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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
explosiveness
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)

Data source

Referenceopen allclose all

Reference Type:
study report
Title:
Unnamed
Year:
1997
Reference Type:
study report
Title:
Unnamed
Year:
2000
Reference Type:
study report
Title:
Unnamed
Year:
2002
Reference Type:
study report
Title:
Unnamed
Year:
2008

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
other: UN-Test-Manual 13.4.2, BAM Fallhammertest
Qualifier:
according to guideline
Guideline:
other: UN Test Manual Nr. 21.4.1, Test A.1
Qualifier:
according to guideline
Guideline:
other: UN-Test-Manual 23.4.1, C.1: Druck/Zeit-Prüfung
Qualifier:
according to guideline
Guideline:
other: UN-Test-Manual Nr. 25.4.1, Koenen-Test
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
5-amino-3-(morpholin-4-yl)-1,2,3-oxadiazolidin-3-ium chloride
EC Number:
605-254-1
Cas Number:
16142-27-1
Molecular formula:
C6 H11 N4 O2 . Cl
IUPAC Name:
5-amino-3-(morpholin-4-yl)-1,2,3-oxadiazolidin-3-ium chloride

Results and discussion

Small-scale preliminary testsopen allclose all
Parameter:
other: More sensitive to shock than m-dinitrobenzene
Remarks:
migrated information
Remarks on result:
negative (not further specified)
Parameter:
other: More sensitive to friction than m-dinitrobenzene
Remarks:
migrated information
Remarks on result:
negative (not further specified)
Parameter:
other: Explosive under influence of flame
Remarks:
migrated information
Remarks on result:
positive (not further specified)
Parameter:
other: Explosive (not specified)
Remarks:
migrated information
Remarks on result:
positive (not further specified)

Any other information on results incl. tables

The substance was tested in the BAM Fallhammer-Test (Test series 3, Test 3 (a) (ii)). The substance is sensitive to shock at an energy of 40 J, it is not sensitive at an energy of 7.5 J.

Additionally the substance was found to be thermally instable in the Koenen-Test (UN Test 2(b), EU A.14) (explosion at 2mm, no explosion at 6mm).

The substance was tested in the BAM 50/60 Steeltube test (UN Test Manual 21.4.1 test A1). The substance was found to be partially able to propargate a detonation.

The substance deflagrates fastly according to UN C.1 (closed system). The gas production rate is 25 l/kg/s (at 3 bar), 430 l/kg/s (at 10 bar), 2200 l/kg/s (at 20 bar). The deflagration rate in an open glas is 4 cm/min.

The dust of the substance is potentially explosive, the minimum ignition energy has been measured and is in the range of 30 - 100 mJ.

The substance was classified by the German Federal Institute for Materials Testing (BAM) as self reactive class B.

Applicant's summary and conclusion

Interpretation of results:
explosive
Remarks:
Migrated information
Conclusions:
The substance is considered to be explosive under certain circumstances. The test results are not sufficient for a classification as Explosive according to 2.1 of the CLP-Regulation, but support a classification as Selfreacting Substance Typ B according to 2.8 of the regulation. Transportation of the substance therefore is limited and requires a permission of the national authorities. The substance should be stored at a cool place, protected from heat or sunlight. The storage facilities should be equipped with pressure relief equipment.