Registration Dossier
Registration Dossier
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EC number: 221-337-1 | CAS number: 3069-33-8
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
General information:
Take persons to a safe place. Observe self-protection for first aid. Always seek medical advice in the event of contact with this substance.
After contact with the eyes:
Rinse immediately with plenty of water for 10-15 minutes. Keep eyelids well open to rinse the whole eye surface and eyelids with water. Seek medical advice immediately and clearly identify substance. Continue to bathe eyes during transport to medical practitioner.
After contact with the skin:
Remove contaminated clothes at once. Wash off with plenty of water or water and soap immediately for 10-15 minutes. In serious cases, use emergency shower immediately. Seek medical advice immediately and clearly identify substance.
After inhalation:
Keep the patient calm. If unconscious place in stable sideways position. Protect against loss of body heat. If breathing stops, administer artificial respiration. Seek medical advice immediately and clearly identify substance.
After swallowing:
If conscious, give several small portions of water to drink. Do not induce vomiting. Seek medical advice immediately and clearly identify substance.
Most important symptoms and effects, both acute and delayed
Any relevant information can be found in other parts of this section.
Indication of any immediate medical attention and special treatment needed
After inhalation: treat as early as possible using cortisone spray. Medical checks necessary up to a latency period of at least 24 hours. In the event of 1st degree burns use corticoid-externa. In the case of 2nd degree burns, use symptomatic treatment.
General information:
Take persons to a safe place. Observe self-protection for first aid. Always seek medical advice in the event of contact with this substance.
After contact with the eyes:
Rinse immediately with plenty of water for 10-15 minutes. Keep eyelids well open to rinse the whole eye surface and eyelids with water. Seek medical advice immediately and clearly identify substance. Continue to bathe eyes during transport to medical practitioner.
After contact with the skin:
Remove contaminated clothes at once. Wash off with plenty of water or water and soap immediately for 10-15 minutes. In serious cases, use emergency shower immediately. Seek medical advice immediately and clearly identify substance.
After inhalation:
Keep the patient calm. If unconscious place in stable sideways position. Protect against loss of body heat. If breathing stops, administer artificial respiration. Seek medical advice immediately and clearly identify substance.
After swallowing:
If conscious, give several small portions of water to drink. Do not induce vomiting. Seek medical advice immediately and clearly identify substance.
Most important symptoms and effects, both acute and delayed
Any relevant information can be found in other parts of this section.
Indication of any immediate medical attention and special treatment needed
After inhalation: treat as early as possible using cortisone spray. Medical checks necessary up to a latency period of at least 24 hours. In the event of 1st degree burns use corticoid-externa. In the case of 2nd degree burns, use symptomatic treatment.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media:
water mist , extinguishing powder , alcohol-resistant foam , carbon dioxide , sand .
Extinguishing media which must not be used for safety reasons:
water jet .
Special hazards arising from the substance or mixture
Risk of hazardous gasses or fumes in the event of fire. Exposure to combustion products may be a health hazard! Hazardous combustion products: carbon oxides , silicon oxides , nitrogen oxides , incompletely burnt hydrocarbons , toxic and very toxic fumes .
Advice for firefighters
Special protective equipment for fire fighting:
Use respiratory protection independent of recirculated air. Keep unprotected persons away.
Suitable extinguishing media:
water mist , extinguishing powder , alcohol-resistant foam , carbon dioxide , sand .
Extinguishing media which must not be used for safety reasons:
water jet .
Special hazards arising from the substance or mixture
Risk of hazardous gasses or fumes in the event of fire. Exposure to combustion products may be a health hazard! Hazardous combustion products: carbon oxides , silicon oxides , nitrogen oxides , incompletely burnt hydrocarbons , toxic and very toxic fumes .
Advice for firefighters
Special protective equipment for fire fighting:
Use respiratory protection independent of recirculated air. Keep unprotected persons away.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Secure the area. Wear personal protection equipment (see section Exposure controls/personal protection). Keep unprotected persons away. Avoid contact with eyes and skin. Do not inhale gases/vapours/aerosols. If material is released indicate risk of slipping. Do not walk through spilled material.
Environmental precautions
Prevent material from entering surface waters, drains or sewers and soil. Close leak if possible without risk. Contain any fluid that runs out using suitable material (e.g. earth). Retain contaminated water/extinguishing water. Dispose of in prescribed marked containers. Inform authorities if substance leaks into surface waters, sewerage or ground.
Methods and material for containment and cleaning up
Take up mechanically and dispose of according to local/state/federal regulations. Do not flush away with water. For small amounts: Absorb with a neutral (non-acidic / non-basic) liquid binding material such as diatomaceous earth and dispose of according to government regulations. For large amounts: Liquids may be recovered using suction devices or pumps. If flammable, only air driven or properly rated electrical equipment should be used. Clean any slippery coating that remains using a detergent / soap solution or another biodegradable cleaner. Silicone fluids are slippery; spills are a safety hazard. Apply sand or other inert granular material to improve traction.
Further information:
Exhaust vapours. Eliminate all sources of ignition. Consider explosion protection. Observe notes under section Handling and Storage.
Reference to other sections
Relevant information in other sections has to be considered. This applies in particular for information given on personal protective equipment (section Exposure controls/personal protection) and on disposal (section Disposal considerations).
Secure the area. Wear personal protection equipment (see section Exposure controls/personal protection). Keep unprotected persons away. Avoid contact with eyes and skin. Do not inhale gases/vapours/aerosols. If material is released indicate risk of slipping. Do not walk through spilled material.
Environmental precautions
Prevent material from entering surface waters, drains or sewers and soil. Close leak if possible without risk. Contain any fluid that runs out using suitable material (e.g. earth). Retain contaminated water/extinguishing water. Dispose of in prescribed marked containers. Inform authorities if substance leaks into surface waters, sewerage or ground.
Methods and material for containment and cleaning up
Take up mechanically and dispose of according to local/state/federal regulations. Do not flush away with water. For small amounts: Absorb with a neutral (non-acidic / non-basic) liquid binding material such as diatomaceous earth and dispose of according to government regulations. For large amounts: Liquids may be recovered using suction devices or pumps. If flammable, only air driven or properly rated electrical equipment should be used. Clean any slippery coating that remains using a detergent / soap solution or another biodegradable cleaner. Silicone fluids are slippery; spills are a safety hazard. Apply sand or other inert granular material to improve traction.
Further information:
Exhaust vapours. Eliminate all sources of ignition. Consider explosion protection. Observe notes under section Handling and Storage.
Reference to other sections
Relevant information in other sections has to be considered. This applies in particular for information given on personal protective equipment (section Exposure controls/personal protection) and on disposal (section Disposal considerations).
Handling and storage
Precautions for safe handling
Precautions for safe handling:
Ensure adequate ventilation. Must be syphoned off in situ. Spilled substance increases risk of slipping. Avoid formation of aerosols. In case of aerosol formation special protective measures are required (exhausting by suction, respiratory protection). Observe information in section 8. Keep away from incompatible substances in accordance with section Stability and reactivity.
Precautions against fire and explosion:
Product can separate methanol. Flammable vapors may accumulate and form explosive mixtures with air in containers, process vessels, including partial, empty and uncleaned containers and vessels, or other enclosed spaces. Keep away from sources of ignition and do not smoke. Take precautionary measures against electrostatic charging. Cool endangered containers with water.
Conditions for safe storage, including any incompatibilities
Conditions for storage rooms and vessels:
Observe local/state/federal regulations.
Advice for storage of incompatible materials:
Observe local/state/federal regulations.
Further information for storage:
Store in a dry and cool place. Protect against moisture. Store container in a well ventilated place.
Specific end use(s)
No data available.
Precautions for safe handling:
Ensure adequate ventilation. Must be syphoned off in situ. Spilled substance increases risk of slipping. Avoid formation of aerosols. In case of aerosol formation special protective measures are required (exhausting by suction, respiratory protection). Observe information in section 8. Keep away from incompatible substances in accordance with section Stability and reactivity.
Precautions against fire and explosion:
Product can separate methanol. Flammable vapors may accumulate and form explosive mixtures with air in containers, process vessels, including partial, empty and uncleaned containers and vessels, or other enclosed spaces. Keep away from sources of ignition and do not smoke. Take precautionary measures against electrostatic charging. Cool endangered containers with water.
Conditions for safe storage, including any incompatibilities
Conditions for storage rooms and vessels:
Observe local/state/federal regulations.
Advice for storage of incompatible materials:
Observe local/state/federal regulations.
Further information for storage:
Store in a dry and cool place. Protect against moisture. Store container in a well ventilated place.
Specific end use(s)
No data available.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 2735
Shipping information
- Proper shipping name and description:
- Amine, flüssig, ätzend, n.a.g. (N-(3-(Methoxydimethylsilyl)propyl)ethylendiamin)
- Chemical name:
- N-(3-(Methoxydimethylsilyl)propyl)ethylendiamin
- Language:
- German
- Labels:
- class 8: corrosive substances
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 2735
Shipping information
- Proper shipping name and description:
- Amine, flüssig, ätzend, n.a.g. (N-(3-(Methoxydimethylsilyl)propyl)ethylendiamin)
- Chemical name:
- N-(3-(Methoxydimethylsilyl)propyl)ethylendiamin
- Language:
- German
- Labels:
- class 8: corrosive substances
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 2735
Shipping information
- Proper shipping name and description:
- Amines, liquid, corrosive, n.o.s. (N-(3-(Methoxydimethylsilyl)propyl)ethylenediamine)
- Chemical name:
- N-(3-(Methoxydimethylsilyl)propyl)ethylenediamine
- Labels:
- class 8: corrosive substances
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 2735
Shipping information
- Proper shipping name and description:
- Amines, liquid, corrosive, n.o.s. (N-(3-(Methoxydimethylsilyl)propyl)ethylenediamine)
- Chemical name:
- N-(3-(Methoxydimethylsilyl)propyl)ethylenediamine
- Labels:
- class 8: corrosive substances
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Control parameters
Maximum airborne concentrations at the workplace:
CAS No. Material Type mg/m3 ppm Dust fract. Fibre/m3
67-56-1 Methanol AGW 270,0 200,0 - -
Methanol (CAS no. 67-56-1): Refer to Technical Rules for Hazardous Substances "TRGS 900" for more details on the German AGW.
BAT-Value:
CAS No. Material Param. Value other material Time
67-56-1 METHANOL 30 mg/l URIN C,B
Exposure controls
Exposure in the work place limited and controlled
General protection and hygiene measures:
Avoid contact with eyes and skin. Do not inhale gases/vapours/aerosols. Do not eat, drink or smoke when handling.
Personal protection equipment:
Respiratory protection
In case of long or strong exposure: gas mask filter ABEK .
Eye protection
tight fitting protective goggles . Provide work station with eye bathing equipment.
Hand protection
Protective gloves made of butyl rubber . Gloves suitable for up to 60 minutes' use. The selection of appropriate gloves not only depends on the material, but also on other quality characteristics, and may vary depending on the manufacturer. Please observe information from your glove supplier in terms of permeability and breakthrough time.
Skin protection
protective clothing .
Exposure to the environment limited and controlled
Prevent material from entering surface waters, drains or sewers and soil.
Further information for system design and engineering measures
Observe information in section Handling and Storage.
Maximum airborne concentrations at the workplace:
CAS No. Material Type mg/m3 ppm Dust fract. Fibre/m3
67-56-1 Methanol AGW 270,0 200,0 - -
Methanol (CAS no. 67-56-1): Refer to Technical Rules for Hazardous Substances "TRGS 900" for more details on the German AGW.
BAT-Value:
CAS No. Material Param. Value other material Time
67-56-1 METHANOL 30 mg/l URIN C,B
Exposure controls
Exposure in the work place limited and controlled
General protection and hygiene measures:
Avoid contact with eyes and skin. Do not inhale gases/vapours/aerosols. Do not eat, drink or smoke when handling.
Personal protection equipment:
Respiratory protection
In case of long or strong exposure: gas mask filter ABEK .
Eye protection
tight fitting protective goggles . Provide work station with eye bathing equipment.
Hand protection
Protective gloves made of butyl rubber . Gloves suitable for up to 60 minutes' use. The selection of appropriate gloves not only depends on the material, but also on other quality characteristics, and may vary depending on the manufacturer. Please observe information from your glove supplier in terms of permeability and breakthrough time.
Skin protection
protective clothing .
Exposure to the environment limited and controlled
Prevent material from entering surface waters, drains or sewers and soil.
Further information for system design and engineering measures
Observe information in section Handling and Storage.
Stability and reactivity
If stored and handled in accordance with standard industrial practices no hazardous reactions are known.
Relevant information can possibly be found in other parts of this section.
Conditions to avoid: moisture
Incompatible materials: Reacts with: water , basic substances and acids . Reaction causes the formation of: methanol .
Hazardous decomposition products: If stored and handled properly: none known .
Relevant information can possibly be found in other parts of this section.
Conditions to avoid: moisture
Incompatible materials: Reacts with: water , basic substances and acids . Reaction causes the formation of: methanol .
Hazardous decomposition products: If stored and handled properly: none known .
Disposal considerations
Waste treatment methods
Material
Recommendation:
Material that cannot be used, reprocessed or recycled should be disposed of in accordance with Federal, State, and local regulations at an approved facility. Depending on the regulations, waste treatment methods may include, e.g., landfill or incineration.
Uncleaned packaging
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used. Observe local/state/federal regulations. Uncleaned packaging should be treated with the same precautions as the material.
Waste Disposal Legislation Ref.No.(EC)
It is not possible to determine a waste code for this product in accordance with the European Waste Catalogue (EWC) since it is only possible to classify it according to how it is used by the customer. The waste code is to be determined within the EU in liaison with the waste-disposal operator.
Material
Recommendation:
Material that cannot be used, reprocessed or recycled should be disposed of in accordance with Federal, State, and local regulations at an approved facility. Depending on the regulations, waste treatment methods may include, e.g., landfill or incineration.
Uncleaned packaging
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used. Observe local/state/federal regulations. Uncleaned packaging should be treated with the same precautions as the material.
Waste Disposal Legislation Ref.No.(EC)
It is not possible to determine a waste code for this product in accordance with the European Waste Catalogue (EWC) since it is only possible to classify it according to how it is used by the customer. The waste code is to be determined within the EU in liaison with the waste-disposal operator.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
