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Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

4.1 Description of first aid measures

General advice


Move out of dangerous area.

Show this safety data sheet to the doctor in attendance.

Do not leave the victim unattended.

If inhaled


If symptoms persist, call a physician.

If unconscious, place in recovery position and get medical attention immediately.

In case of eye contact


Remove contact lenses.

Flush eyes with water as a precaution.

Protect unharmed eye.

Keep eye wide open while rinsing.

If eye irritation persists, consult a specialist.

If swallowed


Induce vomiting immediately and call a physician.

Keep respiratory tract clear.

Do not give milk or alcoholic beverages.

Never give anything by mouth to an unconscious person.

If symptoms persist, call a physician.

Take victim immediately to hospital.

4.2 Most important symptoms and effects, both acute and delayed



Inhalation may provoke the following symptoms:

Shortness of breath


Ingestion may provoke the following symptoms:

Stomach/intestinal disorders

Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media


Use extinguishing measures that are appropriate to local cir-cumstances and the surrounding environment.

Unsuitable extinguishing media


High volume water jet

5.2 Special hazards arising from the substance or mixture

Specific hazards during fire-fighting


Stibine may evolve under reducing conditions (such as con-tact with strong acids or alkalis in the presence of a metal) or in the presence of nascent hydrogen.

Stibine is a colourless, bad smelling gas, highly toxic similar to arsine.

Do not allow run-off from fire fighting to enter drains or water courses.

Hazardous combustion prod-ucts


Metal oxides

5.3 Advice for firefighters

Special protective equipment for firefighters


Wear self-contained breathing apparatus for firefighting if nec-essary.

Further information


Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions


Use personal protective equipment.

Avoid dust formation.

Avoid breathing dust.

6.2 Environmental precautions

Environmental precautions


Prevent product from entering drains.

Prevent further leakage or spillage if safe to do so.

If the product contaminates rivers and lakes or drains inform respective authorities.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up


Keep in suitable, closed containers for disposal.

Handling and storage

7.1 Precautions for safe handling

Advice on safe handling


Avoid formation of respirable particles.

Do not breathe vapours/dust.

Avoid exposure - obtain special instructions before use.

Avoid contact with skin and eyes.

For personal protection see section 8.

Smoking, eating and drinking should be prohibited in the ap-plication area.

Dispose of rinse water in accordance with local and national regulations.

Advice on protection against fire and explosion


Avoid dust formation. Provide appropriate exhaust ventilation at places where dust is formed.

Hygiene measures


When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers


Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully re-sealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. To maintain product quality, do not store in heat or direct sunlight.

Other data


Keep in a dry place. No decomposition if stored and applied as directed.

Transport information

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Marine transport (UN RTDG/IMDG)

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Exposure controls / personal protection

8.1 Control parameters

Occupational Exposure Limits Components CAS-No. Value type (Form of exposure) Control parameters Basis

sodium hexahy-droxoantimonate


TLV 8 hr

0,5 mg/m3



lead monoxide



0,15 mg/m3


98/24/EC I

Further information


Biological occupational exposure limits Substance name CAS-No. Control parameters Sampling time Basis

lead monoxide


Lead (Lead): 0,7 mg/l


98/24/EC II

8.2 Exposure controls

Engineering measures

Handle only in a place equipped with local exhaust (or other appropriate exhaust).

Personal protective equipment

Eye protection


Safety glasses with side-shields conforming to EN166

Hand protection




Break through time


> 240 min

Glove thickness


1,1 mm

Glove length


Standard glove type.



The data about break through time/strength of material is not valid for undissolved solids/dust.

Skin and body protection


Dust impervious protective suit

Respiratory protection


Suitable mask with particle filter P3 (European Norm 143)

Filter type


Particulates type (P)

In the case of dust or aerosol formation use respirator with an approved filter.

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.

Stability and reactivity

10.1 Reactivity

Stable at normal ambient temperature and pressure.

10.2 Chemical stability

No decomposition if stored and applied as directed.

10.3 Possibility of hazardous reactions

Hazardous reactions


No decomposition if stored and applied as directed.

10.4 Conditions to avoid

Conditions to avoid


None known.

10.5 Incompatible materials

Materials to avoid


Alkali metals

Reducing agents

10.6 Hazardous decomposition products

No decomposition if stored normally.

Disposal considerations

13.1 Waste treatment methods



The product should not be allowed to enter drains, water courses or the soil.

Dispose of in accordance with the European Directives on waste and hazardous waste.

In accordance with local and national regulations.

Do not contaminate ponds, waterways or ditches with chemi-cal or used container.

According to the European Waste Catalogue, Waste Codes are not product specific, but application specific.

Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.

Send to a licensed waste management company.

Contaminated packaging


Empty remaining contents.

Dispose of as unused product.

Do not re-use empty containers.