workplace-signs

Workplace Signs - minimum requirements & signs on containers and pipes

EU. Workplace Signage: Annexes I and III, Directive 92/58/EEC, last amended by Directive 2014/27/EU, 5 March 2014

This list contains hazardous substances based on Table 3 of Annex VI to the CLP Regulation 1272/2008/EC. According to the annexes to Directive 92/58/EEC, storage areas and containers containing chemical substances or mixtures that are classified as hazardous according to the CLP Regulation must be duly marked and/or labeled. Directive 92/58/EEC requires employers to ensure proper signage is posted in areas where hazards cannot be avoided or reduced.

RELEVANT LEGISLATION
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Index
081-002-00-9
Danger Symbols
Skull and crossbones

Health hazard


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Group members
This group of substance has the following member substances:
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Name EC / List no. CAS no. Association
Thallium acetate 209-257-5 563-68-8 Expert judgement
Trimethyl thallium - 3003-15-4 Expert judgement
lambda1-thallanylium hexafluoro-lambda5-phosphanuide 633-081-1 60969-19-9 Expert judgement
Bismuth thallium( 1) cation pentadecaiodide - 67338-06-1 Expert judgement
Leach residues, zinc refining flue dust, cadmium-thallium ppt.
Sponge produced by leaching and precipitating cadmium and thallium fumes and flue dusts from lead/zinc smelting operations.
 296-097-4 92257-11-9 Expert judgement
Thallium(1+) propan-2-olate 254-386-2 39262-04-9 Expert judgement
Thallium hydrogen carbonate 249-868-4 29809-42-5 Expert judgement
Dithallium trioxide 215-229-3 1314-32-5 Expert judgement
Niobium thallium trioxide 235-634-9 12396-77-9 Expert judgement
Sulfuric acid, thallium salt - 10031-59-1 Expert judgement
Thallium, (4-methylphenyl)bis(trifluoroacetato-O)- 631-044-4 23586-55-2 Expert judgement
Thallium trifluoride 232-010-8 7783-57-5 Expert judgement
Thallium fluoride 232-154-1 7789-27-7 Expert judgement
Thallium(III) trifluoroacetate 245-761-1 23586-53-0 Expert judgement
Dithallium dichromate 236-626-8 13453-35-5 Expert judgement
Thallium telluride (Tl2Te3) - 12040-16-3 Expert judgement
Thallium (201Tl) Chloride Injection - 55172-29-7 Expert judgement
Oxalic acid dithallium(I) salt 680-447-1 30737-24-7 Expert judgement
Thallium chloride 232-241-4 7791-12-0 Expert judgement
Thallium trinitrate 237-325-4 13746-98-0 Expert judgement
Sulfuric acid, thallium(3+) salt (2:1), monohydrate - 37667-58-6 Expert judgement
Dithallium carbonate 229-434-0 6533-73-9 Expert judgement
Thallium telluride (TlTe) - 12040-12-9 Expert judgement
Thallium iodate 238-831-8 14767-09-0 Expert judgement
Thallium acetate 239-947-1 15843-14-8 Expert judgement
Thallium (I) ethanolate 243-786-2 20398-06-5 Expert judgement
Mercury thallium dinitrate 301-543-9 94022-47-6 Expert judgement
Thallium selenide 234-895-6 12039-52-0 Expert judgement
Dithallium sulphate 231-201-3 7446-18-6 Expert judgement
Waste solids, cadmium-electrolysis, thallium-rich
Residue obtained in the electrolysis of cadmium, composed primarily of thallium chromate. Other non-ferrous metals or metal compounds may also be present.
 285-572-1 85117-20-0 Expert judgement
Residues, thallium - 69029-81-8 Expert judgement
Sulfuric acid, thallium(1+) tin(2+) salt (2:2:1) - 27790-36-9 Expert judgement
Thallium iodide 232-199-7 7790-30-9 Expert judgement
Dithallium tris(sulphate) 240-349-8 16222-66-5 Expert judgement
Silver thallium dinitrate 247-283-9 25822-21-3 Expert judgement
Slimes and Sludges, thallium carbonate - 69029-96-5 Expert judgement
Perrhenic acid, thallium salt 683-357-0 14013-75-3 Expert judgement
Thallic nitrate, trihydrate 627-221-0 13453-38-8 Expert judgement
Dithallium sulphide 215-250-8 1314-97-2 Expert judgement
Thallium tribromide 237-232-9 13701-90-1 Expert judgement
Antimony, compound with thallium (1:1) 249-428-1 29095-38-3 Expert judgement
Thallium bromide 232-163-0 7789-40-4 Expert judgement
Thallium(3+) triformate 276-195-3 71929-23-2 Expert judgement
Thallium iodide (TlI2) - 57232-83-4 Expert judgement
Sulfuric acid, thallium(2+) salt - 37475-01-7 Expert judgement
Selenious acid, dithallium(1+) salt - 15123-92-9 Expert judgement
Dithallium selenide 239-627-1 15572-25-5 Expert judgement
(pentane-2,4-dionato-O,O')thallium 238-081-1 14219-90-0 Expert judgement
Dithallium telluride 234-916-9 12040-13-0 Expert judgement
Sulfuric acid, thallium(3+) salt (2:1) - 15478-75-8 Expert judgement
Dithallium trisulphide 234-886-7 12039-17-7 Expert judgement
Dithallium oxide 215-220-4 1314-12-1 Expert judgement
Thallium formate 213-599-0 992-98-3 Expert judgement
Thallium hydrotris(1-pyrazolyl)borate - 34269-45-9 Expert judgement
2-fluoroacetate;thallium(1+) - 63905-90-8 Expert judgement
Chloric acid, thallium(1+) salt - 13453-30-0 Expert judgement
Thallium(i) metaborate - 16979-36-5 Expert judgement
Thallium nitrate 233-273-1 10102-45-1 Expert judgement
Thallium phosphate 257-461-8 51833-34-2 Expert judgement
Thallium trichloride 236-625-2 13453-32-2 Expert judgement
Cyclopentadienylthallium 252-229-2 34822-90-7 Expert judgement
Sulfuric acid, aluminum thallium salt - 52238-56-9 Expert judgement
Thallium triarsenide 281-902-3 84057-85-2 Expert judgement
Thallium hydroxide 234-708-8 12026-06-1 Expert judgement
Sulfuric acid, thallium(3+) salt (2:1), dihydrate - 87963-73-3 Expert judgement
Carbamic acid, diethyldithio-, thallium complex - 18756-72-4 Expert judgement
Thallium thiocyanate 222-571-7 3535-84-0 Expert judgement
Thallium triiodide 236-627-3 13453-37-7 Expert judgement
Bismuth, compound with thallium (1:1) 234-982-9 12048-36-1 Expert judgement
Slimes and Sludges, thallium
Product of adding a sulfidizer to a thallium-rich solution during lead refining. Consists primarily of thallium and cadmium sulfides.
 273-835-3 69029-95-4 Expert judgement
Thallium(3+) perchlorate 239-677-4 15596-83-5 Expert judgement
Nitric acid, thallium salt - 16901-76-1 Expert judgement
Dithallium malonate 220-414-7 2757-18-8 Expert judgement
Dithallium chromate 236-750-2 13473-75-1 Expert judgement
Dithallium difluoride - 31970-97-5 Expert judgement
2-Butanol, 2-methyl-, thallium(1+) salt - 75222-21-8 Expert judgement
Thallium arsenide 234-481-5 12006-09-6 Expert judgement
m-Toluic acid, alpha,alpha,alpha-trifluoro-, thallium salt - 63980-13-2 Expert judgement
Thallium (III) acetate sesquihydrate 219-913-2 2570-63-0 Expert judgement
Sulfuric acid, thallium(3+) salt (2:1), tetrahydrate - 37667-57-5 Expert judgement