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Physical & Chemical properties

Auto flammability

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Link to relevant study record(s)

Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
14-Jul-2014 to 30-Jul-2014
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Qualifier:
according to guideline
Guideline:
other: DIN 51 794 (2003)
GLP compliance:
yes (incl. QA statement)
Remarks:
Ministerium für Arbeit, Integration und Soziales des Landes Nordhein-Westfalen.
Auto-ignition temperature:
250 °C
Atm. press.:
1 006 hPa
Remarks on result:
other:

Results


 


Test 1

















































































Temperature (°C)



Injected volume (drops)



Time-lag until ignition (s)



300



5



2



295



5 / 10



- / 1



290



10



1



285



10



6



280



10



4



275



10



9



270



10



19



265



10 / 15



- / 25



260



15



33



255



15 / 20



- / 37



250



20



-



253



20



24



251



20



31



249



20



-



 


Test 2














































Temperature (°C)



Injected volume (drops)



Time-lag until ignition (s)



270



5 / 10 / 15



- / - / 18



265



15



27



260



15 / 20



- / 32



255



20



32



250



20



52



245



20



-



248



20



-



 


Test 3




































Temperature (°C)



Injected volume (drops)



Time-lag until ignition (s)



260



5 / 10 / 15



- / - / 23



255



15 / 20



- / 39



250



20



28



245



20



-



248



20



-



 


The measured lowest ignition temperatures of the main test are < 300°C and do not differ by more than 10°C, thus the test is satisfactory.


 


The auto-ignition temperature is defined as the lowest temperature of all single results of the main test, but reduced to the next lower multiple of 5°C.






















 



Test 1



Test 2



Test 3



Lowest ignition temperatures (°C)



251



250



250



Auto-ignition temperature (°C)



250



 


The auto-ignition temperature of the test item was determined according to EU test method A. 15 (Council Regulation (EC) NO. 440/2008, Official Journal L 142/1 2008) and DIN 51 794 (2003).


 


Auto-ignition temperature (1009 hPa): 250°C 


 

Conclusions:
An auto-ignition temperature value of 250°C at 1009 hPa was determined in a reliable study conducted according to an appropriate test protocol, and in compliance with GLP.

Description of key information

250°C at 1013 hPa (EU Method A.15)

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
250 °C

Additional information