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Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
13-14 Aug 2014
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
GLP compliance:
yes (incl. QA statement)
Remarks:
Hess. Ministerium für Umwelt, Landwirtschaft und Forsten, Wiesbaden, Germany
Relative self-ignition temperature:
> 400 °C
Remarks on result:
no self ignition observed under the test conditions

The test item showed an endothermal effect in the temperature range 165 °C to 197 °C which was directly followed by an exothermal effect in the temperature range from 197 °C to 205 °C with a maximum peak temperature of 317 °C. According to EU Method A.16, the exothermic effect has not to be classified as self-ignition. No further endothermic effects or exothermic effects were observed up to 401 °C (final oven temperature of the test).


Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
supporting study
Study period:
14 Jun - 14 Aug 2000
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Qualifier:
according to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
GLP compliance:
yes
Relative self-ignition temperature:
> 400 °C
Remarks on result:
no self ignition observed under the test conditions

An endothermic effect was observed at 163 °C, followed by exothermic decomposition at 190 °C. The maximum reaction temperature was 293 °C.

The substance is determined as not undergoing spontaneous combustion when tested according to this procedure.


Description of key information

no self-ignition up to the temperature of 401 °C

Key value for chemical safety assessment

Additional information

The substance was not self-ignitable in a test according to EU A.16. This was confirmed in an earlier test according to the same guideline.