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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

First-aid measures

Description of first aid measures

General advice: Remove contaminated clothing immediately and dispose of safely.

Inhalation: Move the victim to fresh air and keep at rest. Call a physician or poison control center immediately.

Skin contact: Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water. Call a physician or poison control center immediately.

Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a physician or poison control center immediately.

Ingestion: Keep at rest. Rinse mouth. Induce vomiting only, if: 1. patient is fully conscious, 2. medical aid is not readily available, 3. a significant amount (more than a mouthful) has been ingested and 4. time since ingestion is less than 1 hour. (Vomit should not get into the respiratory tract.) Obtain medical attention.

Most important symptoms and effects, both acute and delayed

Symptoms:

Local: The product causes irritation of eyes, skin and mucous membranes., Sensitisation

Systemic: Tiredness, Thirst, Sweating, anxiety, Hyperventilation, tachycardia, Muscle rigidity, Hyperthermia

Indication of any immediate medical attention and special treatment needed

Treatment:

Local treatment: Initial treatment: symptomatic.

Systemic treatment: Initial treatment: symptomatic. In case of ingestion gastric lavage should be considered in cases of significant ingestions only within the first 2 hours. However, the application of activated charcoal and sodium sulphate is always advisable. In case of hyperthermia physical cooling is advisable; in case of muscle rigidity muscle relaxants and mechanical ventilation may support in counteracting hyperthermia. There is no specific antidote.

Fire-fighting measures

FIREFIGHTING MEASURES

Extinguishing media

Special hazards arising from the substance or mixture: Dangerous gases are evolved in the event of a fire.

Advice for firefighters

Special protective equipment for firefighters:       In the event of fire and/or explosion do not breathe fumes. Wear self-contained breathing apparatus and protective suit.

Further information: Remove product from areas of fire, or otherwise cool containers with water in order to avoid pressure being built up due to heat. Whenever possible, contain fire-fighting water by diking area with sand or earth.

Accidental release measures

ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Precautions: Keep people away from and upwind of spill/leak. Use personal protective equipment. Remove all sources of ignition. Avoid dust formation. Avoid contact with spilled product or contaminated surfaces. When dealing with a spillage do not eat, drink or smoke.

Environmental precautions: Do not allow to get into surface water, drains and ground water.

Methods and materials for containment and cleaning up

Methods for cleaning up: Use mechanical handling equipment. Collect and transfer the product into a properly labelled and tightly closed container. Clean contaminated floors and objects thoroughly, observing environmental regulations.

Additional advice: Check also for any local site procedures.

Handling and storage

HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling: Avoid dust formation. Use only in area provided with appropriate exhaust ventilation.

Advice on protection against fire and explosion: Dust may form explosive mixture in air. Keep away from heat and sources of ignition. Take measures to prevent the build up of electrostatic charge.

Hygiene measures: Avoid contact with skin, eyes and clothing. Keep working clothes separately. Wash hands before breaks and immediately after handling the product. Remove soiled clothing immediately and clean thoroughly before using again.

Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers: Store in original container. Store in a place accessible by authorized persons only. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from direct sunlight. Protect from freezing.

Advice on common storage: Keep away from food, drink and animal feedingstuffs.

Suitable materials: Black mild steel sheet

Specific end use(s): Apart from the uses mentioned in section 1.2 no other specific uses are stipulated.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN 2588
Shipping information
Proper shipping name and description:
PESTICIDE, SOLID, TOXIC, N.O.S. (BROMOXYNIL HEPTANOATE)
Chemical name:
2,6-dibromo-4-cyanophenyl heptanoate
Language:
English
Class or division:
Class 6: Toxic and infectious substances; Division 6.1
Packing group:
Packing group III: Substances presenting low danger
Labels:
HIS: Yes, SP:, LQ: 5,00 Kg, 30,00 Kg, Tunnel Code E
Packaging: 6.1, E1
Bulk: 6.1, E1
Haz ID: 60
EAC 2X
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
UN 2588
Shipping information
Proper shipping name and description:
PESTICIDE, SOLID, TOXIC, N.O.S. (BROMOXYNIL HEPTANOATE)
Chemical name:
2,6-dibromo-4-cyanophenyl heptanoate
Language:
English
Class or division:
Class 6: Toxic and infectious substances; Division 6.1
Packing group:
Packing group III: Substances presenting low danger
Labels:
HIS: Yes, LQ: 5,00 Kg, 30,00 Kg
Packaging: 6.1, E1
Bulk: 6.1, E1
Haz ID: 60
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
UN 2588
Shipping information
Proper shipping name and description:
PESTICIDE, SOLID, TOXIC, N.O.S. (BROMOXYNIL HEPTANOATE)
Chemical name:
2,6-dibromo-4-cyanophenyl heptanoate
Language:
English
Class or division:
Class 6: Toxic and infectious substances; Division 6.1
Packing group:
Packing group III: Substances presenting low danger
EmS code:
F-A
S-A
Labels:
LQ: 5,00 KG 30,00 Kg
Packaging: 6.1, P
Bulk: 6.1, P
Marine pollutant
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
UN 2588
Shipping information
Proper shipping name and description:
PESTICIDE, SOLID, TOXIC, N.O.S. (BROMOXYNIL HEPTANOATE)
Chemical name:
2,6-dibromo-4-cyanophenyl heptanoate
Language:
English
Class or division:
Class 6: Toxic and infectious substances; Division 6.1
Packing group:
Packing group III: Substances presenting low danger
Labels:
HIS: Yes, SP:
PIN: 677
Max net qty: 200,00 Kg
Packaging: 6.1
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Control parameters

Exposure controls

Respiratory protection: Wear respirator with a particle filter mask (protection factor 20) conforming to European Norm EN149FFP3 or EN140P3 or equivalent.

Respiratory protection should only be used to control residual risk of short duration activities, when all reasonably practicable steps have been taken to reduce exposure at source e.g. containment and/or local extract ventilation. Always follow respirator manufacturer's instructions regarding wearing and maintenance.

Hand protection: Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time.

Wash gloves when contaminated. Dispose of when contaminated inside, when perforated or when contamination on the outside cannot be removed. Wash hands frequently and always before eating, drinking, smoking or using the toilet.

      Material:                       Nitrile rubber

      Rate of permeability:       > 480 min

      Glove thickness:         > 0,4 mm

      Protective index:         Class 6

      Directive:                     Protective gloves complying with EN 374.

Eye protection: Wear goggles (conforming to EN166, Field of Use = 5 or equivalent).

Skin and body protection: Wear standard coveralls and Category 3 Type 4 suit.

If there is a risk of significant exposure, consider a higher protective type suit.

Wear two layers of clothing wherever possible. Polyester/cotton or cotton overalls should be worn under chemical protection suit and should be professionally laundered frequently.

Stability and reactivity

STABILITY AND REACTIVITY

Reactivity: Stable under normal conditions.

Chemical stability: Stable under recommended storage conditions.

Possibility of hazardous reactions: No hazardous reactions when stored and handled according to prescribed instructions.

Conditions to avoid: Extremes of temperature and direct sunlight.

Incompatible materials: Store only in the original container.

Hazardous decomposition products: No decomposition products expected under normal conditions of use.

Disposal considerations

DISPOSAL CONSIDERATIONS

Waste treatment methods

Product: In accordance with current regulations and, if necessary, after consultation with the site operator and/or with the responsible authority, the product may be taken to a waste disposal site or incineration plant.

Contaminated packaging: Triple rinse containers. Do not re-use empty containers. Not completely emptied packagings should be disposed of as hazardous waste.

Waste key for the unused product: 02 01 08* agrochemical waste containing hazardous substances