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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Flammability

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Administrative data

Link to relevant study record(s)

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Endpoint:
flammable solids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
09.11.1994
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.10 (Flammability (Solids))
Deviations:
no
GLP compliance:
yes
Test procedure:
burning rate test over 100 mm length
Remarks on result:
substance does not ignite and propagate combustion either by burning with flame or smouldering along 200 mm of the powder train within the 2 minutes test period

In all the tests, the test substance started to melt. It was thereby classified as not highly flamable within the definition of the Directive 84/449/EEC.

Interpretation of results:
GHS criteria not met
Endpoint:
flammable solids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
15.06.2015
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.10 (Flammability (Solids))
Qualifier:
according to guideline
Guideline:
EPA OPPTS 830.6315 (Flammability)
GLP compliance:
yes (incl. QA statement)
Remarks:
Hess. Ministerium für Umwelt, Energie, Landwirtschaft und Verbraucherschutz, Mainzer Straße 80, D65189 Wiesbaden

Individual results

Preliminary test

The test item was a solidified melt. Therefore it was ground in a mortar before the measurement. The test item could not be ignited with a flame. The test item melted. The main test had not to be performed.

Interpretation of results:
not classified based on GHS criteria
Endpoint:
substances / mixtures which in contact with water emit flammable gases
Data waiving:
study scientifically not necessary / other information available
Justification for data waiving:
the study does not need to be conducted because the experience in production or handling shows that the substance does not react with water, e.g. the substance is manufactured with water or washed with water
Endpoint:
pyrophoric solids
Data waiving:
study scientifically not necessary / other information available
Justification for data waiving:
the study does not need to be conducted because the substance is known to be stable in contact with air at room temperature for prolonged periods of time (days) and hence, the classification procedure does not need to be applied
Endpoint:
self-heating substances / mixtures
Data waiving:
study scientifically not necessary / other information available
Justification for data waiving:
the study does not need to be conducted because the substance is completely molten at 160°C

Description of key information

Non flammable solid (EU Method A.10)

No flammability on contact with water (EU Method A.12)

No pyrophoricity (EU Method A.13)

Not self-heating (Melting point < 160 °C)

Key value for chemical safety assessment

Flammability:
not classified

Additional information

The test substance melted when approached by the ignition flame; no flame propagation was observed.

The substance does not emit flammable gases on contact with water.

The test item has no pyrophoric property in the sense of the test procedure.

The substance is completely molten at 160 °C and therefore does not need to be considered for classification as self-heating.

Justification for classification or non-classification

The available data on flammability of the test substance do not meet the criteria for classification according to Regulation (EC) 1272/2008, and are therefore conclusive but not sufficient for classification:

The test substance melted when approached by the ignition flame; no flame propagation was observed (EU Method A.10).

The substance does not emit flammable gases on contact with water (EU Method A.12).

The test item has no pyrophoric property in the sense of the test procedure (EU Method A.13).

The substance has a melting point of 49.35 °C (-22.3 °C tehnical); the determination of self-heating behaviour is not relevant for substances that are completely molten at 160°C.