(3R)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-amine

Guidance on Safe Use

First-aid measures

Description of first aid measures

General advice
Move out of dangerous area. Place and transport victim in stable position (lying sideways). Remove contaminated clothing immediately and dispose of safely. First Aid responders should pay attention to self-protection and use the recommended protective clothing.

 

Inhalation
Move to fresh air. Keep patient warm and at rest. Call a physician or poison control center immediately.

 

Skin contact
Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water. Call a physician or poison control center immediately.

 

Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a physician or poison control center immediately.

 

Ingestion
Rinse mouth. Do NOT induce vomiting. Call a physician or poison control center immediately.

Fire-fighting measures

Extinguishing media

Suitable
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

 

Unsuitable
High volume water jet

 

Special hazards arising from the substance or mixture
In the event of fire the following may be released: Nitrogen oxides (NOx), Carbon monoxide (CO), Carbon dioxide (CO2)

 

Advice for firefighters

Special protective equipment for firefighters
In the event of fire, wear self-contained breathing apparatus. Wear self-contained breathing apparatus and protective suit.

 

Further information
Contain the spread of the fire-fighting media. Do not allow run-off from fire fighting to enter drains or water courses.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Avoid contact with spilled product or contaminated surfaces. Use personal protective equipment. Remove all sources of ignition.

 

Environmental precautions
Do not allow to get into surface water, drains and ground water.

 

Methods and materials for containment and cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).

Handling and storage

This substance is handled under Strictly Controlled Conditions in accordance with  REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4).  Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.  

 

Precautions for safe handling. Advice on safe handling
Use only in area provided with appropriate exhaust ventilation.

 

Hygiene measures
Avoid contact with skin, eyes and clothing. Keep working clothes separately. Wash thoroughly with soap and water after handling. Remove soiled clothing immediately and clean thoroughly before using again. Garments that cannot be cleaned must be destroyed (burnt).

Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
Store in original container. Keep containers tightly closed in a cool, well-ventilated place. Store in a place accessible by authorized persons only. Keep away from direct sunlight.

Advice on common storage
Keep away from food, drink and animal feedingstuffs.

 

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

3082

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

Chemical name:

(R)-2,3-DIHYDRO-1,1,3-TRIMETHYLINDEN-4-AMINE

Language:

English

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

Labels:

Packaging 9 + EHS
Bulk 9+ EHS
Haz ID 90

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

3082

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

Chemical name:

(R)-2,3-DIHYDRO-1,1,3-TRIMETHYLINDEN-4-AMINE)

Language:

English

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

Labels:

Packaging 9 + EHS
Bulk 9+ EHS
Haz ID 90

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

3082

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

Chemical name:

(R)-2,3-DIHYDRO-1,1,3-TRIMETHYLINDEN-4-AMINE)

Language:

English

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

EmS code:

F-A

S-F

Labels:

Packaging, Bulk: 9

Marine pollutant

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

3082

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

Chemical name:

(R)-2,3-DIHYDRO-1,1,3-TRIMETHYLINDEN-4-AMINE)

Language:

English

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

Labels:

Packaging 9 + EHS

Remarks

SpecialProvisions

Exposure controls / personal protection

This substance is handled under Strictly Controlled Conditions in accordance with  REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4).  Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.

 

 

Exposure controls: 

Respiratory protection: If product is handled while not enclosed, and if contact may occur:

Wear respirator with an organic vapours and gas filter mask (protection factor 10) conforming to EN140 type A or equivalent.
Respiratory protection should only be used to control residual risk of short duration activities, when all reasonably practicable steps have been taken to reduce exposure at source e.g. containment and/or local extract ventilation. Always follow respirator manufacturer's instructions regarding wearing and maintenance.

 

Hand protection: Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. Wash gloves when contaminated. Dispose of when contaminated inside, when perforated or when contamination on the outside cannot be removed. Wash hands frequently and always before eating, drinking, smoking or using the toilet.

Material	Nitrile rubber
Rate of permeability	> 480 min
Glove thickness	> 0,4 mm
Protective index	Class 6
Directive	Protective gloves complying with EN 374.

Eye protection: Wear goggles (conforming to EN166, Field of Use = 5 or equivalent).

 

Skin and body protection: Wear standard coveralls and Category 3 Type 4 suit. If there is a risk of significant exposure, consider a higher protective type suit. Wear two layers of clothing wherever possible. Polyester/cotton or cotton overalls should be worn under chemical protection suit and should be professionally laundered frequently.

If chemical protection suit is splashed, sprayed or significantly contaminated, decontaminate as far as possible, then carefully remove and dispose of as advised by manufacturer.

General protective measures: If product is handled while not enclosed, and if contact may occur: Complete suit protecting against chemicals

Stability and reactivity

Chemical stability: Stable under recommended storage conditions

Thermal decomposition / conditions to be avoided: No decomposition if used as directed. Stable at ambient temperature.

 

Possibility of hazardous reactions: No hazardous reactions when stored and handled according to prescribed instructions.

 

Conditions to avoid: Extremes of temperature and direct sunlight.

 

Incompatible materials: Strong oxidizing agents. Store only in the original container.

 

Hazardous decomposition products: No decomposition products expected under normal conditions of use.

 

Disposal considerations

During the whole life cycle of the substance all necessary measures in accordance to art. 18(4) of (EC) 1907/2006 are undertaken. The substance is handled under strictly controlled conditions.

 

Dispose in accordance with current regulations and, if necessary, after consultation with the site operator and/or with the responsible authority, the product may be taken to a waste disposal site or incineration plant.