Substances restricted under REACH

The table below is the Annex XVII to REACH and includes all the restrictions adopted in the framework of REACH and the previous legislation, Directive 76/769/EEC. Each entry shows a substance or a group of substances or a substance in a mixture, and the consequent restriction conditions. The latest consolidated version of REACH presents the restrictions adopted until the date of publication. Subsequent changes are included in the amending Commission regulations.

Further information on the table

The restricted substances (on their own, in a mixture or in an article) are substances for which manufacture, placing on the market or use is limited or banned in the European Union.

The table has been prepared by the European Chemicals Agency (ECHA) to facilitate the searching of restricted substances in the Annex XVII of the REACH Regulation, and the table provides additional information related to the specific restriction entry.

The table contains:

Name: the name as given in column 1 of Annex XVII of each entry. In certain cases a group name is not available and the entry number is used instead;
EC and CAS numbers; please note that not all the entries in Annex XVII of the REACH Regulation have these numbers. Note also that if it is a group entry, the EC and CAS numbers are under the group member information;
Conditions: a document prepared by ECHA that includes the conditions of the restriction according to the latest updated consolidated version of Annex XVII to REACH Regulation. The document also contains the subsequent amendment(s) after the publishing of the consolidated version of REACH;
Appendices: links to appendices that concern only certain entries. Please note that searching with CAS or EC numbers is not yet possible for substances restricted under Appendices 1-6 (CMR substances);
Standards: links providing information on standards, where available (links to the CEN search engine for the European standards, or to the international standards' pages);
History: links to the original restriction and subsequent amendments;
Q&A: the relevant question(s) and answers related to the restriction entry. Please note that the list of Questions and Answers on Restrictions contains also general Q&As, which are not entry specific.

Group members: if there is an entry which concerns several substances (i.e. group entry); the substances within the group entry are described as ‘Group members' and listed in the table. These members are either explicitly mentioned in the specific restriction entry, or they are identified by ECHA in case the entry is of general nature (like cadmium and its compounds). Note that this identification is not yet ready for all entries.

Note that some entries have been deleted from the table:

Regulation (EU) No 552/2009: entries 33 and 39 have been deleted (substances severely restricted under Regulation (EC) No 2037/2000 – substances that deplete the ozone layer).
Regulation (EU) No 207/2011: entries 44 and 53 have been deleted (substances severely restricted under Regulation (EU) No 850/2004 – substances as persistent organic pollutants). Note: Regulation (EC) No 850/2004 is repealed with Regulation (EU) No 2020/2096.
Regulation (EU) No 126/2013: entry 42 has been deleted (substances severely restricted under Regulation (EU) No 519/2012 amending Regulation (EC) No 850/2004 – substances as persistent organic pollutants). Note: Regulation (EC) No 519/2012 is repealed with Regulation (EU) No 2020/2096.
Regulation (EU) No 2020/2096: entries 22, 67 and 68 have been deleted (substances severely restricted under Regulation (EU) No 2019/1021 on persistent organic pollutants). See Regulation (EU) No 2020/2096.

Last updated 12 December 2023. Database contains 73 unique substances/entries.

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Substance name	EC No.	CAS No.	Entry no.	Appendices
Inorganic ammonium salts show/hide Vanadate(3-), hexafluoro-, triammonium salt EC No.: 621-084-0 \| CAS No.: 13815-31-1 Ammonium tetrathiotungstate [(NH4)2WS4] EC No.: 628-727-4 \| CAS No.: 13862-78-7 Molybdate(2-), tetrathioxo-, diammonium, (T-4)- EC No.: 640-219-4 \| CAS No.: 15060-55-6 Sulphuric acid, ammonium magnesium salt EC No.: 244-089-6 \| CAS No.: 20861-69-2 Ammonium samarium(3+) disulphate EC No.: 244-699-2 \| CAS No.: 21995-29-9 Ammonium europium(3+) disulphate EC No.: 244-700-6 \| CAS No.: 21995-30-2 Ammonium gadolinium(3+) disulphate EC No.: 244-701-1 \| CAS No.: 21995-31-3 Ammonium lanthanum(3+) disulphate EC No.: 244-702-7 \| CAS No.: 21995-32-4 Ammonium praseodymium(3+) disulphate EC No.: 244-703-2 \| CAS No.: 21995-33-5 Ammonium neodymium(3+) disulphate EC No.: 244-704-8 \| CAS No.: 21995-34-6 Triammonium triiron tetracitrate EC No.: 257-857-0 \| CAS No.: 52336-55-7 Ammonium iron tetrachloride EC No.: 246-234-9 \| CAS No.: 24411-12-9 Diammonium hexabromoosmate(2-) EC No.: 246-340-5 \| CAS No.: 24598-62-7 Ammonium nickel trichloride EC No.: 246-378-2 \| CAS No.: 24640-21-9 Acetic acid, ammonium zinc salt EC No.: 246-492-2 \| CAS No.: 24846-92-2 Diammonium aquapentachlororuthenate EC No.: 247-008-2 \| CAS No.: 25461-53-4 Ammonium bismuth citrate EC No.: 247-078-4 \| CAS No.: 25530-63-6 Triammonium diaquaoctachloro-μ-nitridodiruthenate(3-) EC No.: 248-399-2 \| CAS No.: 27316-90-1 Ammonium bis(cyano-C)aurate EC No.: 250-464-5 \| CAS No.: 31096-40-9 Ammonium tetrachloroaurate EC No.: 250-476-0 \| CAS No.: 31113-23-2 Citric acid, ammonium bismuth salt EC No.: 250-856-6 \| CAS No.: 31886-41-6 Triammonium tris[carbonato(2-)-O]hydroxyzirconate(3-) EC No.: 251-086-3 \| CAS No.: 32535-84-5 Ammonium chromic sulfate dodecahydrate EC No.: 680-414-1 \| CAS No.: 10022-47-6 Nickel ammonium sulfate hexahydrate EC No.: 680-452-9 \| CAS No.: 7785-20-8 Ethanedioic acid, ammonium iron(3+) salt (3:3:1), trihydrate EC No.: 603-647-2 \| CAS No.: 13268-42-3 Sulfuric acid, ammonium iron(3+) salt (2:1:1), dodecahydrate EC No.: 616-517-5 \| CAS No.: 7783-83-7 Titanate(2-), bis[ethanedioato(2-)-O,O']oxo-, diammonium, monohydrate, (SP-5-21)- EC No.: 600-678-3 \| CAS No.: 10580-03-7 Struvite [(NH4)Mg(PO4).6H2O] EC No.: - \| CAS No.: 15490-91-2 Boric acid (H3BO3), ammonium salt EC No.: - \| CAS No.: 27522-09-4 Sulfuric acid, ammonium magnesium salt (3:2:2) EC No.: - \| CAS No.: 27733-50-2 azanium;lanthanum(3+);tetranitrate EC No.: - \| CAS No.: 31178-09-3 Nitric acid, ammonium cerium(4+) salt (6:2:1) EC No.: - \| CAS No.: 10139-51-2 Ammonium lanthanum nitrate EC No.: - \| CAS No.: 10169-00-3 Aluminate(2-), difluoro[phosphato(3-)-κO]-, ammonium hydrogen (1:1:1) EC No.: - \| CAS No.: 11095-65-1 Ferrate(2-), difluoro[phosphato(3-)-κO]-, ammonium hydrogen (1:1:1) EC No.: - \| CAS No.: 11095-66-2 Vanadate (V10O286-), ammonium (1:6) EC No.: - \| CAS No.: 12208-00-3 Cryptohalite EC No.: - \| CAS No.: 1309-32-6 1,2,3-Propanetricarboxylic acid, 2-hydroxy-, ammonium iron salt, hydrate EC No.: - \| CAS No.: 1332-98-5 Mixtures of a permanganate with an ammonium salt EC No.: - \| CAS No.: 13446-10-1 Phosphoric acid, ammonium cadmium salt (1:1:1) EC No.: - \| CAS No.: 14520-70-8 Ammonium magnesium arsenate EC No.: - \| CAS No.: 14644-70-3 Sulfuric acid, aluminum ammonium salt (2:1:1), tetracosahydrate EC No.: - \| CAS No.: 14725-69-0 Nickelate(1-), trichloro-, ammonium, hexahydrate EC No.: - \| CAS No.: 16122-03-5 Ammonium borate EC No.: - \| CAS No.: 22694-75-3 Selenious acid, ammonium salt (2:1) EC No.: - \| CAS No.: 25425-97-2 Sulfuric acid, ammonium sodium salt, dihydrate EC No.: - \| CAS No.: 7783-10-0 Sulfuric acid, ammonium zinc salt (2:2:1), hexahydrate EC No.: - \| CAS No.: 7783-24-6 Sulfuric acid, ammonium magnesium salt (2:2:1), hexahydrate EC No.: - \| CAS No.: 7785-18-4 Stannate(1-), trifluoro-, ammonium (9CI) EC No.: - \| CAS No.: 15660-29-4 Ammonium cerous sulfate tetrahydrate EC No.: - \| CAS No.: 10049-02-2 Chromate(1-), bis(benzenamine)tetrakis(thiocyanato-N)-, ammonium (9CI) EC No.: - \| CAS No.: 10380-20-8 Ammonium paratungstate hexahydrate EC No.: - \| CAS No.: 12208-54-7 Ammonium phosphotungstenate, trihydrate EC No.: - \| CAS No.: 12704-02-8 Ammonium 12-tungstophosphate EC No.: - \| CAS No.: 1311-90-6 Ferrate(3-), hexafluoro-, triammonium salt EC No.: - \| CAS No.: 13815-28-6 Platinate(1-), amminetrichloro-, ammonium, (SP-4-2)- EC No.: - \| CAS No.: 13820-94-5 Ammonium hexafluorogallate EC No.: - \| CAS No.: 14639-94-2 Cobalt ammonium complex EC No.: - \| CAS No.: 14695-95-5 Nitric acid, ammonium cerium(3+) salt (5:2:1) EC No.: - \| CAS No.: 15318-60-2 Tungstate(2-), dioxodithioxo-, diammonium (9CI) EC No.: - \| CAS No.: 16150-61-1 Triammonium uranyl pentafluoride EC No.: - \| CAS No.: 12062-03-2 Chromate(1-), diamminetetrakis(isothiocyanato)-, ammonium, hydrate EC No.: - \| CAS No.: 19441-09-9 Ferrate(2-), [N,N-bis[2-[bis(carboxymethyl)amino]ethyl]glycinato(3-)]-, ammonium hydrogen EC No.: - \| CAS No.: 19529-40-9 Vitaferro EC No.: - \| CAS No.: 19864-63-2 Sulfuric acid, ammonium cerium(3+) salt (2:1:1) EC No.: - \| CAS No.: 21995-38-0 Arsonic acid, methyl-, monoammonium salt EC No.: - \| CAS No.: 2321-53-1 Carbonic acid, ammoniumplutonium salt (8CI) EC No.: - \| CAS No.: 24917-46-2 Uranic acid, diammonium salt, hydrate EC No.: - \| CAS No.: 28347-83-3 1-Heptene-1-arsonic acid, 2-chloro-, monoammonium salt EC No.: - \| CAS No.: 300-88-9 Molybdate(2-),tetrafluorodioxo-, diammonium (8CI,9CI) EC No.: - \| CAS No.: 30291-63-5 Ammonium ferrocyanide trihydrate EC No.: - \| CAS No.: 32108-79-5 Ammonium Tetrachloroaluminate, NH4AlCl4 EC No.: 885-776-6 \| CAS No.: 7784-14-7 Ammonium ferric chromate EC No.: - \| CAS No.: 7789-08-4 Triammonium hexachloroiridate EC No.: 239-842-0 \| CAS No.: 15752-05-3 Ammonium hexafluorosilicate EC No.: 240-968-3 \| CAS No.: 16919-19-0 Ammonium hexafluorozirconate EC No.: 240-970-4 \| CAS No.: 16919-31-6 Diammonium hexachloroplatinate EC No.: 240-973-0 \| CAS No.: 16919-58-7 Diammonium hexachlorostannate EC No.: 241-033-2 \| CAS No.: 16960-53-5 Ammonium hexafluorotitanate EC No.: 241-036-9 \| CAS No.: 16962-40-6 Ammonium hexafluorogermanate(4) EC No.: 241-037-4 \| CAS No.: 16962-47-3 Hexaammonium heptamolybdate EC No.: 234-722-4 \| CAS No.: 12027-67-7 Ammonium wolframate EC No.: 234-732-9 \| CAS No.: 12028-06-7 Tetramanganese nitride EC No.: 234-785-8 \| CAS No.: 12033-07-7 Diammonium hexachlororhenate EC No.: 234-991-8 \| CAS No.: 12051-87-5 Tetraammonium disodium vanadate EC No.: 235-012-7 \| CAS No.: 12055-09-3 Diammonium hexachloroosmate EC No.: 235-188-5 \| CAS No.: 12125-08-5 Ammonium trivanadium octaoxide EC No.: 235-384-0 \| CAS No.: 12207-63-5 Diammonium tetratungsten tridecaoxide EC No.: 235-638-0 \| CAS No.: 12398-61-7 Tetraammonium hexamolybdate EC No.: 235-650-6 \| CAS No.: 12411-64-2 Ammonium molybdate(VI) EC No.: 236-031-3 \| CAS No.: 13106-76-8 Diammonium tetraoxotellurate EC No.: 236-622-6 \| CAS No.: 13453-06-0 Ammonium dihydrogenarsenate EC No.: 236-667-1 \| CAS No.: 13462-93-6 Ammonium potassium tartrate EC No.: 214-211-2 \| CAS No.: 1114-14-3 Ammonium iron(III) citrate EC No.: 214-686-6 \| CAS No.: 1185-57-5 Triammonium iron(3+) trioxalate EC No.: 220-952-2 \| CAS No.: 2944-67-4 Diammonium tetracyanoplatinate EC No.: 209-237-6 \| CAS No.: 562-79-8 Diammonium dioxalato(oxo)titanate EC No.: 234-174-6 \| CAS No.: 10580-02-6 Ammonium wolframate EC No.: 234-364-9 \| CAS No.: 11120-25-5 Diammonium tetraborate EC No.: 234-513-8 \| CAS No.: 12007-58-8 Ammonium bismuth(3+) 2-hydroxypropane-1,2,3-tricarboxylate(2:1:1) EC No.: 229-528-1 \| CAS No.: 6591-52-2 Tetraammonium cerium tetrakis(sulphate) EC No.: 231-567-4 \| CAS No.: 7637-03-8 Ammonium selenite EC No.: 231-983-6 \| CAS No.: 7783-19-9 Ammonium selenate EC No.: 231-985-7 \| CAS No.: 7783-21-3 Diammonium diuranium heptaoxide EC No.: 231-986-2 \| CAS No.: 7783-22-4 Triammonium hexafluoroaluminate EC No.: 232-052-7 \| CAS No.: 7784-19-2 Aluminium ammonium bis(sulphate) EC No.: 232-055-3 \| CAS No.: 7784-25-0 Diammonium hydrogenarsenate EC No.: 232-067-9 \| CAS No.: 7784-44-3 Ammonium chromate EC No.: 232-138-4 \| CAS No.: 7788-98-9 Ammonium dichromate EC No.: 232-143-1 \| CAS No.: 7789-09-5 Ammonium trioxovanadate EC No.: 232-261-3 \| CAS No.: 7803-55-6 Diammonium iron bis(sulphate) EC No.: 233-151-8 \| CAS No.: 10045-89-3 Ammonium iron phosphate EC No.: 233-255-3 \| CAS No.: 10101-60-7 Ammonium iron bis(sulphate) EC No.: 233-382-4 \| CAS No.: 10138-04-2 Ammonium chromium bis(sulphate) EC No.: 236-923-2 \| CAS No.: 13548-43-1 Diammonium lanthanum pentanitrate EC No.: 236-968-8 \| CAS No.: 13566-21-7 Diammonium manganese bis(sulphate) EC No.: 236-969-3 \| CAS No.: 13566-22-8 Ammonium diamminetetrakis(thiocyanato-N)chromate(1-) EC No.: 237-003-3 \| CAS No.: 13573-16-5 Diammonium copper(2+) disulphate EC No.: 237-021-1 \| CAS No.: 13587-25-2 Diammonium cobalt bis(sulphate) EC No.: 237-043-1 \| CAS No.: 13596-46-8 Ammonium perrhenate EC No.: 237-075-6 \| CAS No.: 13598-65-7 Diammonium gadolinium pentanitrate EC No.: 237-111-0 \| CAS No.: 13628-49-4 Ammonium calcium trinitrate EC No.: 237-425-8 \| CAS No.: 13780-11-5 Diammonium zinc disulphate EC No.: 237-483-4 \| CAS No.: 13814-87-4 Diammonium tetrachloropalladate EC No.: 237-498-6 \| CAS No.: 13820-40-1 Diammonium tetrachloroplatinate EC No.: 237-499-1 \| CAS No.: 13820-41-2 Diammonium pentachloronitrosylruthenate EC No.: 237-504-7 \| CAS No.: 13820-58-1 Bis(acetato-O)diamminecopper EC No.: 237-513-6 \| CAS No.: 13822-80-5 Ammonium tetrafluoroborate EC No.: 237-531-4 \| CAS No.: 13826-83-0 Sulphuric acid, ammonium cerium salt EC No.: 237-557-6 \| CAS No.: 13840-04-5 Ammonium pentafluorozirconate(1-) EC No.: 237-596-9 \| CAS No.: 13859-62-6 Ammonium sodium sulphate EC No.: 237-603-5 \| CAS No.: 13863-45-1 Triammonium trioxalatoferrate EC No.: 238-090-0 \| CAS No.: 14221-47-7 Triammonium hexacyanoferrate EC No.: 238-091-6 \| CAS No.: 14221-48-8 Chromic acid, ammonium salt EC No.: 238-422-4 \| CAS No.: 14445-91-1 Tetraammonium hexacyanoferrate EC No.: 238-476-9 \| CAS No.: 14481-29-9 Ammonium cobalt phosphate EC No.: 238-633-1 \| CAS No.: 14590-13-7 Ammonium iron tartrate EC No.: 238-678-7 \| CAS No.: 14635-18-8 Diammonium cerium(4+) trisulphate EC No.: 238-682-9 \| CAS No.: 14638-69-8 Diammonium tetrachlorozincate(2-) EC No.: 238-687-6 \| CAS No.: 14639-97-5 Triammonium pentachlorozincate(3-) EC No.: 238-688-1 \| CAS No.: 14639-98-6 Triammonium heptafluorozirconate(3-) EC No.: 241-283-2 \| CAS No.: 17250-81-6 Ammonium hexabromoplatinate EC No.: 241-394-6 \| CAS No.: 17363-02-9 Tetraammonium uranyl tricarbonate, of uranium depleted in uranium-235 EC No.: 241-988-5 \| CAS No.: 18077-77-5 Citric acid , ammonium nickel salt EC No.: 242-161-1 \| CAS No.: 18283-82-4 Diammonium hexachlororuthenate EC No.: 242-552-7 \| CAS No.: 18746-63-9 Diammonium hexachloropalladate EC No.: 242-854-9 \| CAS No.: 19168-23-1 Diammonium hexakis(thiocyanato)platinate EC No.: 243-002-9 \| CAS No.: 19372-45-3 Diammonium oxobis[sulphato(2-)-O]titanate(2-) EC No.: 243-090-9 \| CAS No.: 19468-86-1 Diammonium magnesium bis(sulphate) EC No.: 238-782-2 \| CAS No.: 14727-95-8 Beryllium diammonium tetrafluoride EC No.: 238-948-4 \| CAS No.: 14874-86-3 Ammonium scandium(3+) disulphate EC No.: 239-145-1 \| CAS No.: 15091-94-8 Nitric acid, ammonium calcium salt EC No.: 239-289-5 \| CAS No.: 15245-12-2 Ammonium trifluorohydroxyborate(1-) EC No.: 239-326-5 \| CAS No.: 15283-48-4 Triammonium hexachlororhodate EC No.: 239-364-2 \| CAS No.: 15336-18-2 Diammonium yttrium pentanitrate EC No.: 239-605-1 \| CAS No.: 15552-06-4 Ammonium manganese phosphate EC No.: 239-688-4 \| CAS No.: 15609-81-1 Diammonium tetrachlorocuprate EC No.: 239-690-5 \| CAS No.: 15610-76-1 Diammonium neodymium pentanitrate EC No.: 239-721-2 \| CAS No.: 15653-40-4 Diammonium tetrabromopalladate(2-) EC No.: 239-731-7 \| CAS No.: 15661-00-4 Diammonium nickel bis(sulphate) EC No.: 239-793-5 \| CAS No.: 15699-18-0	-	-	65		Details
4,4'-isopropylidenediphenol	201-245-8	80-05-7	66		Details
C9-C14 linear and/or branched perfluorocarboxylic acids (C9-C14 PFCAs), their salts and C9-C14 PFCAs-related substances, perfluorononan-1-oic acid (PFNA); nonadecafluorodecanoic acid (PFDA); henicosafluoroundecanoic acid (PFUnDA); tricosafluorododecanoic acid (PFDoDA); pentacosafluorotridecanoic acid (PFTrDA); heptacosafluorotetradecanoic acid (PFTDA); including their salts and precursors show/hide Tricosafluorododecanoic acid EC No.: 206-203-2 \| CAS No.: 307-55-1 Nonadecafluorodecanoic acid EC No.: 206-400-3 \| CAS No.: 335-76-2 Pentacosafluorotridecanoic acid EC No.: 276-745-2 \| CAS No.: 72629-94-8 Heptacosafluorotetradecanoic acid EC No.: 206-803-4 \| CAS No.: 376-06-7 Henicosafluoroundecanoic acid EC No.: 218-165-4 \| CAS No.: 2058-94-8 Perfluorononan-1-oic acid EC No.: 206-801-3 \| CAS No.: 375-95-1	-	-	68		Details
Methanol	200-659-6	67-56-1	69		Details
Octamethylcyclotetrasiloxane (D4); Decamethylcyclopentasiloxane (D5) show/hide Octamethylcyclotetrasiloxane EC No.: 209-136-7 \| CAS No.: 556-67-2 Decamethylcyclopentasiloxane EC No.: 208-764-9 \| CAS No.: 541-02-6	-	-	70		Details
1-methyl-2-pyrrolidone	212-828-1	872-50-4	71		Details
The following substances which are classified as carcinogenic, mutagenic or toxic for reproduction, category 1A or 1B (See group members) [Entry 72]	-	-	72	Appendix 12	Details
(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silanetriol and any of its mono-, di- or tri-O-(alkyl) derivatives show/hide Triethoxy(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane EC No.: 257-473-3 \| CAS No.: 51851-37-7 Trimethoxy(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane EC No.: 288-657-1 \| CAS No.: 85857-16-5	-	-	73		Details
Diisocyanates show/hide m-tolylidene diisocyanate EC No.: 247-722-4 \| CAS No.: 26471-62-5 4,4’-Methylenediphenyl diisocyanate EC No.: 202-966-0 \| CAS No.: 101-68-8 2-methyl-m-phenylene diisocyanate EC No.: 202-039-0 \| CAS No.: 91-08-7 3,3'-dimethylbiphenyl-4,4'-diyl diisocyanate EC No.: 202-112-7 \| CAS No.: 91-97-4 2,2’-Methylenediphenyl diisocyanate EC No.: 219-799-4 \| CAS No.: 2536-05-2 1,3-bis(1-isocyanato-1-methylethyl)benzene EC No.: 220-474-4 \| CAS No.: 2778-42-9 2,4’-Methylenediphenyl diisocyanate EC No.: 227-534-9 \| CAS No.: 5873-54-1 Hexamethylene diisocyanate EC No.: 212-485-8 \| CAS No.: 822-06-0 2,4,6-triisopropyl-m-phenylene diisocyanate EC No.: 218-485-4 \| CAS No.: 2162-73-4 4-methyl-m-phenylene diisocyanate EC No.: 209-544-5 \| CAS No.: 584-84-9 1,3-bis(isocyanatomethyl)benzene EC No.: 222-852-4 \| CAS No.: 3634-83-1 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate EC No.: 223-861-6 \| CAS No.: 4098-71-9 4,4'-methylenedicyclohexyl diisocyanate EC No.: 225-863-2 \| CAS No.: 5124-30-1 1,5-naphthylene diisocyanate EC No.: 221-641-4 \| CAS No.: 3173-72-6	-	-	74		Details
Substances in tattoo inks and permanent make up	-	-	75	Appendix 13	Details

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