1-[2-(2-chloroethoxy)phenylsulfonyl]-3-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)urea;triasulfuron (ISO)

Guidance on Safe Use

First-aid measures

1. Description of first aid measures
General advice: Have the product container, label or Safety Data Sheet with you when calling the emergency number, a poison control center or physician, or going for treatment.

If inhaled: Move the victim to fresh air.
If breathing is irregular or stopped, administer artificial respiration.
Keep patient warm and at rest.
Call a physician or poison control centre immediately.

In case of skin contact: Take off all contaminated clothing immediately.
Wash off immediately with plenty of water.

If skin irritation persists, call a physician.
Wash contaminated clothing before re-use.
In case of eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses.
Immediate medical attention is required.

If swallowed: If swallowed, seek medical advice immediately and show this container or label.
Do NOT induce vomiting.

2． Most important symptoms and effects, both acute and delayed
Symptoms: Nonspecific
No symptoms known or expected.
3．Indication of any immediate medical attention and special treatment needed
Treatment: There is no specific antidote available.
Treat symptomatically.

Fire-fighting measures

1. Extinguishing media
Suitable extinguishing media:
Extinguishing media - small fires
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Extinguishing media - large fires
Alcohol-resistant foam
Unsuitable extinguishing media:
Do not a solid water stream as it may scatter and spread fire.
2. Special hazards arising from the substance or mixture
Specific hazards during firefighting:
As the product contains combustible organic components, fire will produce dense black smoke containing hazardous products of combustion (see section 10).
Exposure to decomposition products may be a hazard to health.
Flash back possible over considerable distance.
3. Advice for firefighters
Special protective equipment for firefighters: Wear full protective clothing and self-contained breathing apparatus.
Further information : Do not allow run-off from fire fighting to enter drains or water courses.
Cool closed containers exposed to fire with water spray.

Accidental release measures

1. Personal precautions, protective equipment and emergency procedures
Personal precautions : Refer to protective measures listed in Handling and storage and Exposure controls/personal protection.
Avoid dust formation.
2. Environmental precautions
Environmental precautions : Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform respective authorities.
3. Methods and material for containment and cleaning up
Methods for cleaning up : Contain spillage, pick up with an electrically protected vacuum cleaner or by wet-brushing and transfer to a container for disposal according to local regulations (see Disposal considerations).
Do not create a powder cloud by using a brush or compressed air.
Clean contaminated surface thoroughly.

Clean with detergents. Avoid solvents.

Retain and dispose of contaminated wash water.

Handling and storage

1. Precautions for safe handling
Advice on safe handling : This material is capable of forming flammable dust clouds in air, which, if ignited, can produce a dust cloud explosion.
Flames, hot surfaces, mechanical sparks and electrostatic discharges can serve as ignition sources for this material.
Electrical equipment should be compatible with the flammability characteristics of this material. The flammability characteristics will be made worse if the material contains traces of flammable solvents or is handled in the presence of flammable solvents.
This material can become readily charged in most operations.
Avoid contact with skin and eyes.
When using do not eat, drink or smoke.
For personal protection see Exposure controls/personal protection.
2. Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers:
Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep away from food, drink and animal feedingstuffs.
3. Specific end use(s)
Specific use(s) : Active substance for use in plant protection products
Refer to protective measures listed in Handling and storage and Exposure controls/personal protection.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

UN 3077

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S

Chemical name:

Triasulfuron

Language:

English

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

Labels:

9

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

UN 3077

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S

Chemical name:

Triasulfuron

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

Labels:

9

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

UN 3077

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S

Chemical name:

Triasulfuron

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

EmS code:

F-A

S-F

Labels:

9

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

UN 3077

Shipping information

Proper shipping name and description:

Environmentally hazardous substance, solid, n.o.s.

Chemical name:

Triasulfuron

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

Labels:

Miscellaneous

Remarks

SpecialProvisions

Exposure controls / personal protection

Engineering measures
Containment and/or segregation is the most reliable technical protection measure if exposure
cannot be eliminated.
The extent of these protection measures depends on the actual risks in use.
Maintain air concentrations below occupational exposure standards.
Where necessary, seek additional occupational hygiene advice.
Personal protective equipment
Eye protection : No special protective equipment required.
Hand protection Remarks : No special protective equipment required.
Skin and body protection : No special protective equipment required.
Select skin and body protection based on the physical job requirements.
Respiratory protection : No personal respiratory protective equipment normally required.
When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.
Protective measures : The use of technical measures should always have priority over the use of personal protective equipment.
When selecting personal protective equipment, seek appropriate professional advice.

Stability and reactivity

Reactivity: None reasonably foreseeable.
Chemical stability: Stable under normal conditions.
Possibility of hazardous reactions
Hazardous reactions: No dangerous reaction known under conditions of normal use.
Conditions to avoid: No decomposition if used as directed.
Incompatible materials
Materials to avoid: None known.
Hazardous decomposition products: No hazardous decomposition products are known.

Disposal considerations

Waste treatment methods
Product : Where possible recycling is preferred to disposal or incineration.
It must undergo special treatment, e.g. at suitable disposal site, to comply with local regulations.
Contaminated packaging : Dispose of as unused product.