EU-SAFETY_HEALTH_WORK-PREAMBLE

Safety and Health of Workers at Work Directive - Hazardous Substances

EU. Hazardous Substances for Purposes of Directive 89/391/EEC, 29 June 1989, amended by Regulation 1137/2008/EC, 21 November 2008 (Table 3/Annex VI, CLP; Annex III, 2000/54/EC)

This list contains a non-exhaustive inventory of substances that fall within the scope of the European Union's definition of hazardous chemical and biological substances, as provided on: (1) Table 3 of Annex VI to the CLP Regulation 1272/2008/EC; and (2) Annex III of Directive 2000/54/EC (Biological Agents). The EU's Occupational Safety and Health (OSH) Framework Directive 89/391/EEC applies to risks arising from chemical, physical and biological agents at the workplace.

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Last updated 01 May 2024. Database contains 4691 unique substances/entries.
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Substance Name
EC No.
CAS No.
EU CLP (1272/2008)
EU_BA Directive 2000/54/EC
butyl chloroformate; chloroformic acid butyl ester
209-750-5
592-34-7
Flam. Liq. 3; Acute Tox. 3; Skin Corr. 1B
methyl chloroacetate
202-501-1
96-34-4
Flam. Liq. 3; Acute Tox. 3; STOT SE 3; Skin Irrit. 2; Eye Dam. 1
isopropyl chloroacetate
203-301-7
105-48-6
Flam. Liq. 3; Acute Tox. 3; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2
butocarboxim (ISO); 3-(methylthio)-2-butanone O-[(methylamino)carbonyl]oxime
252-139-3
34681-10-2
Flam. Liq. 3; Acute Tox. 3; Eye Irrit. 2
1-isopropyl-4-methylbenzene; p-cymene
202-796-7
99-87-6
Flam. Liq. 3; Acute Tox. 3; Asp. Tox. 1
bis(2,4,4-trimethylpentyl)dithiophosphonic acid
420-160-9
107667-02-7
Flam. Liq. 3; Acute Tox. 3; Acute Tox. 4; Skin Corr. 1B
cyclopentyl chloroformate
CHLOROFORMIATE DE CYCLOPENTYLE; CYCLOPENTYLCHLORFORMIAT
411-460-0
50715-28-1
Flam. Liq. 3; Acute Tox. 3; Acute Tox. 4; STOT RE 2; Eye Dam. 1; Skin Sens. 1
4-methylpyridine; 4-picoline
203-626-4
108-89-4
Flam. Liq. 3; Acute Tox. 3; Acute Tox. 4; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2
1,3-dichloropropene
208-826-5
542-75-6
Flam. Liq. 3; Acute Tox. 3; Acute Tox. 4; Asp. Tox. 1; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2; Skin Sens. 1
(Z)-1,3-dichloropropene
233-195-8
10061-01-5
Flam. Liq. 3; Acute Tox. 3; Acute Tox. 4; Asp. Tox. 1; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2; Skin Sens. 1
2-(2-butoxyethoxy)ethyl thiocyanate
203-985-7
112-56-1
Flam. Liq. 3; Acute Tox. 3
di-n-butylamine
203-921-8
111-92-2
Flam. Liq. 3; Acute Tox. 2; Acute Tox. 3; Skin Corr. 1B; Eye Dam. 1
parathion — methyl (ISO); O,O-dimethyl O-4-nitrophenyl phosphorothioate
206-050-1
298-00-0
Flam. Liq. 3; Acute Tox. 2; Acute Tox. 3; STOT RE 2
allyl methacrylate; 2-methyl-2-propenoic acid 2-propenyl ester
202-473-0
96-05-9
Flam. Liq. 3; Acute Tox. 2; Acute Tox. 3; Acute Tox. 4
trans-methyl-2-ethyl-but-2-enoate
443-150-6
101226-85-1
Flam. Liq. 3
sec-butyl propionate
611-802-0
591-34-4
Flam. Liq. 3
pentyl propionate
210-852-7
624-54-4
Flam. Liq. 3
pentyl acetate
211-047-3
628-63-7
Flam. Liq. 3
n-butyl propionate
209-669-5
590-01-2
Flam. Liq. 3
isopentyl propionate
203-322-1
105-68-0
Flam. Liq. 3
isopentyl acetate
204-662-3
123-92-2
Flam. Liq. 3
isobutyl but-3-enoate
ISOBUTYLVINYL ACETATE; IVA
401-170-2
24342-03-8
Flam. Liq. 3
iso-butyl propionate
208-746-0
540-42-1
Flam. Liq. 3
butyl butyrate
203-656-8
109-21-7
Flam. Liq. 3
7-methylocta-1,6-diene
7-METHYL-1,6-OCTADIENE
404-210-7
42152-47-6
Flam. Liq. 3
2-methylbutyl propionate
219-449-0
2438-20-2
Flam. Liq. 3
2-methylbutyl acetat
210-843-8
624-41-9
Flam. Liq. 3
2-methoxy-1-methylethyl acetate
203-603-9
108-65-6
Flam. Liq. 3
2,4,6-trimethyl-1,3,5-trioxane; paraldehyde
204-639-8
123-63-7
Flam. Liq. 3
2(or 3)-methylbutyl acetate
282-263-3
84145-37-9
Flam. Liq. 3
1-methylbutyl acetate
210-946-8
626-38-0
Flam. Liq. 3
1,3-diethoxypropane
DE 3
413-140-6
3459-83-4
Flam. Liq. 3
Reaction product of: 1,2,3-propanetricarboxylic acid, 2-hydroxy, diethyl ester, 1-propanol and zirconium tetra-n-propanolate
TYZOR ZEC
417-110-3
1379678-99-5
Flam. Liq. 2; Skin Irrit. 2; Eye Dam. 1
ethynyl cyclopropane
425-430-1
6746-94-7
Flam. Liq. 2; Skin Irrit. 2; Eye Dam. 1
tert-butyl methyl ether; MTBE; 2-methoxy-2-methylpropane
216-653-1
1634-04-4
Flam. Liq. 2; Skin Irrit. 2
1-methoxy-2-propylamine
METHOXYISOPROPYLAMINE
422-550-4
37143-54-7
Flam. Liq. 2; Skin Corr. 1B; Acute Tox. 4
propionyl chloride
201-170-0
79-03-8
Flam. Liq. 2; Skin Corr. 1B
butyryl chloride
205-498-5
141-75-3
Flam. Liq. 2; Skin Corr. 1B
acetyl chloride
200-865-6
75-36-5
Flam. Liq. 2; Skin Corr. 1B
3-iodpropene; allyl iodide
209-130-4
556-56-9
Flam. Liq. 2; Skin Corr. 1B
isobutyryl chloride
201-194-1
79-30-1
Flam. Liq. 2; Skin Corr. 1A
methyl methacrylate; methyl 2-methylprop-2-enoate; methyl 2-methylpropenoate
201-297-1
80-62-6
Flam. Liq. 2; STOT SE 3; Skin Irrit. 2; Skin Sens. 1
pentan-3-one; diethyl ketone
202-490-3
96-22-0
Flam. Liq. 2; STOT SE 3
dipropyl ether
203-869-6
111-43-3
Flam. Liq. 2; STOT SE 3
diisopropyl ether
203-560-6
108-20-3
Flam. Liq. 2; STOT SE 3
bis(N-methyl-N-phenylhydrazine)sulfate
GR101655A
423-170-1
618-26-8
Flam. Liq. 2; STOT RE 1; Acute Tox. 4; Eye Dam. 1; Skin Sens. 1
carbon disulphide
200-843-6
75-15-0
Flam. Liq. 2; Repr. 2; STOT RE 1; Eye Irrit. 2; Skin Irrit. 2
toluene
203-625-9
108-88-3
Flam. Liq. 2; Repr. 2; Asp. Tox. 1; STOT RE 2; Skin Irrit. 2; STOT SE 3
n-hexane
203-777-6
110-54-3
Flam. Liq. 2; Repr. 2; Asp. Tox. 1; STOT RE 2; Skin Irrit. 2; STOT SE 3
methyl isocyanate
210-866-3
624-83-9
Flam. Liq. 2; Repr. 2; Acute Tox. 2; Acute Tox. 3; Resp. Sens. 1; Skin Sens. 1; STOT SE 3; Skin Irrit. 2; Eye Dam. 1
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