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Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

4.1. Description of first aid measures

General advice Medical treatment is necessary if symptoms are evidently caused by effects of the

product on the skin, eyes or respiratory system. Remove contaminated, soaked


Inhalation Move subject to fresh air and keep him calm. In case of complaints get medical


Skin contact Wash off immediately with soap and water. If skin irritation persists, call a


Eye contact Flush eyes thoroughly with water.

Ingestion Do not induce vomiting. Get medical advice immediately.

4.2. Most important symptoms and effects, both acute and delayed

Product has dermal defatting effect, May cause eye/skin irritation.

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

Fire-fighting measures

5.1. Extinguishing media

Suitable extinguishing media dry chemical, carbon dioxide, foam

Extinguishing media which must not

be used for safety reasons


5.2. Special hazards arising from the substance or mixture

May be released in case of fire: carbon monoxide, carbon dioxide, organic products of decomposition.

5.3. Advice for firefighters

Wear self-contained breathing apparatus.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Take care for adequate ventilation. Use personal protective clothing. Keep away sources of ignition. Use breathing

apparatus if exposed to vapours/dust/mist/aerosol.

6.2. Environmental precautions

Prevent product from getting into subsoil/soil. Prevent product from getting into drains/surface water/groundwater.

6.3. Methods and material for containment and cleaning up

Larger quantities: Remove mechanically (by pumping). Use explosion-proof equipment! Smaller quantities and/or residues:

Contain with absorbent material (e.g. sand, diatomaceous earth, acid absorbent, universal absorbent or sawdust). Dispose

of in accordance with regulations.

6.4. Reference to other sections

For personal protection see section 8.

Handling and storage

7.1. Precautions for safe handling

Safe handling advice Keep container tightly closed. Ensure the area is well ventilated.

Advice on protection against fire and explosion

When heated above the flash point and/or during spraying (atomizing), ignitible

mixtures may form in air. In the event of fire, cool the endangered containers with


7.2. Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers

Keep only in the original container at a temperature not exceeding 30 °C. Protect

from light. Fill the container by approximately 90 % only as oxygen (air) is required

for stabilisation. With large storage containers make sure the oxygen (air) supply is

sufficient to ensure stability. Can polymerize with intense heat release.

7.3. Specific end use(s)


Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
Not a dangerous good within the meaning of transportation regulations.
Shippingopen allclose all
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

Shippingopen allclose all
Special provisions / remarks
Not a dangerous good within the meaning of transportation regulations.

Marine transport (UN RTDG/IMDG)

UN number:
Not a dangerous good within the meaning of transportation regulations.
Shippingopen allclose all
Special provisions / remarks
Not a dangerous good within the meaning of transportation regulations.

Air transport (UN RTDG/ICAO/IATA)

Shippingopen allclose all
Special provisions / remarks
Not a dangerous good within the meaning of transportation regulations.
SpecialProvisionsopen allclose all

Exposure controls / personal protection

8.1. Control parameters

see section 8.2.

8.2. Exposure controls

For monitoring procedures refer for instance to "Empfohlene Analysenverfahren für Arbeitsplatzmessungen",

Schriftenreihe der Bundesanstalt für Arbeitsschutz and "NIOSH Manual of Analytical Methods", National Institute for

Occupational Safety and Health

Protective measures

Do not inhale vapours. Avoid contact with eyes and skin.

Hygiene measures

Remove soiled or soaked clothing immediately. Follow the usual good standards of

occupational hygiene. Store work clothing separately. Use skin protective

preparation as preventive skin protection.

Respiratory protection

not required on normal handling

Hand protection

nitrile rubber gloves (minimal thickness 0.33 mm), Break through time > 10 min (EN 374)

butyl rubber gloves (minimal thickness 0.7 mm), Break through time > 30 min (EN 374)

In practice, due to variable exposure conditions, this information can only be an aid

to orientation for the selection of a suitable chemical protection glove. In particular,

this information does not substitute suitability tests by the end user.

Splash protection

neoprene gloves

nitrile rubber gloves

General information

Gloves should be replaced regularly, especially after extended contact with the

product. For each work-place a suitable glove type has to be selected.

Eye protection

tightly fitting goggles

Skin and body protection

On handling of larger quantities: face mask, chemical-resistant boots and apron

Stability and reactivity

10.1. Reactivity

see section 10.2.

10.2. Chemical Stability

No decomposition if stored and applied as directed.

Depolymerization begins at 200 °C

10.3. Possibility of hazardous reactions

Polymerization with heat evolution may occur in the presence of radical forming substances (e.g. peroxides), reducing

substances, and/or heavy metal ions.

10.4. Conditions to avoid

High temperature.

10.5. Incompatible materials

Free radical initiators.

Reducing agents.

Tertiary amines.

Heavy metals.


oxidizing agents

Mineral acids.

10.6. Hazardous decomposition products

None when used as directed.

Under conditions of thermal decomposition: Methacrylates

Disposal considerations

13.1. Waste treatment methods


Waste is non-hazardous. It should be disposed of in accordance with the

regulations after consultation of the competent local authorities and the disposal

company in a suitable and licensed facility.

Uncleaned packaging

Contaminated packaging should be emptied optimally and after appropriate

professional cleansing may be taken for reuse. Packaging that cannot be cleaned

should be disposed of professionally. Uncontaminated packaging may be taken for


Code of waste EWC

13 02 05

waste engine, gear and lubricating oils - mineral-based non-chlorinated engine,

gear and lubricating oils

Always check the given waste codes according to the actual conditions of

manufacturing, formulation or use in your facilities.