Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

First-aid measures

Eyes: Flush eyes with copious amounts of water for at least 15 minutes. Remove any contact lenses and open eyelids widely. Seek medical attention, if irritation persist.Skin:remove contaminated clothes. Wash skin with water and soap. Seek medical attention in case of signt of toxic effects.Ingestion:Immediately ribnse mouth and drink 1-2 glasses of water. Keep person under observation. If uncomfortable: Seek hospital. Provokse vomiting, provided the injured is conscious.Inhalation:Bring injured person into fresh air and keep person calm and under observation. If uncomfortable: Seek hospital.

Fire-fighting measures

Recommended extinguishing agents:Extinguish with carbon dioxide or dry powder.Products arising from burning or pyrolysis: Very toxic vapours may be formed (COx, NOx, HCN, F)Protective equipment:Full breathing protection, gloves, goggles.

Accidental release measures

Avoid contact with skin and eyes. Avoid inhalation of dust. Use personal protection (e.g. gloves, safety goggles adn breathing apparatus). Do not discharge into drains, water courses or on the ground. Isolate the spillage. Use vacuum cleaner. If this is not possible, humidify the dust with very little water and transfer spillage to closed containers. Dispose-off waste accroding to national, state and local regulations.

Handling and storage

Handling:Inhalation of dust and contact with skin and eyes should be avoided. Work practice should minimise contact. Adequate ventilation is required. Inhalation of dust should be minimised. In case of ventilation and work of brief duration, suitable respiratory equipement should be used (particle filter, type 3). Protective gloves and goggles/face shield should be used. Special working clothing should be used. Hands should be washed after handling.Storage:Should be stored in original containers in a dry place.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (1-[2-(2,4-Dimethylphenylsulfanyl)-phenyl]piperazine (base).)
Chemical name:
1-[2-(2,4-Dimethylphenylsulfanyl)-phenyl]piperazine (base).
Labels:
9
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (1-[2-(2,4-Dimethylphenylsulfanyl)-phenyl]piperazine (base).)
Chemical name:
1-[2-(2,4-Dimethylphenylsulfanyl)-phenyl]piperazine (base).
Labels:
9
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (1-[2-(2,4-Dimethylphenylsulfanyl)-phenyl]piperazine (base).)
Chemical name:
1-[2-(2,4-Dimethylphenylsulfanyl)-phenyl]piperazine (base).
Labels:
9
Marine pollutant
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (1-[2-(2,4-Dimethylphenylsulfanyl)-phenyl]piperazine (base).)
Chemical name:
1-[2-(2,4-Dimethylphenylsulfanyl)-phenyl]piperazine (base)
Labels:
9
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Working environment:All rooms are well ventilated and with local process ventilation, where appropriate. Cleaning procedures are in force everywhere (GMP production).Direct exposure to (R,S)-Dicarbinol hemisulfate only when discharging filtered material into bags in seperate room .Exposure will be potential direct skin contact and inhalation of dust. Personal protection at discharge into drums: Disposable suit, working shoes, gloves, breathing apparatus.Minor, potential exposure occurs when handling process waste, waste water, sampling for quality and process control, at laboratory work, cleaning and at maintenance of process equipment. Personal equipment elsewhere: Working clothes with long sleeves, gloves where risk of skin contact, goggles where risk of eye contact, breathing apparatus where risk of exposure to dust or solvents.

Stability and reactivity

Dust explosion determined by test: N

Disposal considerations

Environment:Process water, may be directed to external disposal (organic liquid waste from centrifuge) or in part to our biological treatment plant (aqueous phase after quenching of Grignard reactant). All air from vacuum pumps and other high concentration sources passes through multistep scrubber system.Ventilation air passes absolute filters (HEPA). All chemical waste materials and process water containing solvents or dissolved chemicals are sent to external incineration.