Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Hydrolysis

Currently viewing:

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
hydrolysis
Data waiving:
study technically not feasible
Justification for data waiving:
other:
Justification for type of information:
No evaluation of the hydrolytic stability of the test item in aqueous media was possible by Method C.7 Abiotic Degradation, Hydrolysis as a Function of pH of Commission Regulation (EC) No 440/2008 of 30 May 2008 and Method 111 of the OECD Guidelines for Testing of Chemicals, 13 April 2004. This was due to the absence of a suitable substance specific analytical method with which to evaluate the intact test item chelate.

The test substance shows a very quickly occurring hydrolysis or an alternative transformation mechanism (e.g. ligand exchange) as shown by the results of the solubility study and the detection of the partition coefficient.
It can be assumed that the white translucent hydrated solid precipitate obtained is probably constituted by Ti(OH)4. The organic ligands (Ethyl acetoacetate, Pentane-2,4-diol, Propane-1,3-diol) are well soluble in water. In consequence of the rapid abiotic reaction, the analysis of the hydrolysis of the intrinsic hydrolysis of the substance was technically not feasible.

Description of key information

No evaluation of the hydrolytic stability of the test item in aqueous media was possible. This was due to the absence of a suitable substance specific analytical method with which to evaluate the intact test item chelate.

Key value for chemical safety assessment

Additional information