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Diss Factsheets

Physical & Chemical properties

Surface tension

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Reference
Endpoint:
surface tension
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2 Sep 2015
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.5 (Surface Tension)
GLP compliance:
yes
Type of method:
ring method
Surface tension:
29.6 mN/m
Temp.:
21 °C
Conc.:
1 000 mg/L

Details:

Water calibration:

Water calibration: Temp. = 21 °C, density = 0.998 g/cm³

Surface tension of purified water, mN/m

Value 1

71.8

Value 2

71.9

Value 3

71.8

Value 4

71.9

Value 5

71.9

Value 6

71.9

Arithmetic mean

 71.9

Standard deviation

 0.0

Arithmetic mean 71.9 mN/m, standard deviation 0.0 mN/m from the last 6 measurements (theoretical value: 72.4 mN/m →correction factor 1.007)

First test solution

(c = 1143.0 mg/L), Temp. = 21 °C, density = 0.998 g/cm³, age of solution = 46 min)

Surface tension of solution 1, mN/m

Value 1

29.1

Value 2

28.6

Value 3

29.1

Value 4

28.0

Value 5

28.5

Value 6

28.0

 Arithmetic mean  28.5
 Standard deviation  0.5

Arithmetic mean 28.5 mN/m, standard deviation 0.5 mN/m from 6 measurements

Second test solution

 (c = 913 mg/L), Temp. = 20 °C, density = 0.998 g/cm³, age of solution = 71 min)

Surface tension of solution 2, mN/m

Value 1

30.4

Value 2

29.9

Value 3

30.1

Value 4

29.9

Value 5

29.5

Value 6

29.8

 Arithmetic mean  30.0
 Standard deviation  0.3

Arithmetic mean 30.0 mN/m, standard deviation 0.3 mN/m from 6 measurements

Third test solution

 (c = 1013 mg/L), Temp. = 21 °C, density = 0.998 g/cm³, age of solution = 104 min)

Surface tension of solution 3, mN/m

Value 1

30.4

Value 2

30.0

Value 3

29.8

Value 4

29.6

Value 5

29.0

Value 6

29.6

 Arithmetic mean  29.7
 Standard deviation  0.5

Arithmetic mean 29.7 mN/m, standard deviation 0.5 mN/m from 6 measurements

By adjusting the temperature setting of the tensiometer, differences in the density of the liquid can be compensated automatically.

Arithmentic mean of three test solutions:                    29.4 mN/m (+ 0.8 mN/m)

Arithmetic mean corrected by calibration factor

determined via water calibration:                            29.6 mN/m

Description of key information

29.6 mN/m at 20-21 °C, concentration: 1 g/L (EU A.5)

Key value for chemical safety assessment

Additional information

The surface tension was determined by the ring method.

The substance should be regarded as being surface active material.