingestion: No specific data.

Indication of any immediate medical attention and special treatment needed

Notes to physician: Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments: No specific treatment.

Fire-fighting measures

Extinguishing media

Suitable extinguishing media: Use dry chemical, CO2, water spray (fog) or foam. Use an extinguishing agent suitable for the surrounding fire.

Unsuitable extinguishing media: Do not use water jet.

Special hazards arising from the substance or mixture

Hazards from the substance or mixture: In a fire or if heated, a pressure increase will occur and the container may burst. This material is very toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Hazardous combustion products: Decomposition products may include the following materials: carbon dioxide, carbon monoxide, phosphorus oxides.

Advice for firefighters

Special protective actions for fire-fighters: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

For non-emergency personnel: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

For emergency responders: If specialized clothing is required to deal with the spillage, take note of any information in "Exposure controls/personal protection" on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.

Methods and materials for containment and cleaning up

Small spill: Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill: Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product.

Handling and storage

Precautions for safe handling

Protective measures: Put on appropriate personal protective equipment (see “Exposure controls/personal protection” section). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Avoid release to the environment. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Advice on general occupational hygiene: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also “Exposure controls/personal protection” section for additional information on hygiene measures.

Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see “Stability and reactivity” section) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See “Stability and reactivity” section for incompatible materials before handling or use.

Seveso Directive - Reporting thresholds (in tonnes)

Danger criteria

Category: E1: Hazardous to the aquatic environment - Acute 1 or Chronic 1

Notification and MAPP threshold: 100

Safety report threshold: 200

Specific end use(s)

Handling and storage: The information in this section contains generic advice and guidance.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

UN3082

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bis(2-ethylhexyl)phosphonate)

Chemical name:

bis(2-ethylhexyl)phosphonate

Language:

English

Labels:

(No. 9) Miscellaneous dangerous substances and articles;
Environmentally hazardous substances

Special provisions / remarks

Special provisions:

274, 335, 601, 375

Remarks:

This product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg, provided the packagings meet the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8.
Hazard identification number 90
Tunnel code (-)

Inland waterway transport (UN RTDG/ADN(R))

UN number:

UN3082

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bis(2-ethylhexyl)phosphonate)

Chemical name:

bis(2-ethylhexyl)phosphonate

Language:

English

Labels:

(No. 9) Miscellaneous dangerous substances and articles;
Environmentally hazardous substances

Special provisions / remarks

Remarks:

Special provisions: 274, 335, 375, 601


This product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg, provided the packagings meet the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8.

Marine transport (UN RTDG/IMDG)

UN number:

UN3082

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bis(2-ethylhexyl)phosphonate)

Chemical name:

bis(2-ethylhexyl)phosphonate

Labels:

(No. 9) Miscellaneous dangerous substances and articles;
Environmentally hazardous substances

Remarks

Remarks 1

Remarks:

Special provisions: 274, 335, 969


This product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg, provided the packagings meet the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8.

Remarks 2

Remarks:

Marine pollutant = true

Air transport (UN RTDG/ICAO/IATA)

UN number:

UN3082

Shipping information

Proper shipping name and description:

Environmentally hazardous substance, liquid, n.o.s. (bis(2-ethylhexyl)phosphonate)

Chemical name:

bis(2-ethylhexyl)phosphonate

Labels:

(No. 9) Miscellaneous dangerous substances and articles;
Environmentally hazardous substances

Special provisions / remarks

Remarks:

This product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg, provided the packagings meet the general provisions of 5.0.2.4.1, 5.0.2.6.1.1 and 5.0.2.8.

Quantity limitation
Passenger and Cargo Aircraft: 450 L. Packaging instructions: 964. Cargo Aircraft Only: 450 L. Packaging instructions: 964. Limited Quantities - Passenger Aircraft: 30 kg. Packaging instructions: Y964.

Special provisions A97, A158, A197

Additional transport information

Additional information

Special provisions / remarks / other:

Special precautions for user
Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

Exposure controls / personal protection

The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases.

Control parameters

Occupational exposure limits: No exposure limit value known.

Recommended monitoring procedures: If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

DNELs/DMELs: No DNELs/DMELs available.

PNECs: No PNECs available.

Exposure controls

Appropriate engineering controls: Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

Individual protection measures - Hygiene measures: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Individual protection measures - Eye/face protection: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Recommended: Wear tightly-sealed safety glasses. (EN166, splash goggles)

Skin protection - Hand protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Recommended: Wear suitable gloves tested to EN374.

Skin protection - Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Skin protection - Other skin protection: Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Respiratory protection: Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Recommended: Combination filtering device (DIN EN 14387). Filter type: AP-2.

Environmental exposure controls: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Stability and reactivity

Reactivity: No specific test data related to reactivity available for this product or its ingredients.

Chemical stability: The product is stable. Moisture: Hydrolysis.

Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid: Keep away from heat, sparks and flame. Protect from sunlight. Avoid static electrical charge.

Incompatible materials: Reactive or incompatible with the following materials: oxidizing materials, alkalis, halogens, water, metals.

Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Disposal considerations

The information in this section contains generic advice and guidance.

Waste treatment methods

Product

Methods of disposal: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. The allocation of waste identity numbers/waste descriptions must be carried out according to the EEC, specific to the industry and process.

Hazardous waste: The classification of the product may meet the criteria for a hazardous waste.

Packaging

Methods of disposal: The generation of waste should be avoided or minimized wherever possible.

Special precautions

This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.