Alicyclediyldimethanol and [(hydroxymethyl)alicyclic]methyl (hydroxymethyl)alicyclecarboxylate and [oxybis(methylenealicyclediyl)]dimethanol

Guidance on Safe Use

First-aid measures

1, After eye contact

- In case of contact with substance, immediately flush eyes with running water at least 20 minutes.

2. After skin contact

- In case of contact with substance, immediately flush skin with running water at least 20 minutes.

- Remove and isolate contaminated clothing and shoes.

- Wash contaminated clothing and shoes before reuse.

- Get immediate medical advice/attention.

3. After inhalation

- Specific medical treatment is urgent.

- Move victim to fresh air.

- Give artificial respiration if victim is not breathing.

- Administer oxygen if breathing is difficult.

4. After ingestion

- Do not let him/her eat anything, if unconscious.

- Get immediate medical advice/attention.

Fire-fighting measures

1. Extinguishing media

- Suitable extinguishing media: Dry sand, dry chemical, alcohol-resistant foam, water spray, regular foam, CO2

- Unsuitable extinguishing media: High pressure water streams

2. Special hazards arising from the substance or mixture

- May be ignited by heat, sparks or flames.

- Containers may explode when heated.

- Some of these materials may burn, but none ignite readily.

- Fire will produce irritating and/or toxic gases.

- If inhaled, may be harmful.

3. Advice for firefighters

- Dike fire-control water for later disposal; do not scatter the material.

- Move containers from fire area if you can do it without risk.

- Fire involving Tanks; Cool containers with flooding quantities of water until well after fire is out.

- Fire involving Tanks; Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.

- Fire involving Tanks; Always stay away from tanks engulfed in fire.

Accidental release measures

1. Personal precautions, protective equipment and emergency procedures

- Eliminate all ignition sources.

- Stop leak if you can do it without risk.

- Please note that materials and conditions to avoid.

- Ventilate the area.

- Do not touch or walk through spilled material.

- Prevent dust cloud.

2. Environmental precautions

- Prevent entry into waterways, sewers, basements or confined areas.

3. Methods and material for containment and cleaning up

- Small Spill; Flush area with flooding quantities of water. And take up with sand or other non-combustible absorbent material and place into containers for later disposal.

- Large Spill; Dike far ahead of liquid spill for later disposal.

- With clean shovel place material into clean, dry container and cover loosely; move containers from spill area.

Handling and storage

1. Precautions for safe handling

- Please note that materials and conditions to avoid.

- Wash thoroughly after handling.

- Please work with reference to engineering controls and personal protective equipment.

- Be careful to high temperature.

2. Conditions for safe storage, including any incompatibilities

- Store in a closed container.

- Store in cool and dry place.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

N/A

Shipping

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

N/A

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

N/A

Shipping

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

N/A

Shipping

Remarks

SpecialProvisions

Exposure controls / personal protection

1. Appropriate engineering controls :

- Provide local exhaust ventilation system or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value.

2. Individual protection measures, such as personal protective equipment :

1) Respiratory protection

- Wear NIOSH or European Standard EN 149 approved full or half face piece (with goggles) respiratory protective equipment when necessary.

- In case exposed to gaseous/liquid material, the respiratory protective equipments as follow are recommended. escape full facepiece gas mask (of use for acid gas, in case of acid gas for organic compounds) or escape half facepiece gas mask (of use for acid gas, in case of acid gas for organic compounds) or direct full facepiece gas mask (of use for acid gas, in case of acid gas for organic compounds) half facepiece gas mask (of use for acid gas, in case of acid gas for organic compounds) or powered air-purifying gas mask.

- In lack of oxygen(< 19.5%), wear the supplied-air respirator or self-contained oxygen breathing apparatus.

      

2) Eye/face protection

- Wear enclosed safety goggles to protect from gaseous state organic material causing eye irritation or other disorder.

- An eye wash unit and safety shower station should be available nearby work place.

3) Skin protection

Hand protection :

- Wear appropriate protective gloves by considering physical and chemical properties of chemicals.

Other :

- Wear appropriate protective clothing by considering physical and chemical properties of chemicals.

Stability and reactivity

1. Reactivity  

- Some of these materials may burn, but none ignite readily.

2. Chemical stability  

- Stable under normal temperatures and pressures.

3. Possibility of hazardous reactions  

- Containers may explode when heated.

- Fire may produce irritating and/or toxic gases.

- Some liquids produce vapors that may cause dizziness or suffocation.

- Inhalation of material may be harmful.

4. Conditions to avoid  

- Heat, sparks or flames

5. Incompatible materials  

- Combustibles

6. Hazardous decomposition products  

- Irritating and/or toxic gases

Disposal considerations

1. Waste treatment methods

1) Waste from residues  

- Waste must be disposed of in accordance with federal, state and local environmental control regulations.

2) Container  

- Consider the required attentions in accordance with waste treatment management regulation.