Registration Dossier
Registration Dossier
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EC number: 206-687-5 | CAS number: 367-25-9
Guidance on Safe Use
Administrative data
First-aid measures
4.1 Description of first aid measures
General advice
Move out of dangerous area. Place and transport victim in stable position (lying sideways). Remove contaminated clothing immediately and dispose of safely. First Aid responders should pay attention to self-protection and use the recommended protective clothing
Inhalation
Move to fresh air. Keep patient warm and at rest. Call a physician or poison control center immediately.
Skin contact
Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water. Call a physician or poison control center immediately.
Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a physician or poison control center immediately.
Ingestion
Rinse mouth. Do NOT induce vomiting. Call a physician or poison control center immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms
The following symptoms may occur:, Cyanosis
4.3 Indication of any immediate medical attention and special treatment needed
Risks
Danger of formation of methaemoglobin.
Treatment
Treat symptomatically. Oxygen or artificial respiration if needed. Keep respiratory tract clear.
Fire-fighting measures
5.1 Extinguishing media
Suitable
Water spray, Dry chemical, Foam, Carbon dioxide (CO2)
5.2 Special hazards arising from the substance or mixture
The product is combustible.
5.3 Advice for firefighters
Special protective equipment for firefighters
In the event of fire and/or explosion do not breathe fumes. Wear self-contained breathing apparatus and protective suit.
Further information
Contain the spread of the fire-fighting media. Do not allow run-off from fire fighting to enter drains or water courses.
Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Precautions
Avoid contact with spilled product or contaminated surfaces. Use personal protective equipment. Remove all sources of ignition.
6.2 Environmental precautions
Do not allow to get into surface water, drains and ground water.
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Collect and transfer the product into a properly labelled and tightly closed container. Clean contaminated floors and objects thoroughly, observing environmental regulations.
Handling and storage
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.
Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate.
7.1 Precautions for safe handling
Advice on safe handling
Use only in area provided with appropriate exhaust ventilation.
Hygiene measures
Avoid contact with skin, eyes and clothing. Keep working clothes separately. Wash thoroughly with soap and water after handling. Remove soiled clothing immediately and clean thoroughly before using again. Garments that cannot be cleaned must be destroyed (burnt).
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
Store in original container. Keep containers tightly closed in a cool, well-ventilated place. Store in a place accessible by authorized persons only. Keep away from direct sunlight.
Advice on common storage
Keep away from food, drink and animal feedingstuffs.
7.3 Specific end use(s)
Refer to the label and/or leaflet.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 2941
Shipping information
- Proper shipping name and description:
- FLUOROANILINES
- Chemical name:
- FLUOROANILINES
- Language:
- English
- Labels:
- Packaging 6.1 + EHS
Bulk 6.1 + EHS
Haz ID 60
EAC 2X
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 2941
Shipping information
- Proper shipping name and description:
- FLUOROANILINES
- Chemical name:
- FLUOROANILINES
- Language:
- English
- Labels:
- Packaging 6.1 + EHS
Bulk 6.1 + EHS
Haz ID 60
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 2941
Shipping information
- Proper shipping name and description:
- FLUOROANILINES
- Chemical name:
- FLUOROANILINES
- Labels:
- Packaging 6.1, P
Bulk 6.1 , P - Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 2941
Shipping information
- Proper shipping name and description:
- FLUOROANILINES
- Chemical name:
- FLUOROANILINES
- Labels:
- Packaging 6.1
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.
Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate.
8.1 Control parameters
No known occupational limit values.
8.2 Exposure controls
Respiratory protection
If product is handled while not enclosed, and if contact may occur:
Wear respirator with an organic vapours and gas filter mask (protection factor 10) conforming to EN140 type A or equivalent.
Hand protection
Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time.
Wash gloves when contaminated. Dispose of when contaminated inside, when perforated or when contamination on the outside cannot be removed. Wash hands frequently and always before eating, drinking, smoking or using the toilet.
Material
Nitrile rubber
Rate of permeability
> 480 min
Glove thickness
> 0,4 mm
Protective index
Class 6
Directive
Protective gloves complying with EN 374.
Eye protection
Wear goggles (conforming to EN166, Field of Use = 5 or equivalent) and faceshield (conforming to EN166, Field of Use = 3 or equivalent).
Skin and body protection
Wear standard coveralls and Category 3 Type 4 suit.
If there is a risk of significant exposure, consider a higher protective type suit.
Wear two layers of clothing wherever possible. Polyester/cotton or cotton overalls should be worn under chemical protection suit and should be professionally laundered frequently.
If chemical protection suit is splashed, sprayed or significantly contaminated, decontaminate as far as possible, then carefully remove and dispose of as advised by manufacturer.
Stability and reactivity
10.1 Reactivity
Not applicable
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No hazardous reactions when stored and handled according to prescribed instructions.
10.4 Conditions to avoid
Extremes of temperature and direct sunlight.
10.5 Incompatible materials
Store only in the original container.
10.6 Hazardous decomposition products
No decomposition products expected under normal conditions of use.
Disposal considerations
Responsibility of Toller
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
