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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

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Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

In the case of accident or if you feel unwell, seek medical advice immediately. First aider needs to protect himself.
Move out of dangerous area. Take off all contaminated clothing immediately


If inhaled : If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration.
In case of skin contact : In case of contact with skin wash off immediately with soap and water. Summon a doctor immediately.
In case of eye contact : Immediately flush eye(s) with plenty of water. Protect unharmed eye. 


If swallowed : Call a physician immediately. Rinse mouth thoroughly with water. Do NOT induce vomiting.


Most important symptoms and effects, both acute and delayed Risks : irritant effects, carcinogenic effects
Indication of any immediate medical attention and special treatment needed Treatment : Elementary aid, decontamination and symptomatic treatment

Fire-fighting measures

Suitable extinguishing media : Alcohol-resistant foam, Dry powder, Water spray jet, Carbon dioxide (CO2)
Unsuitable extinguishing media: High volume water jet



Hazardous combustion products: Carbon dioxide (CO2), Carbon monoxide, Hydrogen chloride gas

Special protective equipmentfor firefighters: Wear self-contained breathing apparatus and protective suit.
Further information : Standard procedure for chemical fires. In the event of fire and/or explosion do not breathe fumes.
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Please observe escape and rescue routes! Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

Accidental release measures

Personal precautions : Wear personal protective equipment. Unprotected persons must be kept away.
Avoid contact with skin, eyes and clothing. The danger areas must be delimited and identified using relevant warning and safety signs.


Environmental precautions : Avoid release to the environment. Retain and dispose of contaminated wash water


Methods for cleaning up : Use mechanical handling equipment. Clean contaminated floors and objects thoroughly, observing
environmental regulations. Dispose of absorbed material in accordance with the regulations. Containers in which spilt substance has been collected must be adequately labelled.

Handling and storage

Advice on safe handling : Handle in accordance with good industrial hygiene and safety practice. Handle with care and avoid dust formation.
Avoid contact of the substance. Product should be worked up in closed equipment as far as possible. Wear personal protective equipment.


Advice on protection against fire and explosion: Normal measures for preventive fire protection. The product is combustible.
Keep away from heat and sources of ignition.
Hygiene measures : General industrial hygiene practice. Keep away from food and drink. Avoid contact with skin, eyes and clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash hands before breaks and at the end of workday.
Please thoroughly clean and care for the skin after finishing work. 


 


Requirements for storage areas and containers: Keep containers tightly closed in a dry, cool and well ventilated place. Keep away from heat and sources of ignition. Keep away from direct sunlight. Protect from moisture.
Advice on common storage : Do not store or transport together with foodstuffs
Storage class (TRGS 510) : 6.1D, Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effect

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN 3261
Shipping information
Proper shipping name and description:
Corrosive solid, Acidic, organic, N.O.S. (o-Chlorobenzotrichloride)
Chemical name:
o-Chlorobenzotrichloride
Language:
English
Class or division:
Class 8: Corrosive substances
Packing group:
Packing group III: Substances presenting low danger
Labels:
8
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
UN 3261
Shipping information
Proper shipping name and description:
Corrosive solid, Acidic, organic, N.O.S. (o-Chlorobenzotrichloride)
Chemical name:
o-Chlorobenzotrichloride
Language:
English
Class or division:
Class 8: Corrosive substances
Packing group:
Packing group III: Substances presenting low danger
Labels:
8
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
UN 3261
Shipping information
Proper shipping name and description:
Corrosive solid, Acidic, organic, N.O.S. (o-Chlorobenzotrichloride)
Chemical name:
o-Chlorobenzotrichloride
Language:
English
Class or division:
Class 8: Corrosive substances
Packing group:
Packing group III: Substances presenting low danger
EmS code:
F-A
S-B
Labels:
8
Marine pollutant
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
UN 3261
Shipping information
Proper shipping name and description:
Corrosive solid, Acidic, organic, N.O.S. (o-Chlorobenzotrichloride)
Chemical name:
o-Chlorobenzotrichloride
Language:
English
Class or division:
Class 8: Corrosive substances
Packing group:
Packing group III: Substances presenting low danger
Labels:
8
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Engineering measures: Provide sufficient air exchange and/or exhaust in work rooms.


Protective measures : Avoid contact with eyes and skin. Do not breathe vapours or spray mist.

Eye protection : Depending on the risk, wear sufficient eye protection (safety glasses with side protection or goggles, and if necessary,
face shield.)
Hand protection: Wear appropriate protective gloves. Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.
Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact). Gloves must be inspected prior to use. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Gloves must be rinsed thoroughly after use.
Suitable: Fluorinated rubber gloves
Skin and body protection : Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific workplace, e.g. apron, boots, protective suit (EN 14605, EN ISO 13982-1, EN 13034).
Respiratory protection : Use respirator when performing operations involving potential exposure to vapour of the product. In the case of dust or aerosol formation use respirator with an approved filter. Respirator with combination filter for vapour/particulate (EN 141), ABEK-P3-filter

Stability and reactivity

Chemical stability: No decomposition if stored and applied as directed.
Hazardous reactions : Hydrolysis. Reacts with water under emission of toxic gases (HCl).
Conditions to avoid : Protect from moisture.
Materials to avoid : Water, Iron, Strong bases
Hazardous decomposition products: Hydrogen chloride
No decomposition if stored and applied as directed.

Disposal considerations

Product: Special waste incineration plant, after consultation with operators.

Contaminated packaging: Packaging that cannot be cleaned should be disposed of as product waste.