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Auto flammability

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Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2011-11-25 to 2011-12-01
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Version / remarks:
31 May 2008
Deviations:
no
Qualifier:
according to guideline
Guideline:
DIN 51794 (Testing of mineral oil hydrocarbons - Determination of ignition temperature)
Version / remarks:
May 2003
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: IEC standard 79-4: "Electrical Apparatus for Explosive Gas Atmospheres, Part 4, Method of Test for Ignition Temperature" ( 1975)
Deviations:
no
Qualifier:
according to guideline
Guideline:
IEC 60079-4 (Electrical apparatus for explosive gas atmospheres. Part 4: Method of test for ignition temperature)
Version / remarks:
1975
Deviations:
no
GLP compliance:
yes
Key result
Auto-ignition temperature:
275 °C
Atm. press.:
1 011.8 - 1 028.1 hPa
Remarks on result:
other: The lowest temperature at which ignition of the test substance occurred was 275°C.

Preliminary test:

The estimated auto-ignition temperature was 285°C.

Main test:

The results of the main study on the determination of the auto-ignition temperature of the test substance is given in Table 1.

Ignition of the test substance within 5 minutes after introduction was observed with each sample volume and with each test, a minimum auto-ignition temperature was obtained. The maximum deviation between the three values was <10°C.

The lowest temperature at which ignition of the test substance occurred was 275°C. This temperature was a multiple of 5°C and therefore given as the auto-ignition temperature of the test substance.

Test

Volume (µl)

Auto-ignition

temperature

[°C]

Ignition delay [s]

Colour of the

Flame

Minimum auto-ignition

temperature

[°C]

Test 1

70

170

450

284

276

280

8

14

14

orange/blue

orange/blue

orange/blue

276

Test 2

90

350

550

280

276

282

16

15

15

orange/blue

orange/blue

orange/blue

276

Test 3

120

250

500

277

275

279

16

19

15

orange/blue

orange/blue

orange/blue

275

Conclusions:
An auto-ignition temperature of 275°C at 1011.8 - 1028.1 hPa was determined for the substance in accordance with EU Method A.15 and in compliance with GLP. The result is considered to be reliable.

Description of key information

 Auto-ignition temperature: 275°C at 1011.8 – 1028.1 hPa (EU Method A.15)

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
275 °C

Additional information

An auto-ignition temperature of 275°C at 1011.8 – 1028.1 hPa was determined for the substance in accordance with EU Method A.15 and in compliance with GLP. The result is considered to be reliable.