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Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

General advice: Never give anything by mouth to an unconscious person.

Inhalation: Move to fresh air. Oxygen or artificial respiration if needed. Consult a physician.

Skin contact: Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water. In the case of skin irritation or allergic reactions see a physician. Wash contaminated clothing before re-use.

Eye contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. If eye irritation persists, consult a specialist.

Ingestion: Drink 1 or 2 glasses of water. Do not induce vomiting without medical advice. Obtain medical attention.

Fire-fighting measures

Suitable extinguishing media:Water spray, Foam, Dry powder, Carbon dioxide (CO2),

Extinguishing media which shall not be used for safety reasons: High volume water jet, (contamination risk),

Special protective equipment for fire-fighters: In the event of fire, wear self-contained breathing apparatus.

Further information: Prevent fire extinguishing water from contaminating surface water or the ground water system. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

(on small fires) If area is heavily exposed to fire and if conditions permit, let fire burn itself out since water may increase the area contaminated. Cool containers / tanks with water spray.

Accidental release measures

Personal precautions:

Use personal protective equipment. Refer to protective measures listed in sections 7 and 8.

Environmental precautions:

Prevent further leakage or spillage if safe to do so. Use appropriate container to avoid environmental contamination. Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Local authorities should be advised if significant spillages cannot be contained. If the product contaminates rivers and lakes or drains inform respective authorities.

Methods for cleaning up:

Clean-up methods - small spillage Sweep up or vacuum up spillage and collect in suitable container for disposal.

Clean-up methods - large spillage Do not flush with water. Prevent further leakage or spillage. Use approved industrial vacuum cleaner for removal. Shovel into suitable container for disposal.

Additional advice:

Never return spills in original containers for re-use. Dispose of in accordance with local regulations.

Handling and storage

Handling

Advice on safe handling:

Use only clean equipment. Avoid breathing dust. Avoid dust formation. Provide appropriate exhaust ventilation at places where dust is formed. For personal protection see section 8.

Advice on protection against fire and explosion:

Keep away from heat and sources of ignition.

Storage

Requirements for storage areas and containers:

Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Store in a place accessible by authorized persons only. Keep out of reach of children. Keep away from food, drink and animal feeding stuffs.

Advice on common storage:

No special restrictions on storage with other products.

Other data:

Stable under recommended storage conditions.

For intermediate requirements: see attachement

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
Not dangerous goods in the meaning of ADR/RID, ADNR, IMDG-Code, ICAO/IATA-DGR
Shippingopen allclose all
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
Not dangerous goods in the meaning of ADR/RID, ADNR, IMDG-Code, ICAO/IATA-DGR
Shippingopen allclose all
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
Not dangerous goods in the meaning of ADR/RID, ADNR, IMDG-Code, ICAO/IATA-DGR
Shippingopen allclose all
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
Not dangerous goods in the meaning of ADR/RID, ADNR, IMDG-Code, ICAO/IATA-DGR
Shippingopen allclose all
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Engineering measures

Ensure adequate ventilation, especially in confined areas. Provide for appropriate exhaust ventilation and dust collection at machinery.

Personal protective equipment

Respiratory protection:

Manufacturing and processing work: Half mask with a particle filter FFP2 (EN149)

Hand protection:

Material: Nitrile rubber

Glove thickness: 0,4 - 0,7 mm

Wearing time: 480 min

Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time., The suitability for a specific workplace should be discussed with the producers of the protective gloves.

Eye protection:

Safety glasses with side-shields conforming to EN166

Skin and body protection:

Full protective clothing Type 5 + 6 (EN ISO 13982-2 / EN 13034)

Hygiene measures:

Regular cleaning of equipment, work area and clothing. Contaminated work clothing should not be allowed out of the workplace. Wash hands before breaks and immediately after handling the product. When using do not eat, drink or smoke. Keep away from food, drink and animal feeding stuffs. For environmental protection remove and wash all contaminated protective equipment before re-use. Dispose of rinse water in accordance with local and national regulations.

Protective measures:

All chemical protective clothing should be visually inspected prior to use. Clothing and gloves should be replaced in case of chemical or physical damage or if contaminated.

For intermediate requirements: see attachement

Stability and reactivity

Conditions to avoid:

Temperature : > 50 °C

Materials to avoid:

No materials to be especially mentioned.

Hazardous decomposition products:

Carbon oxides, nitrogen oxides (NOx)

Hazardous reactions:

Decomposes on heating.

Disposal considerations

Product:

In accordance with local and national regulations. Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities. Do not contaminate ponds, waterways or ditches with chemical or used container.

Contaminated packaging:

Do not re-use empty containers.

European Waste Catalogue number:

020108: agrochemical waste containing dangerous substances