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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Endpoint summary

Administrative data

Description of key information

Additional information

Reading across results from EPIKOTE 828 (CAS No. 25068-38-6), the registered substance is considered to be susceptible to hydrolysis at pH 4, 7, and 10, with a hydrolysis half-life of 117 hrs at 25 °C (95% confidence range: 68–204 h). Products of hydrolysis are expected to be the mono-diol and the di-diol from ring-opening of the two epoxy groups.

 

Also, evidence of hydrolysis of the registered substance was observed during its water solubility test (Štreit, 2010).  A review of “Fig. No. 1:LC/MS analysis of Grilonit 1/10 water solution” in the Annexes reveal that the primary peak (Retention Time = 10.2 mins) fell from ~3.5 to ~2.2 over the course of the 4-day experiment (3 days at 30°C + 1 at 20°C). This amounts to a 37% loss of the primary component over this 96-hour [4 day] period, which is most probably due to ring-opening hydrolysis of the epoxy groups, and compares well with the 50% loss seen for the read-across substance in 117 hrs [~4.9] days at 25°C, further supporting the read-across.