EU-SAFETY_HEALTH_WORK-PREAMBLE

Safety and Health of Workers at Work Directive - Hazardous Substances

EU. Hazardous Substances for Purposes of Directive 89/391/EEC, 29 June 1989, amended by Regulation 1137/2008/EC, 21 November 2008 (Table 3/Annex VI, CLP; Annex III, 2000/54/EC)

This list contains a non-exhaustive inventory of substances that fall within the scope of the European Union's definition of hazardous chemical and biological substances, as provided on: (1) Table 3 of Annex VI to the CLP Regulation 1272/2008/EC; and (2) Annex III of Directive 2000/54/EC (Biological Agents). The EU's Occupational Safety and Health (OSH) Framework Directive 89/391/EEC applies to risks arising from chemical, physical and biological agents at the workplace.

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Last updated 26 April 2024. Database contains 4691 unique substances/entries.
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Substance Name
EC No.
CAS No.
EU CLP (1272/2008)
EU_BA Directive 2000/54/EC
tosylchloramide sodium
204-854-7
127-65-1
Acute Tox. 4; Skin Corr. 1B; Resp. Sens. 1
Toscana virus
-
-
V Viruses: Member States are to ensure that all viruses which have already been isolated in humains and which have not been assessed and allocated in this Annex are classified in group 2 as a minimum, except where Member States have proof that they are unlikely to cause disease in humans.
Toroviridae
-
-
V Viruses: Member States are to ensure that all viruses which have already been isolated in humains and which have not been assessed and allocated in this Annex are classified in group 2 as a minimum, except where Member States have proof that they are unlikely to cause disease in humans.
Tonate virus
-
-
V Viruses: Member States are to ensure that all viruses which have already been isolated in humains and which have not been assessed and allocated in this Annex are classified in group 2 as a minimum, except where Member States have proof that they are unlikely to cause disease in humans.
tolylfluanid (ISO);dichloro-N-[(dimethylamino)sulphonyl]fluoro-N-(p-tolyl)methanesulphenamide;[containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];tolylfluanid (ISO);dichloro-N-[(dimethylamino)sulphonyl]fluoro-N-(p-tolyl)methanesulphenamide;[containing ≥0.1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
211-986-9
731-27-1
Eye Irrit. 2; STOT SE 3; Skin Irrit. 2; Skin Sens. 1
tolylfluanid (ISO);dichloro-N-[(dimethylamino)sulphonyl]fluoro-N-(p-tolyl)methanesulphenamide;[containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];tolylfluanid (ISO);dichloro-N-[(dimethylamino)sulphonyl]fluoro-N-(p-tolyl)methanesulphenamide;[containing ≥0.1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
211-986-9
731-27-1
Acute Tox. 2; STOT RE 1; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2; Skin Sens. 1
toluidinium chloride
208-740-8
540-23-8
Carc. 2; Acute Tox. 3; Eye Irrit. 2; Skin Sens. 1
toluidine sulphate (1:1)
208-741-3
540-25-0
Carc. 2; Acute Tox. 3; Eye Irrit. 2; Skin Sens. 1
toluene-4-sulphonohydrazide
216-407-3
1576-35-8
Self-react. D
toluene-2,4-diammonium sulphate; 4-methyl-m-phenylenediamine sulfate
265-697-8
65321-67-7
Carc. 1B; Acute Tox. 3; Acute Tox. 4; Eye Irrit. 2; Skin Sens. 1
toluene
203-625-9
108-88-3
Flam. Liq. 2; Repr. 2; Asp. Tox. 1; STOT RE 2; Skin Irrit. 2; STOT SE 3
tolclofos-methyl (ISO); O-(2,6-dichloro-p-tolyl)-O,O-dimethyl thiophosphate
260-515-3
57018-04-9
Skin Sens. 1B
titanium(4+) oxalate
TITANYL OXALAAT
403-260-7
31363-92-5
Eye Dam. 1
titanium tetrachloride
231-441-9
7550-45-0
Skin Corr. 1B
titanium dioxide [in powder form containing 1 % or more of particles with aerodynamic diameter ≤ 10 μm]
236-675-5
13463-67-7
Carc. 2
tin(II) methanesulphonate
STANNOUS METHANE SULPHONAT; STANNOUS METHANE SULPHONATE; TIN (II) METHANE SULPHONATE; TIN METHANE SULPHONATE; TIN METHANESULFONATE; TIN SALT FS; ZINN(II) METHANESULFONATE; ZINN(II)-METHANSULFONAT
401-640-7
53408-94-9
Skin Corr. 1B; Acute Tox. 4; Skin Sens. 1
tin tetrachloride; stannic chloride
231-588-9
7646-78-8
Skin Corr. 1B
Tick-borne orthomyxoviridae: Dhori and Thogoto
-
-
V Viruses: Member States are to ensure that all viruses which have already been isolated in humains and which have not been assessed and allocated in this Annex are classified in group 2 as a minimum, except where Member States have proof that they are unlikely to cause disease in humans.
thymol
201-944-8
89-83-8
Acute Tox. 4; Skin Corr. 1B
thiram (ISO); tetramethylthiuram disulphide
205-286-2
137-26-8
Acute Tox. 4; STOT RE 2; Eye Irrit. 2; Skin Irrit. 2; Skin Sens. 1
thiourea; thiocarbamide
200-543-5
62-56-6
Carc. 2; Repr. 2; Acute Tox. 4
thioquinox(ISO); 2-thio-1,3-dithiolo(4,5,b)quinoxaline
202-272-8
93-75-4
Acute Tox. 4
thiophanate-methyl (ISO); dimethyl (1,2-phenylenedicarbamothioyl)biscarbamate; dimethyl 4,4'-(o-phenylene) bis(3-thioallophanate)
245-740-7
23564-05-8
Carc. 2; Muta. 2; Acute Tox. 4; Skin Sens. 1
thionyl dichloride; thionyl chloride
231-748-8
7719-09-7
Acute Tox. 4; Skin Corr. 1A
thionyl chloride, reaction products with 1,3,4-thiadiazol-2,5-dithiol, tert-nonanethiol andC 12-14-tert-alkylamine
RT 1766A
404-820-3
164637-97-2
Skin Irrit. 2; Skin Sens. 1
thionazin (ISO); O,O-diethyl O-pyrazin-2-yl phosphorothioate
206-049-6
297-97-2
Acute Tox. 1; Acute Tox. 2
thiometon (ISO); S-2-ethylthioethyl O,O-dimethyl phosphorodithioate
211-362-6
640-15-3
Acute Tox. 3; Acute Tox. 4
thioglycolic acid
200-677-4
68-11-1
Acute Tox. 3; Skin Corr. 1B
thiofanox (ISO); 3,3-dimethyl-1-(methylthio)butanone-O-(N-methylcarbamoyl)oxime
254-346-4
39196-18-4
Acute Tox. 1; Acute Tox. 2
thiocyanic acid
207-337-4
463-56-9
Acute Tox. 4
thiocarbonyl chloride
207-341-6
463-71-8
Acute Tox. 3; Acute Tox. 4; Eye Irrit. 2; STOT SE 3; Skin Irrit. 2
thiobencarb (ISO); S-4-chlorobenzyl diethylthiocarbamate
248-924-5
28249-77-6
Acute Tox. 4
thioacetamide
200-541-4
62-55-5
Carc. 1B; Acute Tox. 4; Eye Irrit. 2; Skin Irrit. 2
thiazafluron (ISO); 1,3-dimethyl-1-(5-trifluoromethyl-1,3,4-thiadiazol-2-yl)urea
246-901-4
25366-23-8
Acute Tox. 4
thiamethoxam (ISO); 3-(2-chloro-thiazol-5-ylmethyl)-5-methyl[1,3,5]oxadiazinan-4-ylidene-N-nitroamine
428-650-4
153719-23-4
Repr. 2; Acute Tox. 4
thiacloprid (ISO); (Z)-3-(6-chloro-3-pyridylmethyl)-1,3-thiazolidin-2-ylidenecyanamide; {(2Z)-3-[(6-chloropyridin-3-yl)methyl]-1,3-thiazolidin-2-ylidene}cyanamide
601-147-9
111988-49-9
Carc. 2; Repr. 1B; Acute Tox. 4; Acute Tox. 3; STOT SE 3
theophylline; 1,3-dimethyl-3,7-dihydro-1H-purine-2,6-dione
200-385-7
58-55-9
Repr. 1B
thallium thiocyanate
222-571-7
3535-84-0
Acute Tox. 2; Acute Tox. 4; STOT RE 2
thallium compounds, with the exception of those specified elsewhere in this Annex
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Niobium thallium trioxide EC / List no: 235-634-9 | CAS no: 12396-77-9
Thallium phosphate EC / List no: 257-461-8 | CAS no: 51833-34-2
Thallic nitrate, trihydrate EC / List no: 627-221-0 | CAS no: 13453-38-8
Nitric acid, thallium salt EC / List no: - | CAS no: 16901-76-1
Thallium chloride EC / List no: 232-241-4 | CAS no: 7791-12-0
Cyclopentadienylthallium EC / List no: 252-229-2 | CAS no: 34822-90-7
Sulfuric acid, thallium(3+) salt (2:1), tetrahydrate EC / List no: - | CAS no: 37667-57-5
Thallium telluride (Tl2Te3) EC / List no: - | CAS no: 12040-16-3
Dithallium sulphate EC / List no: 231-201-3 | CAS no: 7446-18-6
Dithallium tris(sulphate) EC / List no: 240-349-8 | CAS no: 16222-66-5
Waste solids, cadmium-electrolysis, thallium-rich
Residue obtained in the electrolysis of cadmium, composed primarily of thallium chromate. Other non-ferrous metals or metal compounds may also be present.
EC / List no: 285-572-1 | CAS no: 85117-20-0
Slimes and Sludges, thallium
Product of adding a sulfidizer to a thallium-rich solution during lead refining. Consists primarily of thallium and cadmium sulfides.
EC / List no: 273-835-3 | CAS no: 69029-95-4
Thallium hydroxide EC / List no: 234-708-8 | CAS no: 12026-06-1
Residues, thallium EC / List no: - | CAS no: 69029-81-8
Sulfuric acid, thallium(2+) salt EC / List no: - | CAS no: 37475-01-7
Dithallium trioxide EC / List no: 215-229-3 | CAS no: 1314-32-5
Sulfuric acid, thallium(3+) salt (2:1), monohydrate EC / List no: - | CAS no: 37667-58-6
Thallium bromide EC / List no: 232-163-0 | CAS no: 7789-40-4
Thallium trinitrate EC / List no: 237-325-4 | CAS no: 13746-98-0
Thallium (III) acetate sesquihydrate EC / List no: 219-913-2 | CAS no: 2570-63-0
Thallium telluride (TlTe) EC / List no: - | CAS no: 12040-12-9
Dithallium difluoride EC / List no: - | CAS no: 31970-97-5
Thallium iodide EC / List no: 232-199-7 | CAS no: 7790-30-9
Thallium triiodide EC / List no: 236-627-3 | CAS no: 13453-37-7
Thallium (I) ethanolate EC / List no: 243-786-2 | CAS no: 20398-06-5
Thallium, (4-methylphenyl)bis(trifluoroacetato-O)- EC / List no: 631-044-4 | CAS no: 23586-55-2
2-Butanol, 2-methyl-, thallium(1+) salt EC / List no: - | CAS no: 75222-21-8
Dithallium carbonate EC / List no: 229-434-0 | CAS no: 6533-73-9
Chloric acid, thallium(1+) salt EC / List no: - | CAS no: 13453-30-0
Thallium fluoride EC / List no: 232-154-1 | CAS no: 7789-27-7
Thallium acetate EC / List no: 209-257-5 | CAS no: 563-68-8
Oxalic acid dithallium(I) salt EC / List no: 680-447-1 | CAS no: 30737-24-7
2-fluoroacetate;thallium(1+) EC / List no: - | CAS no: 63905-90-8
Thallium iodate EC / List no: 238-831-8 | CAS no: 14767-09-0
Thallium arsenide EC / List no: 234-481-5 | CAS no: 12006-09-6
m-Toluic acid, alpha,alpha,alpha-trifluoro-, thallium salt EC / List no: - | CAS no: 63980-13-2
Thallium(3+) perchlorate EC / List no: 239-677-4 | CAS no: 15596-83-5
Thallium(III) trifluoroacetate EC / List no: 245-761-1 | CAS no: 23586-53-0
Trimethyl thallium EC / List no: - | CAS no: 3003-15-4
Slimes and Sludges, thallium carbonate EC / List no: - | CAS no: 69029-96-5
Thallium triarsenide EC / List no: 281-902-3 | CAS no: 84057-85-2
Sulfuric acid, aluminum thallium salt EC / List no: - | CAS no: 52238-56-9
Thallium nitrate EC / List no: 233-273-1 | CAS no: 10102-45-1
(pentane-2,4-dionato-O,O')thallium EC / List no: 238-081-1 | CAS no: 14219-90-0
Thallium hydrotris(1-pyrazolyl)borate EC / List no: - | CAS no: 34269-45-9
Antimony, compound with thallium (1:1) EC / List no: 249-428-1 | CAS no: 29095-38-3
Sulfuric acid, thallium salt EC / List no: - | CAS no: 10031-59-1
Thallium(3+) triformate EC / List no: 276-195-3 | CAS no: 71929-23-2
Bismuth thallium( 1) cation pentadecaiodide EC / List no: - | CAS no: 67338-06-1
Dithallium selenide EC / List no: 239-627-1 | CAS no: 15572-25-5
Dithallium trisulphide EC / List no: 234-886-7 | CAS no: 12039-17-7
Thallium trifluoride EC / List no: 232-010-8 | CAS no: 7783-57-5
Dithallium telluride EC / List no: 234-916-9 | CAS no: 12040-13-0
Carbamic acid, diethyldithio-, thallium complex EC / List no: - | CAS no: 18756-72-4
Thallium acetate EC / List no: 239-947-1 | CAS no: 15843-14-8
Thallium(i) metaborate EC / List no: - | CAS no: 16979-36-5
Dithallium sulphide EC / List no: 215-250-8 | CAS no: 1314-97-2
Sulfuric acid, thallium(1+) tin(2+) salt (2:2:1) EC / List no: - | CAS no: 27790-36-9
Mercury thallium dinitrate EC / List no: 301-543-9 | CAS no: 94022-47-6
Dithallium chromate EC / List no: 236-750-2 | CAS no: 13473-75-1
Thallium(1+) propan-2-olate EC / List no: 254-386-2 | CAS no: 39262-04-9
Thallium (201Tl) Chloride Injection EC / List no: - | CAS no: 55172-29-7
Thallium hydrogen carbonate EC / List no: 249-868-4 | CAS no: 29809-42-5
Perrhenic acid, thallium salt EC / List no: 683-357-0 | CAS no: 14013-75-3
Leach residues, zinc refining flue dust, cadmium-thallium ppt.
Sponge produced by leaching and precipitating cadmium and thallium fumes and flue dusts from lead/zinc smelting operations.
EC / List no: 296-097-4 | CAS no: 92257-11-9
Thallium formate EC / List no: 213-599-0 | CAS no: 992-98-3
Dithallium dichromate EC / List no: 236-626-8 | CAS no: 13453-35-5
Silver thallium dinitrate EC / List no: 247-283-9 | CAS no: 25822-21-3
Thallium trichloride EC / List no: 236-625-2 | CAS no: 13453-32-2
Thallium thiocyanate EC / List no: 222-571-7 | CAS no: 3535-84-0
Thallium selenide EC / List no: 234-895-6 | CAS no: 12039-52-0
Selenious acid, dithallium(1+) salt EC / List no: - | CAS no: 15123-92-9
Sulfuric acid, thallium(3+) salt (2:1) EC / List no: - | CAS no: 15478-75-8
Bismuth, compound with thallium (1:1) EC / List no: 234-982-9 | CAS no: 12048-36-1
Thallium tribromide EC / List no: 237-232-9 | CAS no: 13701-90-1
Thallium iodide (TlI2) EC / List no: - | CAS no: 57232-83-4
Dithallium malonate EC / List no: 220-414-7 | CAS no: 2757-18-8
lambda1-thallanylium hexafluoro-lambda5-phosphanuide EC / List no: 633-081-1 | CAS no: 60969-19-9
Dithallium oxide EC / List no: 215-220-4 | CAS no: 1314-12-1
Sulfuric acid, thallium(3+) salt (2:1), dihydrate EC / List no: - | CAS no: 87963-73-3
-
-
Acute Tox. 2; STOT RE 2
thallium
231-138-1
7440-28-0
Acute Tox. 2; STOT RE 2
tetrasodium ethylene diamine tetraacetate
200-573-9
64-02-8
Acute Tox. 4; Eye Dam. 1
tetrasodium dihydrogen 1,1''-dihydroxy-8,8''-[p-phenylbis(imino-{6-[4-(2-aminoethyl)piperazin-1-yl]}-1,3,5-triazine-4,2-diyl-imino)]bis(2,2'-azonaphthalene-1',3,6-trisulfonate)
RED ULK 1640
420-350-1
172277-97-3
Eye Dam. 1
tetrasodium [7-(2,5-dihydroxy-KO2-7-sulfonato-6-[4-(2,5,6-trichloro-pyrimidin-4-ylamino)phenylazo]-(N1,N7-N)1-naphthylazo)-8-hydroxy-KO8-naphthalene-1,3,5-trisulfonato(6)]cuprate(II)
NAVY 14 05 711
411-470-5
141048-13-7
Skin Sens. 1
tetrasodium 5-benzamido-3-(5-(4-fluoro-6-(1-sulphonato-2-naphthylamino)-1,3,5-triazin-2-ylamino)-2-sulphonatophenylazo)-4-hydroxynaphthalene-2,7-disulphonate
C.I. REACTIVE RED 220; CIBACRON-RED F-2G; CIBACRON-ROT F-2G; REACTIVE RED 220; ROSSO REATTIVO 220; ROUGE REACTIF 220
400-790-0
85665-97-0
Eye Irrit. 2; Skin Irrit. 2; Skin Sens. 1
tetrasodium 5-[4-chloro-6-(N-ethyl-anilino)-1,3,5-triazin-2-ylamino]-4-hydroxy-3-(1,5-disulfonatonaphthalen-2-ylazo)-naphthalene-2,7-disulfonate
REACTIVE RED SR 6947; ROUGE REACTIF SR 6947
411-540-5
130201-57-9
Eye Dam. 1; Skin Sens. 1
tetrasodium 5-(4,6-dichloro-5-cyanopyrimidin-2-ylamino)-4-hydroxy-2,3-azodinaphthalene-1,2,5,7-disulphonate
C.I. REACTIVE RED 219
400-130-1
149057-72-7
Resp. Sens. 1
tetrasodium 4-hydroxy-5-[4-[3-(2-sulfatoethanesulfonyl)phenylamino]-6-morpholin-4-yl-1,3,5-triazin-2-ylamino]-3-(1-sulfonatonaphthalen-2-ylazo)naphthalene-2,7-disulfonate
REACTIVE RED 202 (ESTER)
413-070-6
1379676-82-0
Skin Sens. 1
tetrasodium 4-amino-5-hydroxy-6-(4-(2-(2-(sulfonatooxy)ethylsulfonyl)ethylcarbamoyl)phenylazo)-3-(4-(2-(sulfonatooxy)ethylsulfonyl)phenylazo)naphthalene-2,7-disulfonate
BLEU REACTIF 238; BLEU REATTIVO 238; C.I. REACTIVE BLUE 238; DISAZO MARINE TZ 2646; MARINE DIAZO TZ 2646; REACTIVE BLUE 238
404-320-5
116889-78-2
Skin Sens. 1
tetrasodium 4-amino-3,6-bis(5-(6-chloro-4-(2-hydroxyethylamino)-1,3,5-triazin-2-ylamino)-2-sulfonatophenylazo)-5-hydroxynaphthalene-2,7-sulfonate (containing > 35 % sodium chloride and sodium acetate)
BLEU MARINE DRIMARENE X-GN PKT; BLEU MARINE X-VT 4046; DRIMAREN MARINEBLAU X-GN PKT; DRIMAREN NAVY X-GN PKT; NAVY BLUE X-VT 4046
400-510-7
85665-98-1
Eye Dam. 1; Skin Sens. 1
tetrasodium 4-[4-chloro-6-(4-methyl-2-sulfophenylamino)-1,3,5-triazin-2-ylamino]-6-(4,5-dimethyl-2-sulfophenylazo)-5-hydroxynaphthalene-2,7-disulfonate
AZO MONOCHLOROTRIAZINYL REACTIVE DYE; PROCION RED PX-6B COLOUR; SUBSTANCE S161057
415-400-4
148878-22-2
Eye Dam. 1; Skin Sens. 1
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