PIC Factsheet

Chemicals Subject to PIC - Factsheet

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PIC - Prior Informed Consent Regulation

Substances subject to export controls or banned from export from the EU under the PIC Regulation

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(NE,Z)-N-({3,3'-dimethoxy-4'-[(E)-{[(1Z)-(4-nitrophenyl)[2-(4-nitrophenyl)hydrazin-1-ylidene]methyl]imino}amino]-[1,1'-biphenyl]-4-yl}imino)-4-nitro-N'-[(4-nitrophenyl)amino]benzene-1-carboximidamide
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CAS No: 19333-63-2
EC No: 677-171-9
(NE,Z)-N-({3,3'-dimethoxy-4'-[(E)-{[(1Z)-(4-nitrophenyl)[2-(4-nitrophenyl)hydrazin-1-ylidene]methyl]imino}amino]-[1,1'-biphenyl]-4-yl}imino)-4-nitro-N'-[(4-nitrophenyl)amino]benzene-1-carboximidamide is listed in PIC since it has been identified as a member of the chemical group: Benzidine, its salts and benzidine derivatives
Current PIC Context
Annex Legal Act Category Subcategory Use Limitation From To
Annex I Part 1
Annex I Part 1
Annex I Part 2
304/2003 Industrial Chemicals
Industrial Chemicals
Industrial Chemicals
Industrial chemicals for consumer use
Industrial chemicals for professional use

Banned
Severely Restricted
Severely Restricted
07-03-2003
PIC Regulatory History
Annex Legal Act Category Subcategory Use Limitation From To
Annex I Part 1
Annex I Part 1
Annex I Part 2
304/2003 Industrial Chemicals
Industrial Chemicals
Industrial Chemicals
Industrial chemicals for consumer use
Industrial chemicals for professional use

Banned
Severely Restricted
Severely Restricted
07-03-2003
Legislation text

In accordance with entry 13 of Annex XVII to Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (OJ L 396, 30.12.2006, p. 1-849), pursuant to Commission Regulation (EC) No 552/2009 of 22 June 2009 amending Regulation (EC) No 1907/2006 (REACH) as regards Annex XVII (OJ L 164, 26.6.2009, p. 7-31), the following applies to benzidine and its salts:
- Shall not be placed on the market, or used, as substances or in mixtures in concentrations greater than 0,1 % by weight.

In accordance with entry 9(d) of Annex XVII to Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (OJ L 396, 30.12.2006, p. 1-849), pursuant to Commission Regulation (EC) No 552/2009 of 22 June 2009 amending Regulation (EC) No 1907/2006 (REACH) as regards Annex XVII (OJ L 164, 26.6.2009, p. 7-31), benzidine and/or its derivatives:
1. Shall not be used, in jokes and hoaxes or in mixtures or articles intended to be used as such, for instance as a constituent of sneezing powder and stink bombs.
2. Jokes and hoaxes, or mixtures or articles intended to be used as such, not complying with paragraph 1 shall not be placed on the market.
3. However, paragraphs 1 and 2 shall not apply to stink bombs containing not more than 1,5 ml of liquid.
Submitted Data for (NE,Z)-N-({3,3'-dimethoxy-4'-[(E)-{[(1Z)-(4-nitrophenyl)[2-(4-nitrophenyl)hydrazin-1-ylidene]methyl]imino}amino]-[1,1'-biphenyl]-4-yl}imino)-4-nitro-N'-[(4-nitrophenyl)amino]benzene-1-carboximidamide