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Vapour pressure

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2008-08-07 to 2008-11-07
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Deviations:
no
Qualifier:
according to guideline
Guideline:
EPA OPPTS 830.7950 (Vapor Pressure)
Deviations:
no
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Version / remarks:
2006
Deviations:
no
GLP compliance:
yes
Type of method:
effusion method: vapour pressure balance
Key result
Test no.:
#2
Temp.:
25 °C
Vapour pressure:
0 Pa
Key result
Test no.:
#1
Temp.:
20 °C
Vapour pressure:
0 Pa
Key result
Vapour pressure:
0 Pa
Remarks on result:
not determinable

Vapour Pressure Balance (Effusion Method)


The vapour pressure was measured in the temperature range of 28°C to 123°C. Above 72°C areasonable vapour pressure could be measured. The measured vapour pressures at thecorresponding temperatures are listed in the following table:


















































Temperature / oc



Vapour pressure / hPa



72.4



8.3 x 10-6



76.3



1.2 x 10-5



81.0



2.1 x 10-5



87.8



4.6 x 10-5



94.0



1 x 10-4



100.0



2.1 x 10-4



105.1



3.7 x 10-4



112.4



7.0 x 10-4



120.6



1.4 x 10-3



123.0



1.7 x 10-3



The figure 2 gives the logarithm of the vapour pressure as a function of the inversetemperature (1/T, T in Kelvin). Only for better readability the temperature is reported in a centigradescale. The values for 20, 25 and 50°C are calculated, using the Antoine constants A, B and C as shown there


Final Results


Vapour Pressure


The following vapour pressure values for Pencycuron (pure substance) were extrapolated from theexperimental data:


























 



p /hPa



p/ Pa



20



4.0 x 10-9



4.0 x 10-7



25



9.3 x 10-9



9.3vx 10-7



50



4.2 10-7



4.2 x 10-5


Conclusions:
Vapour pressure is 4.0 x 10-7 pa at 20°C

Description of key information

Vapour pressure is 4.0 x 10-7 Pa at 20°C

Key value for chemical safety assessment

Vapour pressure:
0 Pa
at the temperature of:
20 °C

Additional information