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Diss Factsheets

Physical & Chemical properties

Surface tension

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Reference
Endpoint:
surface tension
Type of information:
experimental study
Adequacy of study:
key study
Study period:
19 Apr 2012
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.5 (Surface Tension)
GLP compliance:
no
Type of method:
ring method
Surface tension:
33 mN/m
Temp.:
23 °C
Conc.:
1 g/L

Details:

Water calibration:

Water calibration: Temp. = 25 °C, σ = 0.997 g/cm³

Surface tension of purified water, mN/m

Value 1

71.0

Value 2

70.9

Value 3

71.0

Value 4

71.0

Value 5

71.0

Value 6

70.9

Arithmetic mean

71.0

Standard deviation

0.0

Arithmetic mean 71.0 mN/m, standard deviation 0.0 mN/m (theoretical value: 71.8 mN/m →correction factor 1.0113)

First test solution

(c = 1001.6 mg/L), Temp. = 23 °C, σ = 0.997 g/cm³, age of solution = 49 min)

Surface tension of solution 1, mN/m

Value 1

33.0

Value 2

32.5

Value 3

32.5

Value 4

32.3

Value 5

32.3

Value 6

32.4

Arithmetic mean

32.5

Standard deviation

0.3

Arithmetic mean 32.5 mN/m, standard deviation 0.3 mN/m

Second test solution

 (c = 1013.6 mg/L), Temp. = 23 °C, σ = 0.997 g/cm³, age of solution = 58 min)

Surface tension of solution 2, mN/m

Value 1

33.1

Value 2

32.8

Value 3

32.7

Value 4

32.7

Value 5

32.8

Value 6

32.7

Arithmetic mean

32.8

Standard deviation

0.1

Arithmetic mean 32.8 mN/m, standard deviation 0.1 mN/m

By adjusting the temperature setting of the tensiometer, differences in the density of the liquid can be compensated automatically.

Arithmetic mean of two test solutions:                    32.7 mN/m (+ 0.2 mN/m)

Arithmetic mean corrected by calibration factor

determined via water calibration:                            33.0 mN/m

The sample was dissolved in water and tempered at 20 °C. Then the automatic measurement was initiated. The measurement was completed after 2000 seconds.

The surface tension was determined as a concentration of 1 g/L.

Description of key information

The surface tension is 33.0 mN/m at 23 °C at a concentration of 1 g/L.  

Key value for chemical safety assessment

Additional information

The surface tension was determined by the ring method according to EU Method A.5. The substance should be regarded as being surface active.