Registration Dossier
Registration Dossier
Diss Factsheets
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EC number: 237-997-9 | CAS number: 14154-09-7
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data

Guidance on Safe Use
Administrative data
First-aid measures
General information: Get medical attention if any discomfort continues.
Inhalation
Move the exposed person to fresh air at once. Get medical attention.
Ingestion
DO NOT INDUCE VOMITING! Remove victim immediately from source of exposure. Drink plenty of water.
Skin contact
Remove affected person from source of contamination. Seek medical attention if symptoms occur after washing. Remove contaminated clothes and rinse skin thoroughly with water.
Eye contact
Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly
wash eyes with plenty of water while lifting the eye lids. Get medical attention immediately. Continue to rinse.
Most important symptoms and effects, both acute and delayed
Prolonged or frequent inhalation may cause permanent damage to the nervous system, including the brain.
Irritating to the eyes.
Fire-fighting measures
Extinguishing media
Use fire-extinguishing media appropriate for surrounding materials. Water spray, fog or mist.
Unsuitable extinguishing media
Extinguishers of the chlorinated hydrocarbon variety are not recommended as toxic products may be produced by the decomposition of the extinguishing medium when it comes into contact with hot manganese compounds.
Advice for firefighters
Special Fire Fighting Procedures: Keep run-off water out of sewers and water sources. Dike for water control.
Protective equipment for fire-fighters: Self contained breathing apparatus and full protective clothing must be worn in case of fire.
Accidental release measures
Personal precautions, protective equipment and emergency procedures: Provide adequate ventilation. Use protective gloves, goggles and suitable protective clothing.
Environmental precautions: Do not discharge onto the ground or into water courses.
Methods and material for containment and cleaning up: Do not contaminate water sources or sewer. Remove spillage with vacuum cleaner. If not possible, collect spillage with shovel, broom or the like. Ensure that waste and contaminated materials are collected and removed from the work area as soon as possible in a suitably labelled container.
Handling and storage
Avoid spilling, skin and eye contact. Use mechanical ventilation in case of handling which causes formation of dust. Avoid inhalation of dust. Wash hands before eating. Wear full protective clothing for prolonged exposure and/or high concentrations.
Store in a cool and well-ventilated place. Store in a dry place. Keep containers tightly closed.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Engineering measures
Provide adequate ventilation. Observe occupational exposure limits and minimize the risk of inhalation of dust.
Respiratory equipment
Respiratory protection must be used if air contamination exceeds acceptable level.
Hand protection
Use suitable protective gloves if risk of skin contact.
Eye protection
Wear tight-fitting goggles or face shield.
Other Protection
Provide eyewash, quick drench.
Stability and reactivity
Stable under the prescribed storage conditions.
Disposal considerations
Dispose of waste and residues in accordance with local authority requirements. Residues and empty containers should be taken care of as
hazardous waste according to local and national provisions.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.

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