Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2017
Report date:
2017

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
other: Self Accelerating Decomposition (SADT) UN Test H4
GLP compliance:
yes

Test material

Constituent 1
Chemical structure
Reference substance name:
3,5,7-triaza-1-azoniatricyclo[3.3.1.13,7]decane nitrate
EC Number:
687-538-5
Cas Number:
18423-20-6
Molecular formula:
C6H13N5O3
IUPAC Name:
3,5,7-triaza-1-azoniatricyclo[3.3.1.13,7]decane nitrate
Specific details on test material used for the study:
3% water

Results and discussion

Relative self-ignition temperature (solids)
Key result
Remarks on result:
other: Performed Self Accelerating Decomposition UN Test H4 shows Hexamine nitrate SADT is 90ºC.
Remarks:
According to CLP 2.8.2.1. any self-reactive substance or mixture shall be considered for classification in this class as a self-reactive substance or mixture unless their self-accelerating decomposition temperature (SADT) is greater than 75 ºC for a 50 kg package.

Applicant's summary and conclusion

Conclusions:
According to CLP 2.8.2.1.(e) Hexamine nitrate shall not be considered for classification in this class (SADT is greater than 75 ºC )