Registration Dossier
Registration Dossier
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EC number: 210-164-7 | CAS number: 608-50-4
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
General information
When in doubt or if symptoms are observed, get medical advice. Remove contaminated, saturated clothing immediately. If unconscious place in recovery position and seek medical advice. Never give anything by mouth to an unconscious person or a person with cramps.
Following inhalation
Remove casualty to fresh air and keep warm and at rest. If breathing is irregular or stopped, administer artificial respiration. In case of respiratory tract irritation, consult a physician.
In case of skin contact
After contact with skin, wash immediately with plenty of water and soap. Do not wash with: Solvents/Thinner
After eye contact
In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist. Protect uninjured eye. Remove contact lenses, if present and easy to do. Continue
rinsing.
After ingestion
If accidentally swallowed rinse the mouth with plenty of water (only if the person is conscious) and obtain immediate medical attention. Do NOT induce vomiting. Keep at rest.
Indication of any immediate medical attention and special treatment needed
Show safety data sheet if possible. Treat symptomatically.
When in doubt or if symptoms are observed, get medical advice. Remove contaminated, saturated clothing immediately. If unconscious place in recovery position and seek medical advice. Never give anything by mouth to an unconscious person or a person with cramps.
Following inhalation
Remove casualty to fresh air and keep warm and at rest. If breathing is irregular or stopped, administer artificial respiration. In case of respiratory tract irritation, consult a physician.
In case of skin contact
After contact with skin, wash immediately with plenty of water and soap. Do not wash with: Solvents/Thinner
After eye contact
In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist. Protect uninjured eye. Remove contact lenses, if present and easy to do. Continue
rinsing.
After ingestion
If accidentally swallowed rinse the mouth with plenty of water (only if the person is conscious) and obtain immediate medical attention. Do NOT induce vomiting. Keep at rest.
Indication of any immediate medical attention and special treatment needed
Show safety data sheet if possible. Treat symptomatically.
Fire-fighting measures
Suitable extinguishing media: alcohol resistant foam , Extinguishing powder
Unsuitable extinguishing media: Full water jet , Carbon dioxide (CO2)
Special hazards arising from the substance or mixture
In case of fire toxic gases may be formed. In flames as well as on hot surfaces toxic and decomposition products with penetrating smell may be formed.
Advice for firefighters
Wear a self-contained breathing apparatus and chemical protective clothing.
Additional information
Use caution when applying carbon dioxide in confined spaces. Carbon dioxide can displace oxygen. Move undamaged containers from immediate hazard area if it can be done safely. Use water spray jet to protect personnel and to cool
endangered containers. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.
Unsuitable extinguishing media: Full water jet , Carbon dioxide (CO2)
Special hazards arising from the substance or mixture
In case of fire toxic gases may be formed. In flames as well as on hot surfaces toxic and decomposition products with penetrating smell may be formed.
Advice for firefighters
Wear a self-contained breathing apparatus and chemical protective clothing.
Additional information
Use caution when applying carbon dioxide in confined spaces. Carbon dioxide can displace oxygen. Move undamaged containers from immediate hazard area if it can be done safely. Use water spray jet to protect personnel and to cool
endangered containers. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Avoid dust formation.
For non-emergency personnel: Remove persons to safety. Provide adequate ventilation.
For emergency responders: Prevent spread over a wide area (e.g. by containment or oil barriers). Wear breathing apparatus if exposed to vapours/dusts/aerosols.
Environmental precautions
Clear spills immediately. Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.
Methods and material for containment and cleaning up
Contain and collect spillage with a vacuum cleaner or by wet brushing and place in container for disposal according to local regulations. Avoid dust formation. Clean contaminated articles and floor according to the environmental legislation. Ventilate affected area.
Avoid dust formation.
For non-emergency personnel: Remove persons to safety. Provide adequate ventilation.
For emergency responders: Prevent spread over a wide area (e.g. by containment or oil barriers). Wear breathing apparatus if exposed to vapours/dusts/aerosols.
Environmental precautions
Clear spills immediately. Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.
Methods and material for containment and cleaning up
Contain and collect spillage with a vacuum cleaner or by wet brushing and place in container for disposal according to local regulations. Avoid dust formation. Clean contaminated articles and floor according to the environmental legislation. Ventilate affected area.
Handling and storage
Precautions for safe handling
Normal precautions taken when handling chemicals should be observed. Avoid dust formation. Wear breathing apparatus if exposed to vapours/dusts/aerosols. Avoid contact with skin and eyes.
Measures to prevent aerosol and dust generation
The substance should only be handled in closed apparatus or systems. If handled uncovered, arrangements with local exhaust ventilation have to be used.
Advices on general occupational hygiene
When using do not eat, drink, smoke, sniff. Wash hands before breaks and after work. In the immediate working surroundings there must be Emergency shower installed . Provide eye shower and label its location conspicuously .
Conditions for safe storage, including any incompatibilities
Keep container tightly closed and in a well-ventilated place. Make sure spills can be contained, e.g. in sump pallets or kerbed areas. Restrict access to stockrooms.
Further information on storage conditions
Keep/Store only in original container. Ensure adequate ventilation of the storage area.
Maximum storage temperature : 40 °C
Protect against : Heat. UV-radiation/sunlight .
Normal precautions taken when handling chemicals should be observed. Avoid dust formation. Wear breathing apparatus if exposed to vapours/dusts/aerosols. Avoid contact with skin and eyes.
Measures to prevent aerosol and dust generation
The substance should only be handled in closed apparatus or systems. If handled uncovered, arrangements with local exhaust ventilation have to be used.
Advices on general occupational hygiene
When using do not eat, drink, smoke, sniff. Wash hands before breaks and after work. In the immediate working surroundings there must be Emergency shower installed . Provide eye shower and label its location conspicuously .
Conditions for safe storage, including any incompatibilities
Keep container tightly closed and in a well-ventilated place. Make sure spills can be contained, e.g. in sump pallets or kerbed areas. Restrict access to stockrooms.
Further information on storage conditions
Keep/Store only in original container. Ensure adequate ventilation of the storage area.
Maximum storage temperature : 40 °C
Protect against : Heat. UV-radiation/sunlight .
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- The product does not constitute a hazardous substance in national / international road, rail, sea and air transport.
Shippingopen allclose all
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- The product does not constitute a hazardous substance in national / international road, rail, sea and air transport.
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- The product does not constitute a hazardous substance in national / international road, rail, sea and air transport.
Shipping information
- Proper shipping name and description:
- The product does not constitute a hazardous substance in national / international road, rail, sea and air transport.
- Chemical name:
- The product does not constitute a hazardous substance in national / international road, rail, sea and air transport.
- Labels:
- The product does not constitute a hazardous substance in national / international road, rail, sea and air transport.
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- The product does not constitute a hazardous substance in national / international road, rail, sea and air transport.
Shipping information
- Proper shipping name and description:
- The product does not constitute a hazardous substance in national / international road, rail, sea and air transport.
- Chemical name:
- The product does not constitute a hazardous substance in national / international road, rail, sea and air transport.
- Labels:
- The product does not constitute a hazardous substance in national / international road, rail, sea and air transport.
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Exposure controls
Appropriate engineering controls
Technical measures and the application of suitable work processes have priority over personal protection equipment. The substance should only be handled in closed apparatus or systems. If handled uncovered, arrangements with local
exhaust ventilation have to be used.
Personal protection equipment
Eye/face protection
Eye glasses with side protection or Face protection shield ( DIN EN 166 )
Skin protection
Hand protection
The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. Avoid contact with the skin and mouth.
Suitable gloves type : protective gloves ( EN ISO 374 )
Thickness of the glove material : ≥ 0.4 mm
Additional hand protection measures : After washing hands replace lost skin fat by fat containing skin creams.
Remark : For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.
Body protection
Use appropriate skin protection cream before work. Chemical resistant safety clothing.
Respiratory protection
Respiratory protection necessary at: insufficient ventilation , insufficient exhaust
Suitable respiratory protection apparatus:
Filtering device (DIN EN 147) , Self-contained respirator (breathing apparatus) (DIN EN 133)
General information
The usual precautionary measures for the handling of chemicals have to be observed. Do not eat or drink during work - no smoking. Wash hands and face before breaks and after work and take a shower if necessary.
Appropriate engineering controls
Technical measures and the application of suitable work processes have priority over personal protection equipment. The substance should only be handled in closed apparatus or systems. If handled uncovered, arrangements with local
exhaust ventilation have to be used.
Personal protection equipment
Eye/face protection
Eye glasses with side protection or Face protection shield ( DIN EN 166 )
Skin protection
Hand protection
The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. Avoid contact with the skin and mouth.
Suitable gloves type : protective gloves ( EN ISO 374 )
Thickness of the glove material : ≥ 0.4 mm
Additional hand protection measures : After washing hands replace lost skin fat by fat containing skin creams.
Remark : For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.
Body protection
Use appropriate skin protection cream before work. Chemical resistant safety clothing.
Respiratory protection
Respiratory protection necessary at: insufficient ventilation , insufficient exhaust
Suitable respiratory protection apparatus:
Filtering device (DIN EN 147) , Self-contained respirator (breathing apparatus) (DIN EN 133)
General information
The usual precautionary measures for the handling of chemicals have to be observed. Do not eat or drink during work - no smoking. Wash hands and face before breaks and after work and take a shower if necessary.
Stability and reactivity
Chemical stability: The substance is chemically stable under recommended conditions of storage, use and temperature.
Possibility of hazardous reactions: No information available.
Conditions to avoid: Stable under recommended storage and handling conditions. Do not store at temperatures above 40°C.
Possibility of hazardous reactions: No information available.
Conditions to avoid: Stable under recommended storage and handling conditions. Do not store at temperatures above 40°C.
Disposal considerations
Waste treatment methods
Do not allow to enter into surface water or drains. Dispose according to legislation. The waste code has to be identified in agreement with the disposal company or the competent authority.
Directive 2008/98/EC (Waste Framework Directive)
After intended use
Contaminated packages must be completely emptied and can be re-used following proper cleaning. Handle contaminated packages in the same way as the substance itself.
Do not allow to enter into surface water or drains. Dispose according to legislation. The waste code has to be identified in agreement with the disposal company or the competent authority.
Directive 2008/98/EC (Waste Framework Directive)
After intended use
Contaminated packages must be completely emptied and can be re-used following proper cleaning. Handle contaminated packages in the same way as the substance itself.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
