Methyl methacrylate

Guidance on Safe Use

First-aid measures

General:       First aider needs to protect himself. Take off all contaminated clothing immediately. Medical treatment is necessary if symptoms occur which are obviously caused by skin or eye contact with the product or by inhalation of its vapours.

 

4.1 Description of first aid measures

Inhalation:       Move subject to fresh air and keep him calm. See a physician.

 

Skin Contact:       Wash off immediately with soap and water. If skin irritation occurs consult a physician.

 

Eye contact:       Keeping the eyelids apart flush thoroughly with water immediately. If irritation persists, contact a physician.

 

Ingestion:       Do not induce vomiting. Call a physician immediately.

Personal Protection for First-aid Responders: No data available.

4.2 Most important symptoms and effects, both acute and delayed:       Headache. confusion Causes skin and eye irritation. Sensitization

 

4.3 Indication of any immediate medical attention and special treatment needed

Hazards:       May cause sensitization by skin contact.

 

Treatment:       Treat symptomatically.

Fire-fighting measures

General Fire Hazards:       Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Vapours are heavier than air and can form an explosive mixture with air. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Prevent fire extinguishing water from contaminating surface water or the ground water system.Retention of fire-extinguishing water in Germany: see FireExtinguishing Water Retention Directive "LoeRueRL":

5.1 Extinguishing media

Suitable extinguishing media:       Extinguish with foam, carbon dioxide or dry powder.

Unsuitable extinguishing media:       High volume water jet

5.2 Special hazards arising from the substance or mixture:       May be released in case of fire: carbon monoxide, carbon dioxide, organic products of decomposition.

5.3 Advice for firefighters

Special fire fighting procedures:       Keep away from sources of ignition - No smoking. Take action to prevent static discharges. In the event of fire, cool the endangered containers with water. When heated above the flash point and/or during spraying (atomizing), ignitible mixtures may form in air. Use only explosion-proof equipment. Vapours are heavier than air and may spread along floors.

Special protective equipment for fire-fighters:       Wear self-contained breathing apparatus.

Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures:       Assure sufficient ventilation. Use personal protective clothing. Keep away sources of ignition. Use breathing apparatus if exposed to vapours/dust/mist/aerosol.

      

6.1.1 For non-emergency personnel:       Evacuate area and do not approach spilled product. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). For personal protection see section 8.

      

6.1.2 For emergency responders:       No data available.

6.2 Environmental Precautions:       Prevent product from getting into drains/surface water/groundwater.

6.3 Methods and material for containment and cleaning up:       Larger quantities: Remove mechanically (by pumping). Use explosion-proof equipment! Smaller quantities and/or residues: Contain with absorbent material (e.g. sand, diatomaceous earth, acid absorbent, universal absorbent or sawdust). Dispose of in accordance with regulations.

6.4 Reference to other sections:

      For personal protection see section 8. For disposal considerations see section 13.

Handling and storage

7.1 Precautions for safe handling
Technical measures: Install appropriate equipment and wear appropriate personal protective equipment (see "8. Exposure control/personal protection").
Local/Total ventilation: Use explosion-proof electrical, ventilating and lighting equipment.
Safe handling advice: Keep container tightly closed. Ensure there is good room ventilation.Do not breathe vapors. Avoid contact with skin
and eyes. Do not eat, drink or smoke during use. Keep away from sources of ignition - No smoking. Take action to prevent static discharges. In the event of fire, cool the endangered containers with water. When heated above the flash point and/or during spraying (atomizing), ignitible
mixtures may form in air. Use only explosion-proof equipment. Vapours are heavier than air and may spread along floors.

Contact avoidance measures: see section 8. see section 10.

7.2 Conditions for safe storage, including any incompatibilities:       Keep only in the original container at a temperature not exceeding 30 °C. Fill the container by approximately 90 % only as oxygen (air) is required for stabilisation. With large storage containers make sure the oxygen (air) supply is sufficient to ensure stability. Can polymerize with intense heat release. Protect from the action of light.

Storage Class:       3: Flammable Liquids

 

7.3 Specific end use(s):       We are unaware of any specific end uses which go beyond the data reported in Section 1.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

UN 1247

Shipping information

Proper shipping name and description:

METHYL METHACRYLATE MONOMER, STABILIZED

Language:

English

Class or division:

Class 3: Flammable liquids

Packing group:

Packing group II: Substances presenting medium danger

Labels:

3

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

UN 1247

Shipping information

Proper shipping name and description:

METHYL METHACRYLATE MONOMER, STABILIZED

Language:

English

Class or division:

Class 3: Flammable liquids

Packing group:

Packing group II: Substances presenting medium danger

Labels:

3

Special provisions / remarks

Remarks:

Official transport information for transport by inland tank barge: UN 1247 Methyl methacrylate, monomer, stabilized, 3 (inst., N3), II

Marine transport (UN RTDG/IMDG)

UN number:

UN 1247

Shipping information

Proper shipping name and description:

METHYL METHACRYLATE MONOMER, STABILIZED

Language:

English

Class or division:

Class 3: Flammable liquids

Packing group:

Packing group II: Substances presenting medium danger

EmS code:

F-E

S-D

Labels:

3

Special provisions / remarks

Remarks:

Clear of living quarters., FOR USA ONLY: When shipping in, by or via USA note of the Reportable Quantity-Regulation!, Protected from sources of heat., IBC Code Product name: METHYL METHACRYLATE; MARPOL Category: Y; Ship Type: 2

Air transport (UN RTDG/ICAO/IATA)

UN number:

UN 1247

Shipping information

Proper shipping name and description:

METHYL METHACRYLATE MONOMER, STABILIZED

Language:

English

Class or division:

Class 3: Flammable liquids

Packing group:

Packing group II: Substances presenting medium danger

Labels:

3

Special provisions / remarks

Remarks:

FOR USA ONLY: When shipping in, by or via USA note of the Reportable Quantity-Regulation!

Additional transport information

Additional information

Special provisions / remarks / other:

14.6 Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations.
14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable for product as supplied.

Exposure controls / personal protection

8.1 Control Parameters

Components or products of decomposition, with limit values related to the place of work which require monitoring

methyl methacrylate, cas no. 80-62-6

Indicative occupational exposure limit value (long-term) established by the EU:

2009/161/EC 2009: 50 ppm

Indicative occupational exposure limit value (short-term)

2009/161/EC (15 minutes) 2009: 100 ppm

A large number of EU member states have also established national occupational exposure limits for MMA. The majority has also adopted 50 ppm / 200-210 mg/m³ (A, B, D, EST, H, I, IRL, LT, P, S, SP, SK, SLO, UK), while a smaller number of EU member states have established lower (BG, CZ, DK, FIN, LV, NL, PL) or higher OELs for MMA (GR, F) (as of spring 2010)

 

DNEL

 

Critical component       Type       Route of Exposure       Health Warnings       Remarks

methyl methacrylate       Workers       Inhalativ              208 mg/m3              Long-term - systemic effects

             Workers       Dermal              13,7 mg/kg/d              Long-term - systemic effects

             Workers       Inhalativ              416 mg/m3              Short-term exposure

             Workers       Dermal              1,500 µg/cm2       Short-term exposure

             Consumers       Inhalativ              74,3 mg/m3              Long-term - systemic effects

             Consumers       Dermal              8,2 mg/kg/d              Long-term - systemic effects

             Consumers       Oral              8,2 mg/kg/d              Long-term - systemic effects

             Consumers       Inhalativ              208 mg/m3              Short-term exposure

 

PNEC

Critical component       Environmental compartment       PNEC-Values       Remarks

methyl methacrylate       Fresh water                     0,94 mg/l       

             freshwater sediment              10,2 mg/kg dry weight

             marine water              0,094 mg/l       

             marine water sediment              1,02 mg/kg dry weight

             soil                     1,48 mg/kg dry weight

             sewage treatment plant (STP)       10 mg/l       

             Humans via the environment       8,2 mg/kg bw/day

 

8.2 Exposure controls
Appropriate Engineering Controls: For monitoring procedures refer for instance to "Empfohlene Analysenverfahren für Arbeitsplatzmessungen",
Schriftenreihe der Bundesanstalt für Arbeitsschutz and "NIOSH Manual of Analytical Methods", National Institute for Occupational Safety and Health
Monitoring methods: Install appropriate equipment and wear appropriate personal protective equipment (see "8. Exposure control/personal
protection").

Individual protection measures, such as personal protective equipment

Eye/face protection:       tightly fitting goggles

 

Hand Protection:       Material: butyl rubber gloves (minimal thickness 0.3 mm)

Break-through time: 60 min

Guideline: EN 374

Additional Information: The above mentioned hand protection is based on special knowledge of the chemical and the intended handling of this product, however, it still may not be suited for all workplaces. A qualified hazard assessment should be made prior to the onset of work in order to determine the suitability of gloves for specific working environments and processes., Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time., Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Additional Information: nitrile rubber gloves, Suitable as spray protection.

 

Skin and Body Protection:       On handling of larger quantities: face mask, chemical-resistant boots and apron

Respiratory Protection:       Breathing apparatus in case of high concentrations short term: filter appliance, filter A

 

Hygiene measures:       Store work clothing separately. Take off all contaminated clothing immediately. Follow the usual good standards of occupational hygiene. Clean skin thoroughly after work; apply skin cream.

 

Environmental Controls:       see section 6.

 

Stability and reactivity

10.1 Reactivity:       see section "Possibility of hazardous reactions"

 

10.2 Chemical Stability:       No decomposition if used as directed.

 

10.3 Possibility of hazardous reactions:       Polymerization with heat evolution may occur in the presence of radical forming substances (e.g. peroxides), reducing substances, and/or heavy metal ions.

 

10.4 Conditions to avoid:       Keep away from heat and sources of ignition. Protect from the action of light. The product is normally supplied in a stabilized form. If the permissible storage period and/or storage temperature is exceeded, the product may polymerize with heat evolution.

 

10.5 Incompatible Materials:       Peroxides, amines, sulfur compounds, heavy metal ions, alkalis, reducing agents and oxidizing agents. Mineral Acid Free radical initiators.

 

10.6 Hazardous Decomposition Products:       None when used as directed.

 

General information: The substance is rapidly metabolized

 

Disposal considerations

13.1 Waste treatment methods

General information:       Dispose of waste and residues in accordance with local authority requirements.

Disposal methods:       Waste is hazardous. It must be disposed of in accordance with the regulations after consultation of the competent local authorities and the disposal company in a suitable and licensed facility. Strictly controlled conditions during disposal or treatment to air, wastewater and waste. Do not add wastewater to a biological wastewater treatment plant Bring wastewater containing AOX for professional disposal. The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.

Contaminated Packaging:       Contaminated packaging should ideally be emptied; it can then be recycled after having been decontaminated. Packaging that cannot be cleaned should be disposed of professionally. Uncontaminated packaging may be taken for recycling.