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EC number: 947-394-9 | CAS number: -
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data

Oxidising properties
Administrative data
Link to relevant study record(s)
- Endpoint:
- oxidising solids
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 22nd April - 20th May 1994
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.17 (Oxidising Properties (Solids))
- Version / remarks:
- Commission Directive 92/69/EEC
- Deviations:
- yes
- Remarks:
- Due to the nature of the test item it was not practical to dry the test item to constant weight before mixing with cellulose. Instead, the test item was mixed with cellulose and the mixtures dried to contant weight.
- GLP compliance:
- yes (incl. QA statement)
- Contact with:
- powdered cellulose
- Sample tested:
- test mixture as specified
- Remarks:
- 2:1 sample to cellulose ratio
- Parameter:
- preliminary test
- Result:
- 301 s
- Remarks on result:
- other:
- Remarks:
- Sample cone burned with a blue/orange flame which self-extinguished after 301 seconds
- Sample tested:
- test mixture as specified
- Remarks:
- 10% - 90% mixtures of test item with cellulose
- Parameter:
- maximum burning rate
- Result:
- 0.606 mm/s
- Sample tested:
- reference mixture as specified
- Remarks:
- 10%-90% mixtures of barium nitrate with cellulose
- Parameter:
- maximum burning rate
- Result:
- 1.77 mm/s
- Sample tested:
- test mixture as specified
- Remarks:
- test item: cellulose ratio = 20:80
- Parameter:
- maximum burning rate
- Result:
- 0.465 mm/s
- Remarks on result:
- other:
- Remarks:
- Fastest burning rate mixtures
- Sample tested:
- test mixture as specified
- Remarks:
- test item: cellulose ratio = 10:90
- Parameter:
- maximum burning rate
- Result:
- 0.508 mm/s
- Remarks on result:
- other:
- Remarks:
- 2nd test fastest burning rate mixtures
- Sample tested:
- test mixture as specified
- Remarks:
- test item: cellulose ratio = 30:70
- Parameter:
- maximum burning rate
- Result:
- 0.422 mm/s
- Remarks on result:
- other:
- Remarks:
- 3rd test fastest burning rate mixutres
- Interpretation of results:
- GHS criteria not met
- Conclusions:
- The test item does not have oxidising properties.
- Executive summary:
The oxidative properties of the test item were determined in a study performed according to Method A.17 of Commission Directive 92/69/EEC.
Reference
In the preliminary test the sample cone burned with a blue/orange flame which self-extinguished after 301 seconds leaving black remains which emitted grey smoke.
The burning times below are for 200 mm propagation after an initial burning distance of 30 mm:
REFERENCE MIXTURES:
% Barium nitrate |
Observations |
Burning times (s) |
Burning rate (mm/s) |
10 |
The pile burned with an orange/blue flame which emitted white smoke and left grey/black remains |
323 |
0.619 |
20 |
The pile burned with an orange/blue flame which emitted white smoke and left grey/black remains |
269 |
0.743 |
30 |
The pile burned with an orange/green/blue flame which emitted white smoke and left grey/white/black remains |
258 |
0.775 |
40 |
The pile burned with an orange/green/blue flaring flame which emitted white smoke and left grey/white/black remains |
291 |
0.687 |
50 |
The pile burned with a large flaring green/orange flame which emitted white smoke and left grey/white remains |
181 |
1.105 |
60 |
The pile burned with a large orange/green flame which emitted white smoke and left grey/white remains |
113 |
1.770 |
70 |
The pile burned with a large orange/green flame which emitted white smoke and left grey/white remains |
196 |
1.020 |
80 |
The pile ignited but failed to propagate combustion over the initial 30 mm |
- |
- |
90 |
The pile failed to support combustion |
- |
- |
Maximum burning rate = 1.770 mm/s
TEST ITEM MIXTURES:
% Test item |
Observations |
Burning times (s) |
Burning rate (mm/s) |
10 |
The pile burned with an orange/blue flame and left black remains which emitted white smoke |
359 |
0.557 |
20 |
The pile burned with an orange/blue flame and left black remains which emitted white smoke |
330 |
0.606 |
30 |
The pile burned with an orange/blue flame and left black remains which emitted white smoke |
396 |
0.505 |
40 |
The pile burned with an orange/blue flame and left black remains which emitted white smoke |
414 |
0.483 |
50 |
The pile burned with an orange/blue flame and left black remains which emitted white smoke |
407 |
0.492 |
60 |
The pile burned with an orange/blue flame and left black remains which emitted white smoke |
502 |
0.398 |
70 |
The pile burned with an orange/blue flame and left black remains which emitted white smoke |
716 |
0.279 |
80 |
The Pile burned with an orange/blue flame which self-extinguished over 11 mm leaving black remains that emitted white smoke. |
- |
- |
90 |
The pile ignited but failed to support combustion over the initial 30 mm |
- |
- |
Maximum burning rate = 0.606 mm/s
Maximum burning rate of reference mixtures = 1.770 mm/s
REFERENCE MIXTURES:
% Barium nitrate |
Observations |
Burning times (s) |
Burning rate (mm/s) |
10 |
The pile burned with an orange/blue flame which emitted white smoke and left grey/black remains |
263 |
0.760 |
20 |
The pile burned with an orange/blue flame which emitted white smoke and left grey/black remains |
271 |
0.738 |
30 |
The pile burned with an orange/green/blue flame which emitted white/grey smoke and left grey/black/white remains |
269 |
0.743 |
40 |
The pile burned with an orange/green/blue flame which emitted white/grey smoke and left grey/black/white remains |
257 |
0.778 |
50 |
The pile burned with a green/orange flame which emitted grey/white smoke and left grey/white remains |
168 |
1.190 |
60 |
The pile burned with a green/orange flame which emitted grey/white smoke and left grey/white remains |
119 |
1.681 |
70 |
The pile burned with a green/orange flame which emitted grey/white smoke and left grey/white remains |
216 |
0.926 |
80 |
The pile ignited but failed to propagate combustion over the initial 30 mm |
- |
- |
90 |
The pile ignited but failed to propagate combustion over the initial 30 mm |
- |
- |
Maximum burning rate = 1.681 mm/s
FASTEST BURNING RATE MIXTURES:
Test item: cellulose ratio = 20:80
Test |
Observations |
Burning times (s) |
Burning rate (mm/s) |
1 |
The pile burned across the top of the pile with an orange/blue flame and left black remains which emitted white smoke |
595 |
0.336 |
2 |
The pile burned across the top of the pile with an orange/blue flame and left black remains which emitted white smoke |
541 |
0.370 |
3 |
The pile burned with a blue/orange flame and left black remains which emitted white smoke |
469 |
0.426 |
4 |
The pile burned with a blue/orange flame and left black remains which emitted white smoke |
430 |
0.465 |
5 |
The pile burned with a blue/orange flame and left black remains which emitted white smoke |
536 |
0.373 |
6 |
The pile burned with a blue/orange flame and left black remains which emitted white smoke |
468 |
0.427 |
Maximum burning rate = 0.465 mm/s
Maximum burning rate of reference mixtures = 1.681 mm/s
FASTEST BURNING RATE MIXTURES (2NDTEST):
Test item: cellulose ratio = 10:90
Test |
Observations |
Burning times (s) |
Burning rate (mm/s) |
1 |
The pile burned with a blue/orange flame and left black remains which emitted white smoke |
452 |
0.442 |
2 |
The pile burned with a blue/orange flame and left black remains which emitted white smoke |
421 |
0.475 |
3 |
The pile burned with a blue/orange flame and left black remains which emitted white smoke |
476 |
0.420 |
4 |
The pile burned with a blue/orange flame and left black remains which emitted white smoke |
423 |
0.473 |
5 |
The pile burned with a blue/orange flame and left black remains which emitted white smoke |
394 |
0.508 |
6 |
The pile burned with a blue/orange flame and left black remains which emitted white smoke |
415 |
0.482 |
Maximum burning rate = 0.508 mm/s
Maximum burning rate of reference mixtures = 1.681 mm/s
FASTEST BURNING RATE MIXTURES (3rd TEST):
Test item: cellulose ratio = 30:70
Test |
Observations |
Burning times (s) |
Burning rate (mm/s) |
1 |
The pile burned across the top with an orange/blue flame and left black remains which emitted white smoke |
478 |
0.418 |
2 |
The pile burned with an orange/blue flame and left black remains which emitted white smoke |
515 |
0.388 |
3 |
The pile burned across the top and one side with an orange/blue flame and left black remains which emitted white smoke |
474 |
0.422 |
4 |
The pile burned across the top with an orange/blue flame and left black remains which emitted white smoke |
531 |
0.377 |
5 |
The pile burned across the top and one side with an orange/blue flame and left black remains which emitted white smoke |
509 |
0.393 |
6 |
The pile burned with an orange/blue flame and left black remains which emitted white smoke |
500 |
0.400 |
Maximum burning rate = 0.422 mm/s
Maximum burning rate of reference mixtures = 1.681 mm/s
Description of key information
The test item is not oxidising based on the results of this test.
Key value for chemical safety assessment
- Oxidising properties:
- non oxidising
Additional information
Justification for classification or non-classification
The oxidising properties of the test item were deduced using EU Test Method A.17 of Commission Directive 92/69/EEC. This test is only designed to indicate whether or not a substance has oxidising properties. Since the test item did not meet the criteria for classification as an oxidising solid under this test method, it is considered that it is also not classified as an oxidising solid under CLP (ref. Guidance on the Application of the CLP Criteria, Verson 4.1 - June 2015).
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