Registration Dossier
Registration Dossier
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 236-828-6 | CAS number: 13501-76-3
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
Remove contaminated or saturated clothing.
Inhalation
Following inhalation of aerosols or mist:
Move victims into fresh air.
If symptoms persist, consult a physician for treatment.
Skin contact
Wash off immediately with plenty of water.
Consult a doctor in the event of permanent skin irritation.
Eye contact
Keeping eyelid open, immediately rinse thoroughly for at least 5 minutes using plenty of water or, if necessary, eye rinsing solution.
In case of persistent discomfort: Consult an ophthalmologist.
Ingestion
Have the mouth rinsed with water.
Have patient drink plenty of water in small sips.
Consult a physician immediately.
Most important symptoms and effects, both acute and delayed
Symptoms
None known
Hazards
None known
Indication of any immediate medical attention and special treatment needed
If required, therapy of irritative effect.
After absorbing large amounts of substance:
administration of activated charcoal.
Acceleration of gastrointestinal passage
Remove contaminated or saturated clothing.
Inhalation
Following inhalation of aerosols or mist:
Move victims into fresh air.
If symptoms persist, consult a physician for treatment.
Skin contact
Wash off immediately with plenty of water.
Consult a doctor in the event of permanent skin irritation.
Eye contact
Keeping eyelid open, immediately rinse thoroughly for at least 5 minutes using plenty of water or, if necessary, eye rinsing solution.
In case of persistent discomfort: Consult an ophthalmologist.
Ingestion
Have the mouth rinsed with water.
Have patient drink plenty of water in small sips.
Consult a physician immediately.
Most important symptoms and effects, both acute and delayed
Symptoms
None known
Hazards
None known
Indication of any immediate medical attention and special treatment needed
If required, therapy of irritative effect.
After absorbing large amounts of substance:
administration of activated charcoal.
Acceleration of gastrointestinal passage
Fire-fighting measures
Suitable extinguishing media
foam, water spray, CO2, dry powder
Special hazards arising from the substance or mixture
Hazardous fumes in fires, specific to the product:
hydrogen chloride
Special protective equipment for fire-fighters
In case of fire: wear a self contained respiratory apparatus
Advice for firefighters
Water used to extinguish fire should not enter drainage systems, soil or stretches of water.
Ensure there are sufficient retaining facilities for water used to extinguish fire.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
foam, water spray, CO2, dry powder
Special hazards arising from the substance or mixture
Hazardous fumes in fires, specific to the product:
hydrogen chloride
Special protective equipment for fire-fighters
In case of fire: wear a self contained respiratory apparatus
Advice for firefighters
Water used to extinguish fire should not enter drainage systems, soil or stretches of water.
Ensure there are sufficient retaining facilities for water used to extinguish fire.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment.
Ensure adequate ventilation.
Environmental precautions
Do not allow entrance in sewage water, soil stretches of water, groundwater, drainage systems.
Methods and material for containment and cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
Fill into marked, sealable containers.
To be disposed of in compliance with existing regulations.
Suitable binder: sand (for damming up), sawdust
Use personal protective equipment.
Ensure adequate ventilation.
Environmental precautions
Do not allow entrance in sewage water, soil stretches of water, groundwater, drainage systems.
Methods and material for containment and cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
Fill into marked, sealable containers.
To be disposed of in compliance with existing regulations.
Suitable binder: sand (for damming up), sawdust
Handling and storage
Handling
Precautions for safe handling
Provide good ventilation or extraction.
Observe the rules usually applicable when handling chemicals.
Advice on protection against fire and explosion
Keep away from sources of ignition - No smoking.
Take precautionary measures against static discharges.
Storage
Conditions for safe storage, including any incompatibilities
Keep containers tightly closed in a cool, well-ventilated place.
Protect from moisture.
Precautions for safe handling
Provide good ventilation or extraction.
Observe the rules usually applicable when handling chemicals.
Advice on protection against fire and explosion
Keep away from sources of ignition - No smoking.
Take precautionary measures against static discharges.
Storage
Conditions for safe storage, including any incompatibilities
Keep containers tightly closed in a cool, well-ventilated place.
Protect from moisture.
Transport information
Shippingopen allclose all
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
Shippingopen allclose all
Remarksopen allclose all
Shippingopen allclose all
Remarksopen allclose all
Additional transport information
Additional information
- Special provisions / remarks / other:
Loading instructions/Remarks
ADR
Not classified as dangerous for conveyance in the meaning of the Carriage of Dangerous Goods by Road and Rail (ADR / RID).
RID
Not classified as dangerous for conveyance in the meaning of the Carriage of Dangerous Goods by Road and Rail (ADR / RID).
IMDG
Not classified as hazardous sea cargo (IMDG code)
IMDG
FOR USA ONLY: In packagings exceeding 450 L, this product must be classified, placarded, marked and shipped as Combustible Liquid to the USA.
IATA_C
Not hazardous freight in air traffic (ICAO-TI / IATA-DGR).
IATA_P
Not hazardous freight in air traffic (ICAO-TI / IATA-DGR).
ADN
Not hazardous freight in inland waterway traffic (ADN).
Exposure controls / personal protection
Control parameters
Engineering measures
Application, processing: Provide good ventilation or extraction.
Personal protective equipment
Respiratory protection
In case of dusts/vapours/aerosols being formed or if the limit values like TLV are exceeded:
use respiratory equipment with suitable filter (filter type ABEK) or wear a self contained respiratory apparatus
Use only respiratory protection equipment with CE-symbol including four digit test number.
The filter class for the respirator must be suitable for the maximum expected contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If this concentration is exceeded, self-contained breathing apparatus must be used.
Note time limit for wearing respiratory protective equipment.
Hand protection
Glove material for example, butyl-rubber
Material thickness 0,5 mm
Break through time >= 480 min
Glove material for example, Fluorinated rubber (Viton)
Material thickness 0,4 mm
Break through time >= 480 min
Selection of protective gloves to meet the requirements of specific workplaces.
Suitability for specific workplaces should be clarified with protective glove manufacturers.
The information is based on our own tests, references from the literature and information from glove manufacturers, or derived by analogy with similar materials.
Please observe that the daily duration of usage of a chemical protective glove is in practice far shorter due to the many influencing factors (e.g. temperature, mechanical strain on the glove material) than the permeation time determined acc. EN 374.
Eye protection
close-fitting protective goggles (e.g. closed goggles)
Skin and body protection
When handling larger quantities:
chemical protective suit, disposable protective suit
Hygiene measures
When using, do not eat, drink or smoke. Wash face and/or hands before break and end of work.
Remove contaminated or saturated clothing.
Wash contaminated clothing before re-use.
Protective measures
Handle in accordance with good industrial hygiene and safety practices.
It should be defined in the work place in the form of a risk analysis according to directive 89/686/EEC and amendments.
If workplace exposure limits are exceeded and/or larger amounts are released (leakage, spilling, dust) the indicated respiratory protection should be used.
If there is the possibility of skin/eye contact, the indicated hand/eye/body protection should be used.
Do not breathe in vapours or aerosols.
Avoid contact with skin and eyes.
Engineering measures
Application, processing: Provide good ventilation or extraction.
Personal protective equipment
Respiratory protection
In case of dusts/vapours/aerosols being formed or if the limit values like TLV are exceeded:
use respiratory equipment with suitable filter (filter type ABEK) or wear a self contained respiratory apparatus
Use only respiratory protection equipment with CE-symbol including four digit test number.
The filter class for the respirator must be suitable for the maximum expected contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If this concentration is exceeded, self-contained breathing apparatus must be used.
Note time limit for wearing respiratory protective equipment.
Hand protection
Glove material for example, butyl-rubber
Material thickness 0,5 mm
Break through time >= 480 min
Glove material for example, Fluorinated rubber (Viton)
Material thickness 0,4 mm
Break through time >= 480 min
Selection of protective gloves to meet the requirements of specific workplaces.
Suitability for specific workplaces should be clarified with protective glove manufacturers.
The information is based on our own tests, references from the literature and information from glove manufacturers, or derived by analogy with similar materials.
Please observe that the daily duration of usage of a chemical protective glove is in practice far shorter due to the many influencing factors (e.g. temperature, mechanical strain on the glove material) than the permeation time determined acc. EN 374.
Eye protection
close-fitting protective goggles (e.g. closed goggles)
Skin and body protection
When handling larger quantities:
chemical protective suit, disposable protective suit
Hygiene measures
When using, do not eat, drink or smoke. Wash face and/or hands before break and end of work.
Remove contaminated or saturated clothing.
Wash contaminated clothing before re-use.
Protective measures
Handle in accordance with good industrial hygiene and safety practices.
It should be defined in the work place in the form of a risk analysis according to directive 89/686/EEC and amendments.
If workplace exposure limits are exceeded and/or larger amounts are released (leakage, spilling, dust) the indicated respiratory protection should be used.
If there is the possibility of skin/eye contact, the indicated hand/eye/body protection should be used.
Do not breathe in vapours or aerosols.
Avoid contact with skin and eyes.
Stability and reactivity
Conditions to avoid
Vapours can form explosive mixtures with air.
Hazardous decomposition products
Ethanol in case of hydrolysis
Vapours can form explosive mixtures with air.
Hazardous decomposition products
Ethanol in case of hydrolysis
Disposal considerations
Product
With respect to local regulations, e.g. dispose of to suitable waste incineration plant.
Uncleaned packaging
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.
If there is product residue in the emptied container, follow directions for handling on the container's label.
Incorrect disposal or reuse of this container is illegal and can be dangerous.
Other countries: observe the national regulations.
Waste Key Number
No waste key number as per the European Waste Types List can be assigned to this product, since such classification is based on the (as yet undetermined) use to which the product is put by the consumer.
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
With respect to local regulations, e.g. dispose of to suitable waste incineration plant.
Uncleaned packaging
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.
If there is product residue in the emptied container, follow directions for handling on the container's label.
Incorrect disposal or reuse of this container is illegal and can be dangerous.
Other countries: observe the national regulations.
Waste Key Number
No waste key number as per the European Waste Types List can be assigned to this product, since such classification is based on the (as yet undetermined) use to which the product is put by the consumer.
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
