Registration Dossier
Registration Dossier
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EC number: - | CAS number: -
Stability: thermal, sunlight, metals
Administrative data
Link to relevant study record(s)
- Endpoint:
- thermal stability
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- April 2020
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
- Qualifier:
- according to guideline
- Guideline:
- other: UN manual on tests and criteria H.2
- GLP compliance:
- no
- Test substance thermally stable:
- no
- Key result
- Operating temp.:
- > 75 °C
- Remarks on result:
- other: SADT (self-accelerating decomposition temperature)
- Sublimation:
- not determined
- Transformation products:
- not measured
- Conclusions:
- The SADT was >75 °C following UN test H.2 with an estimated heat loss of 30 mWkg/K (noninsulated
standard 50 kg package). - Executive summary:
Due to an energy release in the DSC-measurement >300 J/g the SADT was determined for
classification.
The SADT was >75 °C following UN test H.2 with an estimated heat loss of 30 mWkg/K (noninsulated
standard 50 kg package).
UN Transport Regulations: The test item does not have to be classified as "self-reactive substance"
(class +.1idue to its SADT >75'C (non-insulated standard 50 kg package).
EU-GHS/CLP: The test item does not have to be classified as "self-reactive substance" due to its
SADT >75 °C (non-insulated standard 50 kg package).
- Endpoint:
- thermal stability
- Type of information:
- experimental study
- Adequacy of study:
- supporting study
- Study period:
- April 2020
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
- Qualifier:
- according to guideline
- Guideline:
- other: UN Recommendation on the Transport of Dangerous Goods - Manual of Tests and Criteria
- Version / remarks:
- rev. 7 (2019)
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- OECD Guideline 113 (Screening Test for Thermal Stability and Stability in Air)
- GLP compliance:
- no
- Test substance thermally stable:
- no
- Key result
- Operating temp.:
- >= 20 - <= 400 °C
- Remarks on result:
- other: The test item showed an exothermal effect starting at 175 °C with an energy of up to 594 J/g in closed DSC-measurements
- Sublimation:
- not determined
- Transformation products:
- not measured
- Conclusions:
- The energy release was >300J/g (maximum 594Jlg starting at 175"C).
- Executive summary:
The thermal stability was investigated by differential scanning calorimeter (DSC) in closed glass
crucibles with a heating rate of 3 l(min. The energy
release was >300J/g (maximum 594Jlg starting at 175"C). Therefore, the
determination of the SADT was performed.
Referenceopen allclose all
| No | Weight /mg | final Temp. /°C | Temp. Range / °C | Type of effect | Energy J/g |
| 1 | 12.79 | 400 | 180-300 | exothermal | 506 |
| 2 | 13.11 | 400 | 175-305 | exothermal | 594 |
Description of key information
The SADT was >75 "C following UN test H.2 with an estimated heat loss of 30 mWkg/K (noninsulated
standard 50 kg package).
The energy release was >300J/g (maximum 594Jlg starting at 175"C).
Additional information
Justification for classification or non-classification
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
