[N-(1,1-dimethylethyl)-1,1-dimethyl-1-[(1,2,3,4,5-η)-2,3,4,5-tetramethyl-2,4-cyclopentadien-1-yl]silanaminato(2-)-κN][(1,2,3,4-η)-1,3-pentadiene]-titanium

Guidance on Safe Use

First-aid measures

Emergency measure - Inhalation: Remove to fresh air if effects occur. Consult a physician.

Note to physician: No specific antidote. Supportive care.

Treatment based on judgement of the physician in response to

reactions of the patient.

Emergency measure - Eyes: Immediate and continuous irrigation with flowing water for

at least 30 minutes is imperative. Prompt medical

consultation is essential.

Emergency measure - Skin: Wash with soap and plenty of water. Seek medical attention.

Emergency measure - Ingestion: Consult a physician who will decide on need and method of

emptying the stomach. If lavage is performed, suggest

endotracheal and/or oesophageal control. Danger from lung

aspiration must be weighed against toxicity when considering

emptying the stomach.

Fire-fighting measures

Recommended extinguishing agent: Dry chemical, carbon dioxide.

Water must not be used.

Product arising from burning: Carbon monoxide, carbon dioxide, aldehydes, titanium oxides,

silicon oxide, nitrogen oxides. Other decomposition and

combustion products are emitted in the case of incomplete

combustion.

Black sooty smoke is emitted.

Product determined by test: N

Protective equipment: Minimize breathing gases, vapours, fumes or decomposition

products. Use supplied-air breathing equipment.

Accidental release measures

Emergency measures in case of spillage: Evacuate personnel from the immediate vicinity and

extinguish any sources of ignition.

Wear appropriate personal protective equipment including

chemical protective clothing, gloves, eye protection,

footwear and respiratory protection as specified in Section

2.3.10.

Absorb spillages with a suitable inert material (e.g. sand

or soil). Carefully transfer the spillage to closed waste

containers, or use a sealed industrial vacuum machine.

Containers filled with waste material must be labelled in

the same way as the original CGC-7 containers.

Do not allow spilled material to discharge to drain.

Dispose of waste material in accordance with local

regulations by incineration.

Ventilate spillage area after the material is cleaned up.

Handling and storage

Handling: The substance should be stored, handled and used under

conditions of good industrial hygiene and in conformity with

any local regulations to avoid exposure by ingestion,

inhalation, skin and eye contact.

Use local exhaust ventilation.

When exposure cannot be adequately controlled or prevented

personal protective equipment including eye protection e.g.

goggles, impervious gloves such as neoprene or nitrile

butadiene rubber, chemical resistant footwear and chemical

resistant clothing made of neoprene, nitrile butadiene

rubber or PVC (apron) should be worn. Furthermore, when

respiratory equipment is required it must be capable of

adequately controlling exposure, be suitable for the purpose

and conform to the appropriate national or international

standards.  When there is a risk of exposure to vapours, a

half-face filter mask is advised in combination with

cartriges for organic vapours (classification: A2).

Storage: The substance should be stored in sealed containers under an

inert atmosphere such as nitrogen or argon. Exposure to

water or moist air must be avoided.

Packaging of the substance and or preparation: Glass bottles in sealed steel drums with appropriate shock

absorbent materials.  Only UN approved packaging shall be

used.

Transport information

Shipping

SpecialProvisions

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

Shipping

Remarks

Air transport (UN RTDG/ICAO/IATA)

Shipping

Special provisions / remarks

Remarks:

Transport code: UN Class 8, Packing Group III
Transport: Transport in glass bottles in sealed metal drums, packed in
shock absorbent materials. Only UN approved packaging shall
be used.


Road, Rail & Barge: UN number: 1759 Kemler code: 80

Tremcard Nr. CEFIC: 80G09

Sea: UN number: 1759, IMO/IMDG class: 8

Air: UN number: 1759, Air-ICAO/IATA class: 8


Preparations containing the substance should be transported
in UN approved cylinders designed for carrying flammable
liquids.

SpecialProvisions

Stability and reactivity

Danger other than fire: Incompatible with water, alcohols, other protic solvents and

strong oxidising agents such as chlorine.

Chemical reaction with water: Hydrolysis will occur quickly.

Avoid exposure to water and moist air.

Dust explosion: Not anticipated.

Dust explosion determined by test: N

Disposal considerations

Industry - Possibility of recovery/recycling: After use, the substance cannot be traced in the final

polymer as such, therefore cannot be recovered or recycled.

Industry - Possibility of neutralisation: 634 Neutralisation by special techniques

The reactive chemical properties of the substance can be

neutralised by reacting it with isopropanol. No treatment

specifically to neutralise the health or environmental

hazards is known, although chemical neutralisation with

isopropanol might reduce the corrosive effects

Industry - Possibility of destruction: controlled discharge: The substance should not be disposed of by landfill.

Industry - Possibility of destruction - incineration: 661 Incinerator with flue gas scrubbing

The substance should be neutralised with isopropanol and

disposed of by incineration under controlled conditions at a

licensed waste treatment processor in accordance with local

regulations. Stack gases should be scrubbed because noxious

fumes including carbon monoxide, aldehydes, silicon oxide,

titanium oxides and nitrogen oxides may be produced.

Industry - Possibility of destruction - water purification: The substance should not be discharged directly to the

sewage system or the aqueous environment. However, the

substance has been shown not to be unduly toxic to sewage

micro-organisms.

Public at large - Possibility of recovery/recycling: Not applicable; 100% use in chemical plants by industrial

users.

Public at large - Possibility of neutralisation: Not applicable.

Public at large - Possibility of destruction: controlled discharge: Not applicable.

Public at large - Possibility of destruction - incineration: Not applicable.

Public at large - Possibility of destruction - water purification: Not applicable.

Public at large - Possibility of destruction - others: Not applicable.